• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.39 no.4
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• pp.291-297
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• 2003

Al-brass is usually used as the tube material of vessel's heat exchanger for seawater cooling system because it has high thermal conductivity and good mechanical properties and high corrosion resistance due to cuprous oxide (Cu20) layer against seawater. However, Al-brass tubes of heat exchanger for vessel at the actual environment is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment In this paper, the effect of corrosion environment on the stress corrosion cracking of Al-brass in various NH4OH of 3.5% NaCl solution, under flow by constant displacement tester. Based on the test results, the behavior of polarization, stress corrosion crack propagation and dezincification phenomenon of Al-brass are investigated. The main results are as follows：(1) Increasing range of potential from open circuit potential to repassivation gets lower, as the contain rate of NH4OH gets higher. (2) As contain rate of NH4OH gets higher, SCC of Al-brass is become activation but the protection film(Cu20) of Al-brass is created in 3.5% NaCl solution. (3) According as content of NH4OH increases in 3.5% NaCl solution, the dezincifiction area is spread. It is concluded that dezincification occurred by localized preferential anodic dissolution at stress focusing region.

• Advances in concrete construction
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• v.7 no.1
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• pp.11-22
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• 2019

A comprehensive assessing approach for durability of reinforced concrete structures dealing with the corrosion process of rebar subjected to the attack of aggressive agent from environment was proposed in this paper. Corrosion of rebar was suggested in the form of combination of global corrosion and pitting. Firstly, for the purposed of considering the influence of rebar's radius, a type of Plane Corrosion Model (PCM) based on uniform corrosion of rebar was introduced. By means of FE simulation approach, global corrosion process of rebar regarding PCM and LCM (Linear Corrosion Model) was regressed and compared according to the data from Laboratoire $Mat{\acute{e}}riaux$ et $Durabilit{\acute{e}}$ des Constructions (LMDC). Secondly, pitting factor model of rebar in general descend law with corrosion degree was introduced in terms of existing experimental data. Finally, with the comprehensive numerical simulation, the durability of an existing arch bridge was studied in depth in deterministic way, including diffusion process and sectional strength of typical cross section of arch, crossbeam and deck slab. Evolution of structural capacity considering life-cycle rehabilitation strategy indicated the degradation law of durability of reinforced arch bridges.

• Journal of the Korean institute of surface engineering
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• v.57 no.3
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• pp.192-200
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• 2024

Cu as a heat exchanger tube is an important component in thermal fluid transfer. However, Cu tubes are exposed to stress in certain environments, leading to stress corrosion cracking (SCC). In this study, the effect of Sn addition on microstructure and corrosion characteristics was examined. The microstructural examination revealed the presence of columnar crystal and a grain refinement due to the addition of Sn. Electrochemical measurements showed that the 5 wt.% NH₃ environment was the most vulnerable environment to Cu corrosion, and the corrosion current density increased as stress increased. The immersion test exhibited the formation of Cu2O and Cu(OH)₂ corrosion product in 3.5 wt.% NaCl and 5 wt.% NH₃ environments, respectively. Results indicated that Sn addition to Cu was an important factor in improving the mechanical strength.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.3 s.174
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• pp.603-612
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• 2000

Corrosion characteristics on the 12Cr alloy steel of turbine blade was electro-chemically investigated in 3.5wt% NaCI and 12.7wt% Na2S04 solution, respectively. Electro-chemical polarization test, Huey test and Oxalic acid etching test were previously conducted to estimate corrosion susceptibility of the material. And, using the horizontal corrosion fatigue tester, corrosion fatigue characteristics of 12Cr alloy steel in distilled water, 3.5wt% NaCI solution, and 12.7wt%(1M) Na2S04 solution were also fracture-mechanically estimated and compared their results. Parameter considered was room temperature, 60'C and 90'C. Corrosion fatigue crack length was measured by DC potential difference method.Obtained results are as follows,1) 12Cr alloy steel showed high corrosion rate in 3.5wt% NaCI solution and Na2S04 solution at high tempratue.2) Intergranular corrosion sensitivity of 12 Cr alloy was smaller than austenitic stainless steel.3) Corrosion fatigue crack growth rate in 3.5wt% NaCI and 12.7wt%(IM) Na2S04 solution is entirely higher than in the distilled water, and also increased with the temperature increase.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.113-113
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• 2008

Cu CMP (Chemical Mechanical Planarization) has been used to remove copper film and obtain a planar surface which is essential for the semiconductor devices. Generally, it is known that chemical reaction is a dominant factor in Cu CMP comparing to Silicon dioxide CMP. Therefore, Cu CMP slurry has been regarded as an important factor in the entire process. This investigation focused on understanding the effect of corrosion inhibitor on copper surface and CMP results. Benzotriazole (BTA) was used as a corrosion inhibitor in this experiment. For the surface analysis, electrochemical characteristics of Cu was measured by a potentiostat and surface modification was investigated by X-ray photoelectron spectroscopy (XPS). As a result, corrosion potential (Ecorr) increased and nitrogen concentration ratio on the copper surface also increased with BTA concentration. These results indicate that BTA prevents Cu surface from corrosion and forms Cu-BTA layer on Cu surface. CMP results are also well matched with these results. Material removal rate (MRR) decreased with BTA concentration and static etch rate also showed same trend. Consequently, adjustment of BTA concentration can give us control of step height variation and furthermore, this can be applicable for Cu pattern CMP.

