• International Journal of Concrete Structures and Materials
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• 제4권2호
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• pp.71-75
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• 2010

The chloride ion attack on the passive iron oxide layer of reinforcement steel embedded in concrete under variable temperature environment is influenced by several parameters and some of them still need to be further investigated in more detail. Different school of thoughts exist between past researchers and the data is limited in the high temperature and high chloride concentration range which is necessary with regards to setting boundary conditions for enhancement of tafel diagram model presented in this research. The objective of this paper is to investigate the detrimental coupled effects of chloride and temperature on corrosion of reinforced concrete structures in the high range by incorporating classical Tafel diagram chloride induced corrosion model and laboratory controlled experimental non-linear effect of temperature on corrosion of rebar embedded in concrete.

• Computers and Concrete
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• 제19권3호
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• pp.305-313
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• 2017

A robust finite element based reinforced concrete bridge deck corrosion initiation model is applied for time-dependent probabilistic sensitivity analysis. The model is focused on uncertainties in the governing parameters that include variation of high performance concrete (HPC) diffusion coefficients, concrete cover depth, surface chloride concentration, holidays in reinforcements, coatings and critical chloride threshold level in several steel reinforcements. The corrosion initiation risk is expressed in the form of probability over intended life span of the bridge deck. Conducted study shows the time-dependent sensitivity analysis to evaluate the significance of governing parameters on chloride ingress rate, various steel reinforcement protection and the corrosion initiation likelihood. Results from this probabilistic analysis provide better insight into the effect of input parameters variation on the estimate of the corrosion initiation risk for the design of concrete structures in harsh chloride environments.

• 한국표면공학회지
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• 제40권6호
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• pp.271-278
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• 2007

In this study, applicable possibility in chemical decontamination for reactor coolant pump(RCP) was investigated for the various stainless steels. The stainless steel(STS) 304 showed the best electrochemical properties for corrosion current density and the lowest weight loss ratio in chemical decontamination process model 3-3 than other materials. The weightloss quantity in chemical decontamination process model 3-3 presents the lowest value compare to the other chemical decontamination process model 1, 2, 3-1 and 3-2. In the case of SEM observation, the pitting corrosion was generated in both STS 415 and STS 431 with the increasing numbers of cycle. The intergranular corrosion in STS 431 was sporadically observed. The sizes of their pitting corrosion were also increased with increasing cycle numbers.

• 상하수도학회지
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• 제20권5호
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• pp.737-745
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• 2006

The goal of this study is to present an external pit corrosion rate($p_{ecr}$) model with considering both the age of pipe and the soil characteristics. The correlation of nonlinear exponential model among conventional empirical models was a little higher than other empirical models in the prediction of $p_{ecr}$ according to the age of pipe. However, there has been a limit to predict Peer with the model by using only a pipe age since installation as a variable. The soil analysis results from sixty nine samples showed that all of the samples were non corrosive in the assessment of ANSI/AWWA scoring system. The correlation of soil corrosion factors and $p_{ecr}$ was also low. The application result of linear and nonlinear regression models that soil characteristics only showed a low correlation with $p_{ecr}$ Proposed nonlinear regression model in this study, with considering both the age of pipe and the soil characteristics, showed a little higher correlation ($R^2=0.46$) than conventional model.

• Corrosion Science and Technology
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• 제12권1호
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• pp.40-49
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• 2013

Effects of magnesium and pH on corrosion of aluminum galvanically coupled to iron have studied by using potentio- dynamic and static tests for polarization curves, Mott-Schottky test for analysis of semiconductor property, and GD-AES and XPS for film analysis. Pitting potential was sensitive to magnesium as an alloying element but not to pH, while passive current was sensitive to pH but not to magnesium. It was explained with, instead of point defect model (PDM), surface charge model describing that the ingression of chloride depends on the state of surface charge and passive film at film/solution interface is affected by pH. In addition, galvanic current of aluminum electrically coupled to iron was not affected by magnesium in pH 8.4, 0.2M citrate solution but was increased by magnesium at the solution of pH 9.1. The galvanic current at pH 9.1 increased with time at the initial stage and after the exposure of about 200 minute, decreased and stabilized. The behavior of the galvanic current was related with the concentration of magnesium at the surface. It agreed with the depletion of magnesium at the oxide surface by using glow discharge atomic emission spectroscopy (GD-AES). In addition, pitting potential of pure aluminum was reduced in neutral pH solution where chloride ion maybe are competitively adsorbed on pure aluminum. It was confirmed by the exponential decrease of pitting potential with log of [$Cl^-$] around 0.025 M of [$Cl^-$] and linear decrease of the pitting potential. From the above results, unlike magnesium, alloying elements with higher electron negativity, lowering isoelectric point (ISE), are recommended to be added to improve pitting corrosion resistance of aluminum and its alloys in neutral solutions as well as their galvanic corrosion resistance in weakly basic solutions.

