• Journal of Soil and Groundwater Environment
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• v.17 no.1
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• pp.13-21
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• 2012

This study reports a surfactant-enhanced in-situ remediation treatment at a test site which is located in a hilly terrain. The leakage oils from a storage tank situated on the top of the hill contaminated soils and groundwater in the lower elevation. Sixteen vertical injection wells (11 m deep) were installed at the top of the hill to introduce 0.1-0.5 vol.% of non-ionic Tween-80 surfactant. The contaminated area that required remediation treatment was about $1,650\;m^2$. Two cycles of injecting surfactant solution followed by water were repeated over approximately 7.5 months: first cycle with 0.5 month of surfactant injection followed by 3 months of water injection, and second cycle with 1 month of surfactant followed by 3 months of water injection. The seasonal fluctuation in groundwater table was also considered in the selection of periods for surfactant and water injection. The results showed that the initial Total Petroleum Hydrocarbon (TPH) concentration of 1,041 mg/kg (maximum 3,605 mg/kg) was reduced significantly down to 76.6 mg/kg in average. After 2nd surfactant injection process finished, average TPH concentration of soils was reduced to 7.5% compared to initial concentration. Also, average BTEX concentration of soils was reduced to 10.8%. This resultes show that the surfactant enhanced in-situ remediation processes can be applicable to LNAPL contaminated site in field scale.

• Journal of the Korean Chemical Society
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• v.24 no.5
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• pp.398-403
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• 1980

Carboxyl-terminated polybutadiene was prepared by free-radical polymerization using 4,4'-azobis-[4-cyano valeric acid] as an initiator and the effect of initiator concentration on polymer properties was investigated. Polymerization of the carboxyl-terminated polybutadiene was carried out varying the initiator concentration reacting with a constant butadiene concentration. The carboxyl weight percent decreased with increasing initiator concentration. The conversion was proportional to the square root of initiator concentration, giving a functionality greater than 2.0 which is consistent with the general tendency of free radical polymerization.

• Nuclear Engineering and Technology
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• v.33 no.1
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• pp.83-92
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• 2001

The properties of off-gas generated from vitrification process of ion-exchange resin were characterized. Theoretical composition and flow rate of the off-gas were calculated based on chemical composition of resin and it＇s burning condition inside CCM. The calculated off-gas flow rate was 67.9Nm$^3$/h at the burning rate of 40kg/h. And the composition of off-gas was avaluated as $CO_2$(41.4%), steam(40.0%), $O_2$(13.3%), NO(3.6%), and SO$_2$(1.6%) in order. Then, actual flow rate and composition of off-gas were measured during pilot-scale demonstration tests and the results were compared with theoretical values. The actual flow rate of off-gas was about 1.6 times higher than theoretical one. The difference between theoretical and actual flow rates was caused by the in-leakage of air to the system, and the in-leakage rate was evaluated as 36.3Nm$^3$/h. Because of continuous change in the combustion parameters inside CCM, during demonstration tests, the concentration of toxic gases showed wide fluctuation. However, the concentration of CO, a barometer of incompleteness of combustion inside CCM, was stabilized soon. The result showed quasi-equilibrium state was achieved two hours after feeding of resin.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.1 no.1
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• pp.47-55
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• 1991

Exposure level of respirable coal dust of underground coal mines in Taebaek area was evaluated. Personal air samplers with 10-mm nylone cyclones were attached to the coal workers including drillers, coal cutters, their assistants, haulers, and separators. Log-normality of respirable dust exposure concentration were tested by Kolmogorov-Smirnov one-sample test. Differences of means of respirable dust exposure concentration between work sites were tested by one-way ANOVA test and multiple comparison(Scheffe) test. And differences of respirable dust exposure concentration of principal and assistant workers in drilling sites and in coal faces were tested by paired t-test. Relation of respirable dust exposure concentration for the principal workers and their assistants in drilling sites and in coal faces were tested by regression analysis. The results were as follows : 1. All of the respirable dust concentration were log-normally distributed. 2. There were not only significantly different means of exposure concentration between drillers and coal cutters but between coal cutters and haulers. 3. Means of exposure concentration of drillers and drilling assistants were not significantly different. And means of exposure concentration of coal cutters and coal cutting assistants were not different.

• Journal of Pharmaceutical Investigation
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• v.15 no.1
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• pp.32-39
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• 1985

Bioavailability studies in guinea pigs and dissolution tests of sustained release capsules of ascorbic acid were investigated comparing with those of solution. The results were as follows; 1. In the dissolution test sustained release capsules released 90% of ascorbic acid after 12 hours, and ascorbic acid in the chewable tablet was dissolved. completely within 10 minutes. 2. In the determination of total ascorbic acid concentration in serum, the area under the curve between 0 and 24 hours $(AUC\;0{\sim}24h)$ ana the maximum serum concentration $(C_{max})$ did not show any significant difference between solution and sustained release capsule. The time to the maximum concentration $(C_{max})$ and the time over $50{\mu}g/ml$ concentration showed significant difference. 3. The time reached to maximum excretion rate $(T_{max})$ in sustained release capsule was longer than that of solution.

