• Title/Summary/Keyword: Corrosion Potential 부식전위

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The Study on the Corrosion Behavior of Al-alloy for Radiator (Radiator용 Al합금의 부식거동에 관한 연구)

  • 임우조;정기철;윤대영
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.135-139
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    • 2002
  • Most of all the mechanical devices are becoming more high-speed and high-power as well as their used condition being more polluted. So, it is necessary for these devices to equip cooling system to overcome that kind of severe using condition. In this study, corrosion test was carried out in distilled and tap water for the investigation on the corrosion characteristics of Al-alloy that is using as material for radiator.

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An Electrochemical Evaluation of the Corrosion Properties of the Steel with the Type and the Thickness of Metallizing Coatings (금속용사 코팅제의 종류 및 두께에 따른 강재 내식성의 전기화학적 평가)

  • Kang, Myeong-Sik;Eom, Sung-Hyun;Cho, Yeon-Chul;Ahn, Jae-Woo;Kim, Seong-Soo;Lee, Jeong-Bae
    • Resources Recycling
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    • v.25 no.3
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    • pp.55-62
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    • 2016
  • Steel structures exposed to extremely corrosive environment like marine environments and industrial area are generally manufactured by applying various protection treatment to increase their lifetime. Metal spraying is one of the protection methods to overcome some drawbacks of the widely employed technologies. Therefore, lots of research needs to be done to improve the corrosion resistance of steel structures. In this study, the corrosion resistance of steel structures was evaluated with the variation in the type and thickness of metal spray by measuring the corrosion potential and current density. As a raw material for spraying, Zn, Al and their mixture were employed to obtain coating thickness of $30{\sim}100{\mu}m$. Our data indicated that the pure zinc coating with $100{\mu}m$ showed the lowest corrosion potential. In the case of pure Al and Zn 85%-Al 15%, the corrosion potential and current density was decreased compared to pure zinc. It was found that the corrosion potential was decreased with the increase of coating thickness irrespective of the type of the coating.

Quantification of Half Cell Potential with Mix Properties in RC Member under Long-Term Chloride Exposure Conditions (장기 염해에 노출된 RC 부재의 배합 특성을 고려한 반 전위의 정량화)

  • Yoon, Yong-Sik;Jeong, Gi-Chan;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.307-313
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    • 2022
  • In this study, the correlation between Half Cell Potential(HCP) and the corrosion influencing factors was analyzed with considering three levels of water-cement ratio, the concentration of chloride solution, and cover depth. As a result of long-term corrosion monitoring, HCP behavior was close to the critical corrosion potential(-350 mV) in all water-cement ratios in the case of 3.5 % and 7.0 % chloride concentration. Regarding the passed charge test in 548 curing days, the passed charge results were improved to 'Moderate' grade. Multiple regression analysis was performed to evaluate the correlation between corrosion influencing factors and HCP, and it was evaluated that the effects of influencing factors to HCP were in the order of chloride concentration, water-cement ratio, and cover depth. In the case of the relationship between HCP and the passed charge, the coefficient of determination showed a high level of 0.9, which yielded a close correlation between the passed charge and HCP.

Analysis of Electrochemical Corrosion Resistance of Inconel 625 Thermal Spray Coated Fin Tube of Economizer (Inconel 625 용사코팅된 절탄기 핀튜브의 전기화학적 내식성 분석)

  • Park, Il-Cho;Han, Min-Su
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.1
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    • pp.187-192
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    • 2021
  • In this study, Inconel 625 was used as a thermal spray material to prevent dew point corrosion damage to the economizer tube, and sealing treatment was performed after applying the arc thermal spray coating technology. Various electrochemical experiments were conducted in the 0.5 wt% sulfuric acid solution to analyze the corrosion resistance of the thermal spray coating (TSC) layer. After the anodic polarization experiment, the degree of corrosion damage was determined through a scanning electron microscope and EDS component analysis. When measuring the open circuit potential, the effect of the sealing treatment was confirmed through stable potential formation of the TSC+sealing treatment (TSC+Sealing). As a result of the anodic polarization experiment, the passivation region was confirmed in TSC and TSC+Sealing, and corrosion resistance was improved as no corrosion damage was observed. In addition, the corrosion resistance of TSC+Sealing was the best when analyzing the corrosion potential and corrosion current density calculated by Tafel analysis.

Consideration on the Risk of Corrosion Assessment in Reinforced Concrete Structure by Corrosion Potential Criterion (부식전위 기준에 의한 철근콘크리트 구조물의 부식진단의 위험성에 관한 고찰)

  • Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.14 no.3
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    • pp.147-152
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    • 2015
  • Corrosion of steel reinforcement is a major factor in the deterioration of harbour and bridge structure. Steel corrosion in concrete must be checked for assessing the condition of a reinforced concrete structure. There are several ways how to measure the corrosion condition of reinforced concrete, but the corrosion potential measurement is a very simple, rapid, cost-effective and non-destructive technique to evaluate the severity of corrosion in reinforced concrete structure, therefore commonly used by engineers. However some particular situations may not relate to the reinforcement corrosion probability and a simple comparison of the corrosion potential data with the ASTM C876 Standard on steel reinforcement corrosion probability could be meaningless and not give reliable informations because of environment factors as oxygen concentration, chloride content, concrete resistance. Therefore this paper explains the risk of corrosion assessment in reinforced concrete structure and how many factors can affect the reliability of the corrosion potential data.

