• 한국구조물진단유지관리공학회 논문집
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• 제14권1호
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• pp.78-83
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• 2010

철근부식에 의해 발생된 녹은 철근 주위의 콘크리트에 팽창압력을 발생시켜 콘크리트의 균열유발, 피복콘크리트의 박리나 탈락, 철근의 단면적 감소들을 야기 시킨다. 또한 철근콘크리트 구조물 내에 매입된 철근의 부식은 철근과 콘크리트의 일체 거동을 저하시킴으로써 구조물이 외력에 견딜 수 있는 구조성능의 감소를 초래한다. 본 논문에서는 3차원 스캐너를 이용하여 철근이 부식됨에 따른 철근의 표면적을 측정하여 부식률과 표면 거칠기와의 관계를 파악하였다. 철근부식률 1~2%의 경우에서는 철근 표면적이 증가하는 것으로 나타났다. 이는 동일 범위내에서 철근의 부착강도가 증가한 기존의 실험결과와 매우 유사한 결과를 나타낸다. 철근부식률 2% 이상에서는 오히려 표면적이 감소하였으며, 이는 단면적 손실로 인한 기존 부착강도 실험과 부합되는 결과를 나타냈다.

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1795-1799
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• 2013

The corrosion property of aluminum by lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt is investigated in liquid and gel electrolytes consisting of ethylene carbonate/propylene carbonate/ethylmethyl carbonate/diethyl carbonate (20:5:55:20, vol %) with vinylene carbonate (2 wt %) and fluoroethylene carbonate (5 wt %) using conductivity measurement, cyclic voltammetry, scanning electron microscopy, and energy dispersive X-ray spectroscopy. All corrosion behaviors are attenuated remarkably by using three gel electrolytes containing 3 wt % of hydrophilic and hydrophobic fumed silica. The addition of silica particles contributes to the increase in the ionic conductivity of the electrolyte, indicating temporarily formed physical crosslinking among the silica particles to produce a gel state. Cyclic voltammetry also gives lower anodic current responses at higher potentials for repeating cycles, confirming further corrosion attenuation or electrochemical stability. In addition, the degree of corrosion attenuation can be affected mainly by the electrolytic constituents, not by the hydrophilicity or hydrophobicity of silica particles.

• 비파괴검사학회지
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• 제27권2호
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• pp.142-147
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• 2007

콘크리트에 매입된 철근의 정량적인 부식률을 측정하기 위해 적외선 열화상법을 이용하였다. 적외선 촬영 실험에서는 부식률(0, 1, 3, 5, 7, 10%)과 대기온도(16, 21, 25, $28^{\circ}C$), 피복두께(10 mm, 20 mm, 30 mm)에 변수를 주어 콘크리트 표면온도를 측정하였으며, 콘크리트 표면온도의 초기 온도상승률에 대해서 측정결과를 분석하여 다음과 같은 결론을 얻었다. 적외선 촬영으로 얻어진 열화상 정보는 서로 다른 부식률과 피복두께에서는 현저한 차이를 보였으나 대기온도에 대해서는 그 영향이 미비하게 나타났다. 철근의 부식률에 따른 열 발생량이 콘크리트 표면온도에 부식률에 비례하여 열을 발생시킴으로써 철근의 부식률을 정량적으로 평가할 수 있는 분석기법을 연구하였다.

• Journal of Welding and Joining
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• 제19권1호
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• pp.65-74
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• 2001

A study on the corrosion behavior in case of As-welded and PWHT temperature 55$0^{\circ}C$ of welding part of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential measurement of weld metal(WM), base metal(BM) and heat affected zone(HAZ), both Al anode generating current and Al anode weight loss quantity under sacrificial anode cathodic protection conditions. And also we carried out slow strain rate test(SSRT) in order to research both limiting cathodic polarization potential for hydrogen embrittlement and optimum cathodic protection potential as well as mechanical properties by post-weld heat treatment(PWHT) effect. Hardness of HAZ was the highest among three parts(WM, BM and HAZ) and the highest galvanic corrosion susceptibility was HAZ. And the optimum cathodic polarization potential showing the best mechanical properties by SSRT method was from -770mV to -875mV(SCE). In analysis of SEM fractography, applied cathodic potential from -770mV to -875mV(SCE) it appeared dimple pattern with ductile fracture while it showed transgranular pattern (Q. C : quasicleavage) under -900mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement was under -900mV(SCE).

• 콘크리트학회논문집
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• 제17권2호
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• pp.303-309
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• 2005

This study aims the evaluation of the corrosion of steel bar embedded in antiwashout underwater concrete, which has rather been neglected to date. To that goal, accelerated steel bar corrosion tests have been performed on three series of steel bar-reinforced antiwashout underwater concrete specimens manufactured with different admixtures. The three series of antiwashout underwater concrete were: concrete constituted exclusively with ordinary portland cement (OPC), concrete composed of ordinary portland cement mixed with fly-ash in $20\%$ ratio (FA20), and concrete with ground granulated blast furnace slag mixed in $50\%$ ratio (BFS50). The environment of manufacture was in artificial seawater. Measurement results using half-cell potential surveyor showed that, among all the specimens, steel bar in OPC was the first one that exceeded the threshold value proposed by ASTM C 876 with a potential value below -350mv after 14 cycles. And, the corresponding corrosion current density and concentration of water soluble chloride were measured as $30{\mu}A/mm^2$ and $0.258\%$. On the other hand, for the other specimens that are FA20 and BFS50, potential values below -350mV were observed later at 18 and 20 cycles, respectively. Results confirmed the hypothesis that mineral admixtures may be more effective on delay the development of steel bar corrosion in antiwashout underwater concrete.

