• Title/Summary/Keyword: Corrosion potential

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A Study on the Corrosion Monitoring of Multi-functional Sensors for Reinforced Concrete Structures: Part 1 (철근 콘크리트 구조물용 다기능 멀티센서의 부식 모니터링에 관한 연구: Part 1)

  • Jin, Chung-Kuk;Jeong, Jin-A;Kyoung, Eun-Jin
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.270-274
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    • 2012
  • This study represents the result of corrosion monitoring on reinforced concrete specimens by means of multi-functional corrosion monitoring sensors. To confirm the effectiveness of the sensors, eight different kinds of condition were adopted. Test factors were corrosion potential, current, corrosion rate, resistivity, and temperature, which were monitored with the sensors. Through this study, judging corrosion of steel in concrete with single corrosion factor such as corrosion potential was difficult, because many other factors can have an influence on the reaction of corrosion. By using three different kinds of sensors, it could enhance the accuracy of corrosion monitoring.

Effect of the Specific Resistance of Water on Corrosion Characteristics of STS 304 for Gas Boiler (가스보일러용 STS 304의 부식특성에 미치는 용수의 비저항의 영향)

  • Lim, Uh-Joh;Kim, Hwan-Sik;Yun, Byoung-Du
    • Journal of Fisheries and Marine Sciences Education
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    • v.19 no.3
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    • pp.323-328
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    • 2007
  • This paper was studied on the effect of the specific resistance of water on corrosion characteristics of STS 304 for gas boiler. The electrochemical polarization test of STS 304 for gas boiler was carried out. And the polarization resistance, uniform corrosion, corrosion behavior by impressed potential and corrosion sensitivity of STS 304 with specific resistance were considered. The main results are as following: 1) With being low the specific resistance of water, the polarization resistance and corrosion potential of STS 304 decreases, while corrosion current density increases. 2) Under constant impressed potential, the corrosion sensitivity of STS 304 is large with being low the specific resistance due to synergy effect of Cl ion.

Effect of ICCP Potential with Electrolyte on Corrosion and Discolor of Silver (은의 부식 및 변식에 미치는 전해질 용액에 따른 ICCP 전압의 영향)

  • Shin, Byung-Hyun;Kim, Do-Hyung;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.53 no.5
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    • pp.207-212
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    • 2020
  • Silver is an inexpensive precious metal and is used in various jewelry in Asia. Although silver has high potential, it has corrosion resistance that is vulnerable to boiling sulfuric acid and nitric acid. So, silver research is needed to prevent the corrosion with environment. But silver corrosion is not studied. sulfuric acid make the uniform corrosion and chloride ion make the pitting corrosion. ICCP inhibits the corrosion because it offset electrons. This study used a potential from - 4 V to 4 V to check the effect of potential. Corrosion rate is lowet at -1 V.

Electrochemical Random Signal Analysis during Localized Corrosion of Anodized 1100 Aluminum Alloy in Chloride Environments

  • Sakairi, M.;Shimoyama, Y.;Nagasawa, D.
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.168-172
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    • 2008
  • A new type of electrochemical random signal (electrochemical noise) analysis technique was applied to localized corrosion of anodic oxide film formed 1100 aluminum alloy in $0.5kmol/m^3$ $H_3BO_4/0.05kmol/m^3$ $Na_2B_4O_7$ with $0.01kmol/m^3$ NaCl. The effect of anodic oxide film structure, barrier type, porous type, and composite type on galvanic corrosion resistance was also examined. Before localized corrosion started, incubation period for pitting corrosion, both current and potential slightly change as initial value with time. The incubation period of porous type anodic oxide specimens are longer than that of barrier type anodic oxide specimens. While pitting corrosion, the current and potential were changed with fluctuations and the potential and the current fluctuations show a good correlation. The records of the current and potential were processed by calculating the power spectrum density (PSD) by the Fast Fourier Transform (FFT) method. The potential and current PSD decrease with increasing frequency, and the slopes are steeper than or equal to minus one (-1). This technique allows observation of electrochemical impedance changes during localized corrosion.