• Corrosion Science and Technology
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• v.4 no.4
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• pp.155-163
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• 2005

Heavy duty coating are required to have minimum durable period of 15 years under average usage environment because these paints are coated with purpose of anti-corrosion, antifouling, plastering etc. Onto steel structures constructed upon land and sea and other ferrous structures of electric power generation plants, electricity transmission towers, large structures of various plants, etc. Therefore we tried to estimate heavy duty coating longevity through reliability evaluation method and used combined cyclic anti-conrrosion test method composed of drying, moisturizing and salt spray as for accelerated life test to estimate longevity. Accelerated life test hours to heavy duty coating of first grade (with longevity not less than 15 years) specification may be obtained from troubleless test hours $t_n=\frac{B_p}{n^{1/\beta}}\left[\frac{1n(1-CL)}{1n(1-p)} \right]^{1/\beta}=19.671$ (yr) where shape parameter $\beta=1.1$, confidence level CL=80 %, warranty life $B_{10}=15$ yr and sampling size n=10 (2 sets). Because acceleration factor {AF} found by accelerated test is 41.7, accelerated life test hours required may be represented about 4,132 hr so that if this amount of hours is converted to number of cycles(6 hr/cycle) of complex cycle corrosion resistance test then the amount is tantamount about 690 cycles. That means if there does not occur trouble failure (with defect factor sum not more than 20) during when there is performed 690 cycles of combined cyclic anti-corrosion test to heavy duty coating specimen then it signifies that there can be warranted longevity $B_{10}$ of 15 yr under condition of confidence level CL=80 %.

• Journal of Fisheries and Marine Sciences Education
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• v.9 no.2
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• pp.198-208
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• 1997

Recently, with rapid increase of gas demand, there occurs much interest their security of safety in the gas storage tanks and pressure vessels etc. In order to solve the problems, the occurrence of corrosion fatigue crack and the propagation behavior must be investigated. Especially the occurrence of corrosion fatigue crack and the propagation behavior in the part which has concentrated stress or defects, must be studied more carefully. In this paper, the high-tensile steel of SPV 50 which is much used for building the LPG storage tanks was tested by the use of a plane bending corrosion fatigue tester under the various marine environment and in the air. These experiments were carried out to investigate the surface crack propagation behavior, the value of experimental constant for Paris' rule(da/dN=$C(K)^m$), the crack depth propagation rate and the accelerative factor of the surface crack propagation rate. The main results obtained are as follows ; 1) As the specific resistances of marine environment decreases, the exponential value of slope m of Paris' rule(da/dN=$C(K)^m$) decreases and the value of intercept C increases. 2) The surface crack propagation rate and the crack depth propagation rate are delayed, as the specific resistances of marine environment is increased. 3) The accelerative factor of the surface crack propagation rate by corrosion fatigue is higher, according as the stress intensity factor range ${\Delta}K_A$ is small.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.205-206
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• 2002

In this paper we examined the contribution of mechanical and electrochemical factors in corrosive wear for Zr-alloy against $Al_2O_3$ ball in $Na_2SO_4$ solution. Normal load and the area of metallic specimen was varied to change the corrosion behavior. At the commence of sliding, the potential drop took place, which increased with load due to the great exposure of fresh surface. Wear volume was linearly proportional to load. The corrosion factor was about 15%. By increasing the Aa/Ac ratio, corrosion factor to total wear decreases and saturates above Aa/Ac=0.15.

• Journal of Industrial Technology
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• v.18
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• pp.453-460
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• 1998

The purpose of this study was to analyze their status of underground storage tank(UST) facilities and level of soil contamination, and to establish its management criteria. DB program was developed to analyze the correlation between specific characteristic of UST and level of soil contamination. For a suitable management of UST, leakage monitoring and inspection method of UST was investigated. Inspection period was established based on the leakage rate. The most dominant factor for leakage seemed to be caused by the corrosion. Therefore, main factor, construction method and installation year of UST, and corrosion protection system were suggested for optimal protection of UST. Considering the present management status of UST in Korea, inspection and management criteria of UST should be accomplished in term of contamination protection of leakage, and flexible regulation act should be introduced for each specific site.

• Corrosion Science and Technology
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• v.3 no.1
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• pp.6-13
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• 2004

The effect of inhibitors on the electrochemical behavior and the stress corrosion cracking resistance of Alloy 600(UNS N06600) was evaluated in 10% sodium hydroxide solution at $315^{\circ}C$. The specimens of a C-ring type for stress corrosion cracking test were polarized at 150 mV above the corrosion potential for 120 hours with and without inhibitors such as titanium oxide, titanium boride and cerium boride. The chemical compositions of the films formed on the crack tip in the C-ring specimens were analyzed using a scanning Auger electron spectroscopy. The cerium boride, the most effective, was observed to decrease the crack propagation rate more than a factor of three compared with that obtained in no inhibitor solution. It was found that the changes of the active-passive transition potentials and the film compositions were related to the resistance to stress corrosion cracking in high temperature caustic solution.