• 대한기계학회논문집A
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• 제35권2호
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• pp.143-148
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• 2011

정유 석유화학 플랜트에서 탑 상부의 부식은 현장에서 자주 발생되는 심각한 문제이다. 특히 정유 공정 탑 상부에는 황화수소, 염소 등의 부식 물질들로 인하여 그 피해 정도가 심각하다. 따라서 본 연구에서는 정유 공정 탑 상부의 부식 메커니즘을 분석하고, 부식률을 예측하는 모델을 개발하였다. 정유 공정 탑 상부의 부식 메커니즘을 분석한 결과, 부식에 가장 큰 영향을 미치는 네 가지 성분인 $H_2S$, $CO_2$, $H^+$, $Cl^-$을 고려하여 예측 모델을 개발하였다. 부식 메커니즘을 해석하는 데에 이동 현상 및 반응 공학의 관점으로 접근하여 모델을 개발 하였다. 또한 실제 정유공장에서 측정된 데이터들을 토대로 그 신뢰성을 검증하였다.

• Journal of Mechanical Science and Technology
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• 제16권7호
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• pp.889-895
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• 2002

This paper presents the effect of external corrosion, material properties, operation condition and design thickness in pipeline on failure prediction using a failure probability model. The predicted failure assessment for the simulated corrosion defects discovered in corroded pipeline is compared with that determined by ANSI/ASME B31G code and a modified B31G method. The effects of environmental, operational, and random design variables such as defect depth, pipe diameter, defect length, fluid pressure, corrosion rate, material yield stress and pipe thickness on the failure probability are systematically studied using a failure probability model for the corrosion pipeline.

• Steel and Composite Structures
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• 제10권6호
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• pp.475-487
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• 2010

Most of steel structures in various industries are subjected to corrosion due to environmental exposure. Corrosion damage is a serious problem for these structures which may reduce their carrying capacity. These aging structures require maintenance and in many cases, replacement. The goal of this research is to consider the effects of corrosion by developing a model that estimates corrosion loss as a function of exposure time. The model is formulated based on average measured thickness data collected from three severely corroded I-beams (nearly 30 years old). Since corrosion is a time-dependent parameter. Analyses were performed to calculate the lateral buckling capacity of steel beam in terms of exposure time. Minimum curves have been developed for assessment of the remaining lateral buckling capacity of ordinary I-beams based on the loss of thicknesses in terms of exposure time. These minimum curves can be used by practicing engineers for better estimates on the service life of corrosion damaged steel beams.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1999년도 춘계학술발표회요약집
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• pp.279-279
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• 1999

To improve the corrosion model of the fuel performance analysis code COSMOS, a model was developed considering thermohydraulic phenomena and the effect of water chemistry and low Sn in the alloy composition on the corrosion behavior. It is assumed that the lithium enhancement factor influences the corrosion behavior only if the subcooled void is present in the coolant. The developed model was verified with the database obtained from Grohnde and Ringhals 3 reactors. Comparison of predicted oxide thickness with measured data showed the applicability of COSMOS code to analyze the cladding oxidation. In the future, the effect of the hydride in the cladding and the precipitate changes due to irradiation should be included.cluded.

• Steel and Composite Structures
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• 제50권3호
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• pp.363-374
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• 2024

The fatigue life of steel wire is affected not only by fatigue load, but also by corrosion environment in service period. Specially, the corrosion pit will lead to stress concentration on the surface of steel wire inducing the formation of fatigue cracks, and the fatigue cracks will accelerate the corrosion process. Therefore, the corrosion fatigue of steel wire is a coupling effect. In this study, the corrosion-fatigue coupling life curve is derived with considering corrosion-fatigue pitting stage, corrosion-fatigue short crack stage and corrosion-fatigue long crack stage. In addition, the stress concentration factors of different corrosion pits are calculated by COMSOL software. Furthermore, the effect of corrosion environment factors, that is, corrosion rate, corrosion pit morphology, frequency and action factor of fatigue load, on fatigue life of steel wire is analyzed. And then, the corrosion-fatigue coupling life curve is compared with the fatigue life curve and fatigue life curve with pre-corrosion. The result showed that the anti-fatigue performance of the steel wire with considering corrosion-fatigue coupling is 68.08% and 41.79% lower than fatigue life curve and fatigue life curve with pre-corrosion. Therefore, the corrosion-fatigue coupling effect should be considered in the design of steel wire.