An Electrochemical Property Stud on the Corrosion Behavior of Welding Part of RE36 Steel for Marine Structure (해양구조물용 RE36강의 용접부 부식거동에 관한 전기화학적 특성 연구)

  • 김성종;김진경;문경만
    • Journal of Welding and Joining
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    • v.18 no.5
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    • pp.70-76
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    • 2000
  • The effect of Post Weld Heat Treatment(PWHT) of RE36 steel for marine structure was investigated with parameters such as micro-vickers hardness, corrosion potential and corrosion current density of weld metal(WM), base metal(BM) and heat affected zone(HAZ), and both Al alloy anode generating current and Al alloy anode weight loss quantity etc. Hardness of post-weld heat treated BM, WM and HAZ is lower than that of As-welded condition of each region. However, hardness of HAZ was the highest among those three parts regardless of PWHT temperature and corrosion potential of WM was the highest among those three parts without regard to temperature and corrosion potential of WM was the highest among those three parts without regard to PWHT temperature. The amplitude of corrosion potential difference of each other three parts at PWHT temperature $550^{\circ}C$, $650^{\circ}C$ are smaller than that of three parts by As-welded condition and corrosion current density obtained by PWHT was also smaller than that of As-welded condition. Eventually, it was known that corrosion resistance was increased by PWHT. However both Al anode generating current and anode weight loss quantity were also decreased by PWHT compare to As-welded condition when RE36 steel is cathodically protected by Al anode. Therefore, it is suggested that the optimum PWHT temperature with increasing corrosion resistance and cathodic protection effect is $550^{\circ}C$.

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The Effect of Shot Peening on the Corrosion and Fatigue Crack to SAE5155 Steel (SAE 5155강에서 쇼트피닝이 부식과 피로균열특성에 미치는 영향)

  • Park, Kyeong-Dong;Shin, Yung-Jin;Kim, Dong-Ug
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.6
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    • pp.731-739
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    • 2006
  • Corrosion and lassitude are very important in the metal construction Currently, the shot peening is used much for removing the defect on the surface, improving the fatigue strength on surface. In this study. the influence of shot peening to the corrosion property were investigated in 3.5% NaCl, 10% HNO3 + 3% HF. 6% FeC13. The immersion test was performed on two kind of specimen(Removed corrosion product. RCP and Continuous immersed specimen: CIS). The immersion periods was 3600hours. Corrosion potential. weight loss, and fatigue crack growth characteristics were investigated. The result, shot peening in corrosion potential showed stable potential. Also, shot peening displayed small Weight loss than un peening. And Fatigue crack resistivity of shot peening in corrosion solution's fatigue crack appeared greatly than un peening.

Anti-corrosive Effects of Multi-Walled Carbon Nano Tube and Zinc Particle Shapes on Zinc Ethyl Silicate Coated Carbon Steel

  • Jang, JiMan;Shon, MinYoung;Kwak, SamTak
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.1-5
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    • 2016
  • Zinc ethyl silicate coatings containing multi walled carbon nanotubes (MWCNTs) were prepared, to which we added spherical and flake shaped zinc particles. The anti-corrosive effects of MWCNTs and zinc shapes on the zinc ethyl silicate coated carbon steel was examined, using electrochemical impedance spectroscopy and corrosion potential measurement. The results of EIS and corrosion potential measurement showed that the zinc ethyl silicate coated with flake shaped zinc particles and MWCNT showed lesser protection to corrosion. These outcomes were in agreement with previous results of corrosion potential and corrosion occurrence.