• 동력기계공학회지
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• 제6권1호
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• pp.74-81
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• 2002

The characteristics of corrosion resistance for the surface of ductile cast iron(GCD40) by plasma nitriding process have been studied in terms of electrochemical polarization behaviors including corrosion potential($E_{corr}$), anodic polarization trends, polarization resistance($R_p$), and also have been studied microstructures, hardness and specific wear of nitrided layer Nitrided layer showed an enhanced hardness values in all the plasma nitriding condition investigated. In the result of wear test, specific wear of nitrided specimens were much decreased than that of non-treated specimens. In the results of XRD, ${\gamma}'phase\;and\;{\varepsilon}$ phase were detected in nitrided surface. And it was found that ${\varepsilon}$ phase was decreased and ${\gamma}'phase$ was increased respectively, as the nitriding time became longer. In the test of corrosion resistance, natural potentials in all the nitrided specimens were towards noble directions than in the case of non-treated specimens. The measurement of electrode potentials revealed that corrosion resistivity of plasma nitrided specimens were higher than in the case of the non-treated specimens.

• Corrosion Science and Technology
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• 제21권2호
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• pp.147-157
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• 2022

Electrochemical characteristics and damage behavior of 6061-T6 aluminum alloy used as a battery housing material for electric vehicles were investigated in solution simulating the acid rain environment with chloride concentrations. Potentiodynamic polarization test was performed to analyze electrochemical characteristics. Damage behavior was analyzed through Tafel analysis, measurement of damage area, weight loss, and surface observation. Results described that corrosion current density was increased rapidly when chloride concentration excceded 600 PPM, and it was increased about 7.7 times in the case of 1000 PPM compared with 0 PPM. Potentiodynamic polarization experiment revealed that corrosion damage area and mass loss of specimen increased with chloride concentrations. When chloride concentration was further increased, the corrosion damage area extended to the entire surface. To determine damage tendency of pitting corrosion according to chloride concentration, the ratio of damage depth to width was calculated. It was found that the damage tendency decreased with chloride concentrations. Thus, 6061-T6 aluminum alloy damage becomes larger in the width direction than in the depth direction when a small amount of chloride is contained in an acid rain environment.

• 한국재료학회지
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• 제32권10호
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• pp.442-447
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• 2022

Sealing treatment is a post-surface treatment of the plasma spray coating process to improve the corrosion resistance of the coating material. In this study, the effect of the sealing on the corrosion resistance and adhesive strength of the plasma spray-coated alumina coatings was analyzed. For sealing, an epoxy resin was applied to the surface of the coated specimen using a brush. The coated specimen was subjected to a salt spray test for up to 48 hours and microstructural analysis revealed that corrosion in the coating layer/base material interface was suppressed due to the resin sealing. Measurement of the adhesive strength of the specimens subjected to the salt spray test indicated that the adhesive strength of the sealed specimens remained higher than that of the unsealed specimens. In conclusion, the resin sealing treatment for the plasma spray-coated alumina coatings is an effective method for suppressing corrosion in the coating layer/base material interface and maintaining high adhesive strength.

• 한국가스학회지
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• 제18권5호
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• pp.66-71
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• 2014

가스 배관은 도시가스 시설물의 핵심 시설물로 대부분 지하에 매설되어 있으며, 매설 토양의 특성 및 환경적 영향 등으로 인해 배관부식 등의 시설물 손상 위험에 상시 노출되어 있다. 매설배관은 관련법규에 따라 방식 상태나 배관의 방식전위를 주기적으로 측정하고 있다. 본 연구에서는 기존 방식전위 측정시스템의 문제점을 보완하기 위해 매설배관의 방식전위 측정시스템 개발에 관한 연구를 수행하였다. 연구내용은 관련 법규를 만족시키기 위한 방식전위 측정 기준 및 규격, 기준전극 규격 조사와 방식전위 측정시스템 구축을 위한 측정회로 및 데이터 송신 모듈 개발이다. 개발된 시작품의 테스트를 통해 현장 적용성을 검증하고, 선행연구를 통한 보완점과 향후 연구개발 방향에 대하여 고찰하였다.

• 한국구조물진단유지관리공학회 논문집
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• 제24권6호
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• pp.171-179
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• 2020

본 연구에서는 강박스 부재의 국부 부식열화환경을 모니터링하기 위하여 실제 강교량 부재로 사용하는 부재와 동일한 형상의 강박스 모형 시험체를 제작하였으며, 실제 공용 중인 강교량과 동일한 부식환경이 구현된 강박스 모형 시험체를 상부부재, 복부부재, 하부부재로 구분하여 모니터링을 진행하였다. 각 부재에 부식환경 모니터링 센서를 설치하여 부식전류를 계측하였으며, 부식전류량 계측 값으로부터 젖음시간을 계산하여 강박스 부재에 따른 국부적인 부식환경을 평가하였다. 모니터링 결과를 통하여 주위의 대기환경으로 인하여 나타날 수 있는 부식환경과 강박스 부재 표면에 직접적으로 나타날 수 있는 부식환경의 상대적인 차이를 검토하였으며, 강박스 부재들의 상대적 부식환경과 평균부식두께의 관계를 평가하였다.