• Corrosion Science and Technology
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• 제23권2호
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• pp.121-130
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• 2024

In recent years, Zn-Al-Mg alloy galvanized steel sheets have been widely used as coated steel sheets to support social capital in the infrastructure field. A feature of Zn-Al-Mg alloy-coated steel sheets is that they provide a better corrosion protection period than Zn-coated steel sheets. In this study, the corrosion resistance of a new Zn-Al-Mg alloy-coated steel sheet was investigated and compared to that of conventional commercially available coated steel sheets. The investigation confirmed that increasing the Mg concentration in the Zn-Al-Mg-coated steel sheet improved corrosion resistance, which was more than 10 times that of the galvanized steel sheet specified in JIS G 3302. The study findings also confirmed that the corrosion resistance reached more than twice that of the coated steel sheet specified in JIS G 3323. If such galvanized steel sheets are applied to social infrastructures that are exposed to severely corrosive environments, the service life of the infrastructure might be extended.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.1787-1791
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• 2007

For structural design and diagnosis, quantitative relationship between corrosive degradation and variation of mechanical properties such as tensile strength and fatigue strength is needed. But it is difficult to find data associated with corrosive degradation of structural structures. In this study, first of all we established the atmospheric corrosion test procedure. And using specimens of SM490A and SS400 on the atmospheric corrosion test bed, we carried out tensile and fatigue tests at regular intervals. And we studied the effect of post-weld heat treatment on the tensile and fatigue behaviour. It is found fatigue strength decreases as the atmospheric corrosion period increases.

• Corrosion Science and Technology
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• 제5권6호
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• pp.189-195
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• 2006

Effects of tungsten (W) on the precipitation kinetics of secondary phases and the associated resistance to pitting corrosion of 25%Cr duplex stainless steels were investigated through microstructural and electrochemical noise analyses. With the partial substitution of W for Mo in duplex stainless steel, the potential and current noises of the alloy were significantly decreased in chloride solution due to retardation of the ${\sigma}$ phase precipitation. The preferential precipitation of the $\chi$ phase in the W-containing alloy during the early period of aging contributed to retarding the precipitation of the $\sigma$ phase by depleting W and Mo along grain boundaries. In addition, the retardation of the nucleation and growth of the $\sigma$ phase in the W-containing alloy appears to be attributed to the inherently low diffusivity of W compared with that of Mo.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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• pp.262-263
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• 2019

In this study, a sensor for detecting corrosion of rebar embedded in reinforced concrete structures was fabricated and its performance was verified. In order to monitor the open circuit potential(OCP) of the rebar embedded in reinforced concrete, a concrete embedded solid electrode was constructed as a sensor using MnO2. The OCP of the rebar could be observed using a sensor and a data logger. The decrease of the OCP to -510mV (vs.MnO2) or less was judged to be corrosion of the rebar. Since it is a solid-mediated sensor, it is more stable and durable than an electrode using an aqueous solution, and it is considered that the corrosion state of the rebar can be monitored for a long period of time.

• Journal of Advanced Marine Engineering and Technology
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• 제28권2호
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• pp.332-337
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• 2004

The use of gas absorption refrigeration machine has considerably increased because of the shortage of the electric power in the summer and the regulation of freon refrigerant. Gas absorption refrigeration machine consists of a condenser, a heat exchanger. supplying pipes, a radiator etc, This system is likely to be corroded by acid. dissolved oxygen and gases, Cavitation erosion-corrosion by flow velocity of cooling water may happen in absorption refrigeration machine. In these cases. erosion and corrosion occur simultaneously. Then, it makes a serious damage with synergy effect. Therefore, this paper was studied on the cavitation damage of cupronickel(70/30) tube for gas absorption refrigeration machine, In the $30^{\circ}C$ tap water, linear polarization test and anodic polarization test were carried out for copper(C1220T-OL) and cupronickel(70/30) tube. Also, cavitation erosion-corrosion behavior of cupronickel (70/30) tube was considered, The main results are as following: (1) In the linear test, the corrosion current density of cupronickel(70/30) is higher than that of copper. (2) The erosion-corrosion rate of cupronickel(70/30) displayed later tendency than that of copper by vibratory cavitation in cooling water. (3) In cooling water, the progress mechanism of erosion-corrosion rate of copper and cupronickel(70/30) follows a pattern of incubation, acceleration, attenuation and a steady state period.