• Journal of the Korean Institute of Gas
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• v.5 no.3 s.15
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• pp.36-44
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• 2001

In case of low odor level, accident probabilities are very high Otherwise, when the odorant concentration is too high, the deterioration of pipeline and governor facilities and the environmental problems may occur. Odorants fade in the pipeline and other equipment due to physical and chemical adsorption and reactions with odorant and materials. So, it is very important to maintain odorant concentration properly In this study, the current status of odorization technologies has been reviewed. And the characteristics of small odorant system have been analyzed. In case that the small odorant system Is introduced in our country, this paper is proposed the feasible management plan and showed feasibility results through the analysis of current available technology.

• Korean Journal of Pharmacognosy
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• v.36 no.4 s.143
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• pp.273-277
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• 2005

In mammalian melanocytes, melanin synthesis is controlled by tyrosinase, the key enzyme in the pigment synthesis. In this study, to develop a new whitening agent, we have investigated the antioxidant and the inhibitory effect of Artemisia anomala extract on tyrosinase activity and melanigenesis in the B16/F1 melanoma cells. The inhibition ratio of tyrosinase activity of butanol fraction from A. anomala was higher than that of arbutin ($97.5{\pm}0.5%$ at the concentration of 2 mg/ml). The butanol fraction was shown scavenging activities of 1,1-diphenyl-2-picrylhydrazyl (DPPH) radicals and superoxide anion radicals in a dose dependent manner. The highest inhibitory activity of melanogenesis was also butanol fraction ($25.0{\pm}3%$ at the concentration of $200\;{\mu}g/ml$). From these results, we suggest that the A. anomala extract might be used to be a potential agent for skin whitening.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.3
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• pp.233-244
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• 2014

The objective of this study was to explore the characteristics of concentration of indoor air pollutants, such as $PM_{10}$, $CO_2$, and $NO_2$, measured by tele-monitoring system in a Seoul Metropolitan underground railway station from January 1, 2008 to December 31, 2012. The annual average concentration of indoor air pollutants actually varied over a wide range and was found to exhibit marked variation with time and measurement sites (tunnel inlet, platform, and concourse). After installing platform screen doors, the average $PM_{10}$ concentration on platform and concourse was decreased by 43.8% and 31.2%, respectively during the study periods. The relationship between the concentration of $PM_{10}$ and meteorological parameters (relative humidity and rainfall) or the Asian dust events was regarded as statistically significant. The correlations between the number of boarding/alighting passengers and $PM_{10}$, $CO_2$, and $NO_2$ were calculated. A p-value of less than 0.01 was regarded as significant except $NO_2$. The I/O ratio of $PM_{10}$ concentration was elevated after a congested time (about 08:00 am). The average I/O ratios of $NO_2$ were observed in concourse and platform on 03:00 am with $1.76{\pm}0.91$ and $1.50{\pm}0.51$, respectively. The average daily variation of standard excess rate of $PM_{10}$ and $NO_2$ concentration in concourse and platform was investigated. The highest standard excess rate was observed on 21:00 (09:00 pm).

• 대한예방의학회:학술대회논문집
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• 1993.10a
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• pp.199-200
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• 1993

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.4 no.2
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• pp.168-179
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• 1994

In some ceramic industries, worker exposure to dust, crystalline free silica and lead were determined and evaluated. The conclusions are as follows. 1. Crystalline silica in bulk samples was 10.5 % in sanitary ware industry, 9.4 % in tile industry, and 2.1 % in ceramic insulator industry respectively. The free silica content of air filter sample was 8.03 % in table ware industry, 5.59 % in sanitary ware industry, and 1.32 % in ceramic insulator industry. Because silica content in ceramic dust is relatively high, it is should be considered silica as important factor in evaluating for ceramic industry. 2. The silica contents in dust from tile, sanitary ware and table ware industries are above 5%, it should be classified as "Type" 2 dust. 3. The airborne concentration of respirable crystalline silica was $27.9{\mu}g/m^3$ in a sanitary ware factory and $5.8{\mu}g/m^3$ in a ceramic insualtor factory. Three of ten samples sampled the above factories were exceeded the occupational exposure levels, $100{\mu}g/m^3$. 4. Geometric mean(GM) of total dust in 11 factories was $1.00mg/m^3$ and GM of respirable dust concentration in 5 factories was $0.33mg/m^3$. Sanitary ware industry had the highest concentration of total dust, $1.62mg/m^3$ and of respirable dust, $0.88mg/m^3$. 5. Average lead concentration in air was $0.05mg/m^3$ in glazing process of 2 factories manufacturing table ware. Five of ten sample(50%) were exceeded $0.05mg/m^3$. Therefore lead exposure in pottery industry should be considered as important problem.