• 한국신재생에너지학회:학술대회논문집
• /
• 2008.10a
• /
• pp.1-5
• /
• 2008

Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

• Corrosion Science and Technology
• /
• v.13 no.4
• /
• pp.125-129
• /
• 2014

Shinning spot defects on galvanized steel sheets were studied by optical microscope, scanning electron microscope(SEM), Energy Dispersive Spectrometer (EDS) and Laser-Induced Breakdown Spectroscopy Original Position Statistic Distribution Analysis (LIBSOPA) in this study. The research shows that the coating thickness of shinning spot defects which caused by the substrate defect is much lower than normal area, and when skin passed, the shinning spot defect area can not touch with skin pass roll which result in the surface of shinning spot is flat while normal area is rough. The different coating morphologies have different effects on the reflection of light, which cause the shinning spot defects more brighter than normal area.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.11a
• /
• pp.461-461
• /
• 2008

According to previous report, aged sleeves for old transmission lines have various defect such as biased installation or corrosion of steel sleeve. These defects occupied almost 50 percent of investigated aged sleeves. The defects have been limited power capacity of transmission line. And it can cause serious problems such as rapid increasing of sag or falling out of overhead conductor from sleeve. This paper study on thermal behavior of sleeve with various defect model. The detailed results were presented in the text.

• Proceedings of the KSME Conference
• /
• 2008.11a
• /
• pp.305-310
• /
• 2008

This paper provides the methods to estimate the burst pressures of the pipes with defects, based on finite element analyses. FE codes are frequently adopted for the simulations of the burst tests of the pipes with defects. However, those do not give the burst pressure directly. Because the post-processing should be followed; determination of the fracture strains in accordance with triaxialities, monitoring the strains of pipes, etc. In the present work, these efforts are implemented in the user subroutine UHARD within the general-purpose FE code, ABAQUS. Four fracture criterions are introduced to estimate the burst pressure of pipes, and a simple fracture strain estimate is also developed. FE analyses for the pipe with gouge and corrosion are performed, and the results are compared with the experiment results.

• Proceedings of the KSME Conference
• /
• 2004.04a
• /
• pp.234-239
• /
• 2004

A study on the probabilistic methodology for the estimation of the remaining life of Pressurized pipelines containing active corrosion defects is presented. This reliability assessment is earned out using extream value distribution of the corroded defects instead of already published failure perssure moded like NG18 or ASME B31G. The failure probability of pipelines depends on the number of corroded defects. and it could be calculated directly as the area exceeded a defined L V(Limited Value of corrosion depth). The remaining life of pressurized pipelines can also be estimated by the PDF of extream value distribution as calculating the exceeded area with a defined failure probability.

• Corrosion Science and Technology
• /
• v.16 no.3
• /
• pp.151-159
• /
• 2017

The MA8 alloy (formula Mg-Mn-Се) has been shown to have greater corrosion stability than the VMD10 magnesium alloy (formula Mg-Zn-Zr-Y) in chloride-containing solutions by Scanning Vibrating Electrode Technique (SVET) and by optical microscopy, gravimetry, and volumetry. It has been established that the crucial factor for the corrosion activity of these samples is the occurrence of microgalvanic coupling at the sample surface. The peculiarities of the kinetics and mechanism of the corrosion in the local heterogeneous regions of the magnesium alloy surface were investigated by localized electrochemical techniques. The stages of the corrosion process in artificial defects in the coating obtained by plasma electrolytic oxidation (PEO) at the surface of the MA8 magnesium alloy were also studied. The analysis of the experimental data enabled us to determine that the corrosion process in the defect zone develops predominantly at the magnesium/coating interface. Based on the measurements of the corrosion rate of the samples with PEO and composite polymer-containing coatings, the best anticorrosion properties were displayed by the composite polymer-containing coatings.