Electrochemical Analysis of the Microbiologically Influenced Corrosion of Steels by Sulfate-Reducing Bacteria

  • Moon, Kyung-Man;Lee, Myung-Hoon;Kim, Ki-Joon;Kim, Seong-Jong;Shin, Sung-Kyu;Koh, Sung-Cheol
    • Corrosion Science and Technology
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    • v.3 no.5
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    • pp.187-193
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    • 2004
  • We have investigated the differences between the general corrosion and microbiologically influenced corrosion (MIC) of steels in terms of electrochemical behavior and surface phenomena. Corrosion potential of steels in the absence of SRB (sulfate-reducing bacteria) shifted to a low level and was maintained throughout the experimental period (40 days). The potential in the presence of SRB, however, shifted to a noble level after 20 days' incubation, indicating the growth of SRB biofilms on the test metal specimens and a formation of corrosion products. In addition, the color of medium inoculated with SRB changed from gray to black. The color change appeared to be caused by the formation of pyrites (FeS) as a corrosion product while no significant color change was observed in the medium without SRB inoculation. Moreover, corrosion rates of various steels tested for MIC were higher than those in the absence of SRB. This is probably because SRB were associated with the increasing corrosion rates through increasing cathodic reactions which caused reduction of sulfate to sulfide as well as formation of an oxygen concentration cell. The pitting corrosions were also observed in the SRB-inoculated medium.

Application of the Polarised Potential-pH Diagrams to Investigate the Role of Sulfate and Dissolved Oxygen in the 3550-ppm NaCl Solution on the Corrosion Behaviour of AISI 316L Stainless Steel

  • Chandra-ambhorn, S.;Kumpai, K.;Muangtong, P.;Wachirasiri, W.;Daopiset, S.
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.45-49
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    • 2008
  • The cyclic polarisation technique was applied to determine the corrosion, primary-passivation, transpassive, and protection potential of AISI 316L stainless steels immersed in 3550-ppm NaCl solution containing sulfate in the content up to 3000 ppm. The solutions were kept constant at $27^{\circ}C$ and saturated by laboratory air. The solution pH was varied from 3 to 11. Each type of potentials was plotted in function of pH and linked as lines to determine the different zones in the constructed potential-pH diagram. The predominant regimes of the immunity, general corrosion, perfect passivation, imperfect passivation, and pitting corrosion were determined based on those lines of potentials. Comparing to the potential-pH diagram of specimens immersed in the aerated and deaerated 3550-ppm NaCl solutions, the addition of 3000-ppm $Na_2SO_4$ to these solutions increased the overall, perfect and imperfect, passivation regime by shifting the transpassive-potential line to the noble direction. However, it also widened the imperfect passivation area. The addition of $Na_2SO_4$ did not significantly affect the corrosion potential. It was found that the dissolved oxygen tends to negatively shift the transpassive-potential and protection-potential lines at all studied pH. The considerable effect of dissolved oxygen on corrosion and primary-passivation potentials could not be observed.

The Effect of Shot Peening on Corrosive Behavior of SAE 5155 in $3.5\%$ NaCl Solution ($3.5\%$ NaCl수용액에서 SAE 5155의 부식거동에 미치는 쇼트피닝의 영향)

  • An Jae-Pil;Park Keyung-Dong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.6
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    • pp.692-700
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    • 2005
  • In this study. investigated the effect of shot peening on the corrosion of SAE 5155 steel immersed in $3.5\%$ NaCl solution and corrosion characteristics by the heat treatment during shot peening process. The immersion test was Performed on the four kinds of specimens. Corrosion Potential, polarization curve, residual stress etc. were investigated from experimental results. From these test results, the effect of shot peening on the corrosion was evaluated The important results of the experimental study on the effects of shot peened SAE 5155 on the corrosion are as follows; Shot peened specimens show the low of corrosion current as compared with un peened specimens. In the case of corrosion potential, shot Peened specimen shows more negative Potential as compared with that of parent metal Surface of specimen, which is treated with shot peening Process. is Placed as more activated state against inner parent metal. Corrosion rate is shown that shot Peened specimens have less corrode than un peened specimens. But non heat treated shot peened specimens show the biggest weight loss owing to variable compressive residual stress layer by shot ball.