A Study on the Corrosivity according to Soil Characteristics and Electrolytic Protection for the Materials of Fuel Gas Pipe (토양 특성 및 전기방식에 따른 연료 가스용 강관의 부식 차이에 관한 연구)

  • Yim, Sang-Sik;Kim, Ji-sun;Ryu, Young-don;Lee, Jin-Han
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.16-22
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    • 2016
  • Coating pipe(PLP) has been generally used in buried site for protecting the corrosion. To prevent the damage by occurring the defect, other construction or execution works, an anti-oxidation environment was forcibly made by using protective potential. Coating and protective potential are applied simultaneously, but corrosion rate or defects are not easy to observe because soil composition has many uncertainty. Also, defect of coating pipe can not be directly observed. A corrosion coupon can easily measure a corrosion rate directly. The corrosion rate was measured with 6 scenarios using corrosion coupon during about 1 year(6 scenarios are based on soil type and protective potential or not in this research. Resultingly, the corrosion coupon has not occurred in the case of protected by potential current, but corrosion has occurred in a non-protected site. The corrosion rate was measured at least in the clay, and the propensity of corrosion rate was similar in other soil(sand and loams). The local corrosion has occurred in the clay because of high water content. On the other hand, general corrosion was occurred in sand and loams. Commonly, sand is not to corrosive soil. Although, corrosion occurred in sand can be estimated by chemical component and valid with chemical analysis report.

Study on the Web-based Prediction System for Corrosion Monitoring and Anti-corrosion (부식감시 및 방식을 위한 웹기반 예측시스템에 관한 연구)

  • Park, Hyoung-Keun;Kim, Sun-Yeob
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.2
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    • pp.784-789
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    • 2012
  • In this paper, a number of anode and reference electrodes that are installed around the target anti-corrosion objects to monitor, appropriate to your situation of a fixed potential and polarization methods can be applied automatically in the system was developed. In particular, this system was configured with a remote electric anti-corrosion automatic control device that have automatically adjust function to uniformal anti-corrosion in all parts of target objects, a corrosion monitoring device to perform the function of corrosion potential detection and a web-based operating program to perform the function of real-time monitoring, control and prediction. Using this system, by preventing oxidative corrosion phenomena can maximize the life of the target anti-corrosion objects.

A Study on Corrosion Estimates of Steel in Mortar Accelerated under the Environment of Artificial Seawater (인공해수(人工海水)에서 촉진시험(促進試驗)한 모르터 중의 철근부식(鐵筋腐蝕) 평가(評價)에 대한 연구(研究))

  • Moon, Han Young;Kim, Seong Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.5
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    • pp.67-75
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    • 1993
  • This study was performed for the purpose of estimating steel corrosion and of considering a countermeasure to prevent steel corrosion of concrete structures under the environment of seawater or using seasand. The corrosion of steel was accelerated in artificial seawater with seven kinds of specimen which was embedded steel in mortar. To assume the degree of steel corrosion, soluble chloride content in mortar, $Cl^-$ binding capacity, half cell potential and corrosion area ratio were measured. The results show that corrosion area ratio was correlative with half cell potential and soluble chloride content in mortar.

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Hydrodynamic and Oxygen Effects on Corrosion of Cobalt in Borate Buffer Solution (Borate 완충용액에서 코발트의 부식에 대한 대류와 산소의 영향)

  • Kim, Younkyoo
    • Journal of the Korean Chemical Society
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    • v.58 no.5
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    • pp.437-444
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    • 2014
  • The electrochemical corrosion and passivation of Co-RDE in borate buffer solution was studied by Potentiodynamic and electrochemical impedance spectroscopy. The mechanisms of both the active dissolution and passivation of cobalt and the hydrogen evolution in reduction reaction were hypothetically established while utilizing the Tafel slope, the rotation speed of Co-RDE, impedance data and the pH dependence of corrosion potential. Based on the EIS data, an equivalent circuit was suggested. In addition, the electrochemical parameters for specific anodic dissolution regions were carefully measured. An induction loop in Nyquist plot measured at the open-circuit potential was observed in the low frequency, and this could be attributed to the adsorption-desorption behavior in the corrosion process.

Non-Destructive Diagnosis on the Corrosion of Reinforcing Bar in Concrete (콘크리트중의 철근부식에 대한 비파괴 진단방법에 관한 연구)

  • 윤재환
    • Magazine of the Korea Concrete Institute
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    • v.4 no.2
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    • pp.75-81
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    • 1992
  • 염분을 함유한 철근콘크리트중의 철근부식에 관한 2년 촉진시험으로부터 콘크리트표면에서 측정한 자연전위값과 실제의 철근 부식상황과를 비교한 결과 철근의 수식상황을 자연전위법을 이용하여 비파괴적으로 진단하는 방법이 유효함을 알았다. 포화칼로멜전극을 사용했을 경우 -300mV이하이면 부식이 발생하였으며 -200mV이상이면 부식이 발생하지 않았다. 또한 부시공시체에 대한 휨강도시험도 행하였으며 중성화에 대한 검토로 행하였다.