• 한국세라믹학회지
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• 제40권10호
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• pp.1015-1020
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• 2003

$\rho$-알루미나 결합 진동성형용 알루미나 캐스터블 내화물의 매트릭스부분과 용응 슬래그와의 침식거동을 젭센(Jabsen)이 주장한 이론을 기초로 하고 킹거리(Kingery)가 제안한 반응 기구를 통해 규명하였다. 매트릭스 부분의 초기침식이 분자확산거동에 의하여 지배되며, 아레니우스 관계식과 잘 일치하고 있어 온도의존성 활성화 과정으로 받아들 수 있다. 슬래그와 경계층의 Ca 농도차이가 23.2%로서 경계층을 형성하기 위한 물질이동의 구동력이 되었다. 매트릭스의 침식정도가 뮬라이트 소결체보다 심하지만 킹거리의 침식반응 기구와 잘 일치하고 있어 캐스터블의 수명예측이 가능하다.

• 보존과학연구
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• 통권16호
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• pp.59-111
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• 1995

Chemical composion and crystal form of Corrosion products found on archaeological iron objects were analyzed using X-ray fluorescence analysis, micro-X-ray powder diffraction analysis and ion chromatographic technique. The nature and behavior of the corrosion products were studied in order to aid in the conservation and restoration of burial iron objects. Twenty-two samples analyzed in this study were collected from iron object found in Korea and Japan. The corrosion products of iron objects from burial mounds contain $\alpha$-FeOOH, $\beta$-FeOOH, $\gamma$-FeOOH, $Fe_3O_4$and amorphous iron hydroxides. The content of $\alpha$-HeOOH is the greatest. Because, Ageing for long period should change the amorphous iron hydroxides is considerably less than that in usual atmospheric corrosion products. The concentration of chlorine and sulfine is remarkably variable ($Cl^-$ : 100- 30,000ppm, $SO_4^-2$ : 20-10,000ppm),but the reasons are unclear. The presence of generally high concentrations of chlorine and sulfine the corrosion products of iron objects seem to be influenced by the marine climatic condition. The presence of high chlorine and sulfine concentrations in the corrosion products of iron objects seem to be influenced by the marine burial environments.

• 한국건설순환자원학회논문집
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• 제5권2호
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• pp.113-120
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• 2017

HCP 측정법은 철근부식을 판단하는 비파괴 시험으로 현장에서 효과적으로 사용되고 있다. 본 연구는 실내실험을 통하여 촉진부식실험을 수행하고 건조 상태에서 측정된 HCP 측정값과 부식량의 상관성을 분석하는 연구이다. 이를 위해 4가지 피복두께와 3가지 물-시멘트비를 가진 시멘트 모르타르 시편을 제조하여 6시간, 18시간, 42시간동안 20V의 전압을 가하여 ICM에 의한 촉진실험을 수행하였다. 분석결과 피복두께의 감소, 물-시멘트비의 증가, 촉진부식시간의 증가에 따라 부식량이 증가하였으며, 측정된 HCP 값과는 선형적인 관계를 나타내었다. HCP를 사용하여 부식량을 평가하기 위해서는 전체 부식량을 비교하는 것보다, 일정수준의 HCP 값을 선정하고 이에 따라 부식량을 평가하는 것이 높은 결정계수를 얻는 합리적인 방법으로 평가되었다.

• 대한기계학회논문집
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• 제11권6호
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• pp.867-876
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• 1987

본 연구에서는 보통강재인 SS 41 강을 열처리하여 얻은 M.E.F.복합조직강의 모상입경변화와 3.5% NaCl수용액의 pH변화 조건하에서 반복굽힘피로실험을 하여 부식 피로파괴에 미치는 영향에 대해 고찰하였다.

• 한국산학기술학회논문지
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• 제16권8호
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• pp.5039-5044
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• 2015

본 연구에서는 철도차량의 차축소재로 사용되는 RSA1 소재에 대한 해수 부식특성 평가를 하였다. 미국재료시험협회에서 규정한 ASTM-D1141에 해당하는 인공해수를 사용하여 3전극 셀 구조를 이용한 동전위 분극법과 임피던스 분광법을 바탕으로 산출된 부식전류밀도와 부식속도는 각각 $18.3{\mu}A/cm2$와 0.217 mm/yr이다. 이 결과에 따르면 철도차량의 일반적인 내구연한인 25년을 가정할 때 한 면에서의 차축부식량은 5mm정도로 예상된다. 패러데이법칙을 바탕으로 한 정전류 부식 가속화 시험을 통해 1,3,4년의 부식양을 인위적으로 형성하였고, 단면적 감소분을 고려하여 인장시험을 시행하였다. 탄성구간에서는 부식에 의한 기계적 특성변화가 관찰되지 않았지만 소재의 연성 값은 부식이 진행 될수록 감소되는 경향을 보였다. 본 연구 결과는 향후 해수환경에서 사용될 철도차량 설계 시 고려할 기초 부식데이타로 활용될 것으로 기대된다.