• Korean Journal of Materials Research
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• v.17 no.7
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• pp.366-370
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• 2007

Silicon nitride ($Si_3N_4$) ceramics have been considered for various components of nuclear power plants such as the mechanical seal of a reactor coolant pump (RCP), the guide roller for a control rod drive mechanism (CRDM), and a seal support, etc. Corrosion behavior of $Si_3N_4$ ceramics in a high-temperature and high-pressure water must be elucidated before they can be considered as components for nuclear power plants. In this study, the corrosion behaviors of $Si_3N_4$ ceramics containing MgO and $Al_2O_3$ as sintering aids were investigated at a hydrothermal condition ($300^{\circ}C$, 9.0 MPa) in pure water and 35 ppm LiOH solution. The corrosion reactions were controlled by a diffusion of the reactive species and/or products through the corroded layer. The grain-boundary phase was preferentially corroded in pure water whereas the $Si_3N_4$ grain seemed to be corroded at a similar rate to the grain-boundary phase in LiOH solution. Flexural strengths of the $Si_3N_4$ ceramics were significantly degraded due to the corrosion reaction. Results of this study imply that a variation of the sintering aids and/or a control (e.g., crystallization) of the grain-boundary phase are necessary to increase the corrosion resistance of $Si_3N_4$ ceramics in a high-temperature water.

• Journal of the Korean institute of surface engineering
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• v.52 no.4
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• pp.194-202
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• 2019

A systematic investigation was made on the influence of processing parameters such as gas composition and treatment temperature on the surface characteristics of hardened layers of low temperature plasma nitrided 316L Austenitic Stainless Steel. Various nitriding processes were conducted by changing temperature ($370^{\circ}C$ to $430^{\circ}C$) and changing $N_2$ percentage (10% to 25%) for 15 hours in the glow discharge environment of a gas mixture of $N_2$ and $H_2$ in a plasma nitriding system. In this process a constant pressure of 4 Torr was maintained. Increasing nitriding temperature from $370^{\circ}C$ to $430^{\circ}C$, increases the thickness of S phase layer and the surface hardness, and also makes an improvement in corrosion resistance, irrespective of nitrogen percent. On the other hand, increasing nitrogen percent from 10% to 25% at $430^{\circ}C$ decreases corrosion resistance although it increases the surface hardness and the thickness of S phase layer. Therefore, optimized condition was selected as nitriding temperature of $430^{\circ}C$ with 10% nitrogen, as at this condition, the treated sample showed better corrosion resistance. Moreover to further increase the thickness of S phase layer and surface hardness without compromising the corrosion behavior, further research was conducted by fixing the $N_2$ content at 10% with introducing various amount of $CH_4$ content from 0% to 5% in the nitriding atmosphere. The best treatment condition was determined as 10% $N_2$ and 5% $CH_4$ content at $430^{\circ}C$, where the thickness of S phase layer of about $17{\mu}m$ and a surface hardness of $980HV_{0.1}$ were obtained (before treatment $250HV_{0.1}$ hardness). This specimen also showed much higher pitting potential, i.e. better corrosion resistance, than specimens treated at different process conditions and the untreated one.

• Corrosion Science and Technology
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• v.3 no.2
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• pp.47-53
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• 2004

The conditions to simulate the atmospheric corrosion behavior in the laboratory were investigated to clarify atmospheric corrosion mechanism of steel material in coastal area, For airborne sea salt and artificial seawater droplet, the various behaviors were observed by optical microscope, The particle size of the dried airborne sea salt was about $20{\mu}m$, and was about 1/10 compared with the artificial seawater droplet. Though the airborne sea salt represented the same behavior as the thermodynamic water absorption, the behavior of the artificial seawater droplet deviated from the results of the thermodynamic calculation, It is concluded that the water absorption behavior is influenced by the particle size of the dried sea salt. The corrosion behaviors of carbon steels were observed under the deposited condition of airborne sea salt and artificial seawater droplet. The corrosion behaviors showed a different trend, indicating that the corrosion behavior depended on the particle size of the dried sea salt. The corrosion in the actual environrnent progressed greater than that in the chamber. Furthermore, the summer showed the greater corrosion than the spring. It is found that the corrosion behaviors are attributed to the influence of the environmental factors.

• Corrosion Science and Technology
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• v.12 no.2
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• pp.85-92
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• 2013

This work is concerned with an evaluation of dynamic boric acid corrosion (BAC) of low alloy steel for reactor pressure vessel of a pressurized water reactor (PWR). Mockup test method was newly established to investigate dynamic BAC of the low alloy steel under various conditions simulating a primary water leakage incident. The average corrosion rate was measured from the weight loss of the low alloy steel specimen, and the maximum corrosion rate was obtained by the surface profilometry after the mockup test. The corrosion rates increased with the rise of the leakage rate of the primary water containing boric acid, and the presence of oxygen dissolved in the primary water also accelerated the corrosion. From the specimen surface analysis, it was found that typical flow-accelerated corrosion and jet-impingement occurred under two-phase fluid of water droplet and steam environment. The maximum corrosion rate was determined as 5.97 mm/year at the leakage rate of 20 cc/min of the primary water with a saturated content of oxygen within the range of experimental condition of this work.