• International Journal of Precision Engineering and Manufacturing
• /
• v.1 no.2
• /
• pp.48-54
• /
• 2000

This paper presents the effect of shape of external corrosion in pipeline on failure prediction by using a numerical simulation. The numerical study for the pipeline failure analysis is based on the FEM(Finite Element Method)with an elastic-plstic and large-deformation analysis. Corrosion pits and narrow corrosion grooves in pressurized pipeline were analysed. A failure criterion, based on the local stress state at the corrosion and a plastic collapse failure mechanism, is proposed. The predicted failure stress assessed for the simulated corrosion defects having different corroded shapes along the pipeline axis compared with those by methods specified in ANSI/ASME B31G code and a modified B31G code. It is concluded the corrosion geometry significantly affects the failure behavior of corroded pipeline and categorisation of pipeline corrosion should be considered in the development of new guidance for integrity assessment.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2016.11a
• /
• pp.105-105
• /
• 2016

Recently, high power impulse magnetron sputtering (HIPIMS) has attracted considerable attentions due to its high potential for industrial applications. By pulsing the sputtering target with high power density and short duration pulses, a high plasma density and high ionization of the sputtered species can be obtained. HIPIMS has exhibited several merits such as increased coating density, good adhesion, microparticle-free and smooth surface, which make the HIPIMS technique desirable for synthesizing hard coatings. However, hard coatings present intrinsic defects (columnar structures, pinholes, pores, discontinuities) which can affect the corrosion behavior, especially when substrates are active alloys like steel or in a wear-corrosion process. Atomic layer deposition (ALD), a CVD derived method with a broad spectrum of applications, has shown great potential for corrosion protection of high-precision metallic parts or systems. In ALD deposition, the growth proceeds through cyclic repetition of self-limiting surface reactions, which leads to the thin films possess high quality, low defect density, uniformity, low-temperature processing and exquisite thickness control. These merits make ALD an ideal candidate for the fabrication of excellent oxide barrier layer which can block the pinhole and other defects left in the coating structure to improve the corrosion protection of hard coatings. In this work, CrN/Al2O3/CrN multilayered coatings were synthesized by a hybrid process of HIPIMS and ALD techniques, aiming to improve the CrN hard coating properties. The influence of the Al2O3 interlayer addition, the thickness and intercalation position of the Al2O3 layer in the coatings on the microstructure, surface roughness, mechanical properties and corrosion behaviors were investigated. The results indicated that the dense Al2O3 interlayer addition by ALD lead to a significant decrease of the average grain size and surface roughness and greatly improved the mechanical properties and corrosion resistance of the CrN coatings. The thickness increase of the Al2O3 layer and intercalation position change to near the coating surface resulted in improved mechanical properties and corrosion resistance. The mechanism can be explained by that the dense Al2O3 interlayer acted as an excellent barrier for dislocation motion and diffusion of the corrosive substance.

• Journal of the Korean institute of surface engineering
• /
• v.32 no.3
• /
• pp.472-483
• /
• 1999

Hard coatings playa continuously increasing role in the field of tribology as well as for decorative applications. In both areas they are often also exposed to corrosive media. While especially hard nitride coatings show a high corrosion resistance for themselves, hard $coating_strate systems may suffer from a severe corrosion attack due to the defects in the coating structure (pores, pinholes) resulting from the PVD-typical film morphology. While a huge number of investigations cover the tribological properties, only limited studies deal with the corrosion behavjour of coating substrate systems and attempts are made to improve their corrosion resistance. The present paper shortly describes the corrosion mechanisms and repots characteristic examples of the system behaviour. Special emphasis is laid on recent investigations to improve the corrosion resistance by alloying, interlayers or multilayered coating structures.es.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2022.11a
• /
• pp.81-82
• /
• 2022

Al and Zn are used to protect the steel structures from corrosion. In the present studies, 15Al-85Zn alloy wires has been used for the deposition of coating by arc thermal spray process. Moreover, this process of coating exhibited severe defects formation, therefore, this coating was post-treated with different concentrations i.e. 0.05, 0.1 and 0.5M sodium hexa meta phosphate (Na6[(PO3)6]: SHMP) to fill to defects of deposited coatings and assessed their corrosion resistance in 3.5 wt.% NaCl solution with exposure periods. After the treatment, the porosity of the coating reduced significantly by formation of composite oxide films onto the coating surface. Initially, 0.5 M SHMP treated coating exhibited highest in total impedance due to significant reduction of porosity but once the exposure periods are extended, the composite oxides are dissolved, thus, total impedance is decreased.