• Corrosion Science and Technology
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• v.9 no.1
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• pp.39-47
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• 2010

Galvanic coupling between GECM(graphite epoxy composite material) and metallic materials can facilitate corrosion of metals and alloys because GECM is noble and electrically conductive. Galvanic corrosion is affected by many factors including metallic materials, area ratio, surface condition, and corrosivity. This work aims to evaluate the effect of area ratio on galvanic corrosion between GECM and several metals. In the case of glavanic coupling of carbon steel and Al to GECM, corrosion rate increased with increasing area ratio. Corrosion rate of sensitized STS 316S stainless steel decreased a little at an area ratio 1:1 but increased at an area ratio 30:1. It is considered to be due to that area ratio affects galvanic corrosion more in less corrosion resistant alloys. However, in case of STS 316 and Ti, galvanic coupling reduces corrosion rate by the formation of passive film.

• Corrosion Science and Technology
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• v.16 no.2
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• pp.59-63
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• 2017

Chelating solutions can be damaged by strong acids during oil production. To design effective corrosion inhibitors and other alternatives for corrosion control, it is important to understand not only the behavior of the system under operating condition but also the kinetics of electrochemical reactions during the corrosion process. In this study, the electrochemical behaviors of P-110 steel in aqueous fluids based on ethylenediaminetetraacetic acid (EDTA) compounds under various temperatures and hydrodynamic regime conditions were assessed. Electrochemical measurements were conducted using rotating disc electrodes manufactured. Electrolytes were prepared using aqueous compounds of EDTA like diammonium salt, disodium salt, and tetrasodium salt. Potentiodynamic polarization, electrochemical impedance, and mass loss tests were performed in order to assess the corrosion kinetic in electrolytes. Hydrodynamic effects were observed only in the cathodic polarization curve. This proves that hydrodynamic regime plays an important role in the corrosion of steel mainly in disodium and diammonium EDTA solutions. Two cathodic reactions controlled the corrosion process. However, oxygen level and pH of the electrolyte played the most important role in metal corrosion. Corrosion rates in those fluids were decreased drastically when oxygen concentration was reduced.

• Computers and Concrete
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• v.18 no.1
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• pp.69-97
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• 2016

Performance-based remaining life assessment of reinforced concrete bridge girders, subject to chloride-induced corrosion of reinforcement, is addressed in this paper. Towards this, a methodology that takes into consideration the human judgmental aspects in expert decision making regarding condition state assessment is proposed. The condition of the bridge girder is specified by the assignment of a condition state from a set of predefined condition states, considering both serviceability- and ultimate- limit states, and, the performance of the bridge girder is described using performability measure. A non-homogeneous Markov chain is used for modelling the stochastic evolution of condition state of the bridge girder with time. The thinking process of the expert in condition state assessment is modelled within a probabilistic framework using Brunswikian theory and probabilistic mental models. The remaining life is determined as the time over which the performance of the girder is above the required performance level. The usefulness of the methodology is illustrated through the remaining life assessment of a reinforced concrete T-beam bridge girder.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.361-366
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• 2002

The deterioration of concrete structure due to corrosion of the reinforcement has created big financial losses on the overall industries. The volume expansion of the corrosion products causes internal pressure to concrete wall around reinforcing bar. If the maximum principal stress induced by internal pressure exceeds the tensile strength of the concrete at any point of time, a crack forms at any point of material. Therefore, in terms of life assessment of concrete structure, it is very important to predict the amount of corrosion products which induces initial concrete cracking. With this objective, this paper proposes the critical amount of corrosion products at interface between reinforcement and concrete using finite element analysis. If an actual survey of corrosion rates could be made, the model might supply information for condition assessment of existing concrete structure. As the mechanical properties of corrosion product and instantaneous geometry of corroded steel are considered in the analysis, the value obtained will be more realistic.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.8
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• pp.1286-1290
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• 2004

This paper describes the anti-corrosion system on underwater structures of ships. Metals and alloys have several positions in the series such as immunity, corrosion and passivity. The iron potential has to change from the corrosion position to the anodic protection or cathodic protection for preventing corrosion by providing corrosion protection system such as ICCP(Impressed Current Cathodic Protection). The purpose of ICCP system is to eliminate the rusting or corrosion, which occurs on metal immersed in water. The system includes a power supply unit, which consists of a transformer, a converter. a controller, etc. This paper presents the protection performance of ICCP under dynamic condition such as velocity. The variation of potential and current density with time and environment factors are also described Finally, the experimental results will be explained and analysed.

• Journal of the Korean institute of surface engineering
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• v.40 no.5
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• pp.219-224
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• 2007

The corrosion characteristics of Fe-18Cr-10Ni steels were studied between $600^{\circ}C$ and $1000^{\circ}C$ in Ar+(0.2, 1)%$SG_2$ gas for up to 300 hr in order to employ Fe-18Cr-10Ni steels in the coal-fired power plants. The corrosion resistance of Fe-18Cr-10Ni steels was good due mainly to the high amount of Cr, which formed $Cr_2O_3$ from the initial corrosion stage. Fe in the steels corroded to mainly $Fe_2O_3$ and $Fe_3O_4$. Ni was not susceptible to corrosion under the current corrosion condition. Relatively thin, single-layered scales formed.