• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2546-2552
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• 2012

A novel biguanide-functionalized $Fe_3O_4/SiO_2$ magnetite nanoparticle with a core-shell structure was developed for utilization as a heterogeneous organosuperbase in chemical transformations. The structural, surface, and magnetic characteristics of the nanosized catalyst were investigated by various techniques such as transmission electron microscopy (TEM), powder X-ray diffraction (XRD), vibrating sample magnetometry (VSM), elemental analyzer (EA), thermogravimetric analysis (TGA), $N_2$ adsorption-desorption (BET and BJH) and FT-IR. The biguanide-functionalized $Fe_3O_4/SiO_2$ nanoparticles showed a superpara-magnetic property with a saturation magnetization value of 46.7 emu/g, indicating great potential for application in magnetically separation technologies. In application point of view, the prepared catalyst was found to act as an efficient recoverable nanocatalyst in nitroaldol and domino Knoevenagel condensation/Michael addition/cyclization reactions in aqueous media under mild condition. Additionally, the catalyst was reused six times without significant degradation in catalytic activity and performance.

• Journal of Korean Academy of Nursing
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• v.43 no.5
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• pp.669-680
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• 2013

Purpose: This study was done to explore the process of accepting CATs among nurses who experienced CATs in Korea. Methods: Grounded theory methodology was utilized. Data were collected from 10 nurses during individual in-depth interviews. Theoretical sampling was used until the data reached saturation. Data were analyzed using the constant comparative analysis method. Results: The core category emerged as "resolving the doubt and integrating" explaining the process of accepting CATs. The nurses engaged in three stages: need awareness, look for solution and integration. Causal conditions were interest as a nursing intervention and orthodox medical limitations. Context was lack of basis for application and increase in social interest. Strategies were new knowledge acquisition, having a strong will, combined with existing knowledge, and individualized intervention. Intervening conditions were others' eye, exhaustion for nurses and physical environment. Consequences were expanding of the nursing role and improved nurse satisfaction. Conclusion: The results of the study should facilitate application of CATs in nursing practice. To help nurses who are interested in CATs, there is a need for education programs, and further research on CATs.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.1
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• pp.115-126
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• 2001

In this paper, through a series of comparative experiments, effects of two different cure processing methods, cocure and precure, on the mechanical properties of honeycomb core materials for aircraft applications are considered. Mass of moisture accumulated into the closed cells of the sandwich panel specimen from the measured mass of moisture diffused to the full saturation state into the elements(skin, adhesive layer, Nomex honeycomb), consisting the honeycomb sandwich specimen has been calculated. Water reservoir of 70$\^{C}$ was used to have specimens absorb moisture to see the influence of moisture absorbed into sandwich panel on its mechanical properties. For the repair condition holding for 2 hours at 177$\^{C}$(350℉) temperature, a pressure due to the vapor expansion in each cell of the sandwich panel, which may result in the local separation of the interface between laminated skin and the surface of the honeycomb, has been estimated by vapor pressure-temperature relation from the thermodynamic steam table and compared to the pressure from the ideal gas state equation. The bonding strengths of the laminated skins on the flat surface of the Nomex honeycomb have been compared by the flatwise tension test and climbing drum peel test performed at room temperature for dry, wet and wet-repair specimens, respectively.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.58 no.1
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• pp.79-84
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• 2009

In order to increase the capacity of the superconducting fault current limiter(SFCL), the current and voltage grades of the SFCL must be increased. As a method for the increase of the current and voltage grades of the SFCL, we compared the various characteristics between the flux-lock type SFCL "With three superconducting units connected in series and the transformer type SFCL using the transformer with three secondary circuits. One of three superconducting units had not quenched in the flux-lock type SFCL. Therefore, the unbalanced power burden happened because of the voltage difference generated by unbalanced quenching between the superconducting units. In the meantime, the three superconducting units were all quenched in the transformer type SFCL using the transformer, and the voltage difference generated between the superconducting units was decreased. Therefore, the difference of critical characteristics was complemented by distribution of fault current in accordance with the turn's ratio between primary and secondary windings. The unbalanced power burden of the superconducting units was reduced due to flux-share between the superconducting units in the transformer. In conclusion, the capacity increment of the SFCL using a transformer was easier due to equal distribution of voltages generated by simultaneous quench of the superconducting units. We think that the characteristics is improved more because of the decrease of saturation in the iron core if the secondary winding is increased in the SFCL using the transformer.

• Journal of Powder Materials
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• v.10 no.2
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• pp.83-88
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• 2003

Nanocrystalline materials of Ni and Ni-Cu alloy have been synthesized by the pulsed wire evaporation (PWE) method and these abnormal magnetic properties in the magnetic ordered state have been characterized using both VSM and SQUID in the range of high and low magnetic fields. Ni and Ni-Cu particles with an average size of 20 to 80 nm were found to influence magnetic hysterisis behavior and the results of powder neutron diffraction patterns and saturation magnetization curves are shown to indicate the absence of the NiO phase. The shifted hysterisis loop and irreversibility of the magnetization curve in the high field region were observed in the magnetic-ordered state of both Ni and Ni-Cu. The virgin magnetization curve for Ni slightly spillover on the limited hysterisis loop ($\pm$20kOe). This irreversibility in the high field of 50 kOe can be explained by non-col-linear behavior and the existence of the metastable states of the magnetization at the surface layer (or core) of the particle in the applied magnetic field. Immiscible alloy of Cu-Ni was also found to show irreversibility having two different magnetic phases.

• 한국초전도학회:학술대회논문집
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• v.9
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• pp.401-404
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• 1999

본 논문은 고온초전도한류기가 투입된 회로에 사고가 발생했을 경우 사고각에 따른 사고전류의 패턴에 관한 연구이다. 계통에 심각한 영향을 끼치는 이러한 사고전류의 순간 특성을 해석하기 위해 유도형 고온초전도한류기를 직접 제작하였으며 임의로 다른 각도에서 사고를 발생시켜 실험하였다. 임의의 사고각을 위해 triac으로 구성되어있는 위상각제어 및 사고 발생기를 부하와 직렬로 연결하였다. 또한, 순간적으로 큰 사고전류의 유입은 철심을 포화시키기에 충분하며 철심의 포화로 인해 상대투자율이 작아짐으로서 고온초전도한류기의 임피던스가 작게 발생하게 된다. 본 논문에서는 이러한 영향으로 인한 사고전류의 패턴에 관하여 연구하였다.

• Bulletin of the Korean Chemical Society
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• v.32 no.8
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• pp.2531-2536
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• 2011

Ethanol is a prototype molecule used in probing catalytic reactivity of oxide catalysts such as $TiO_2$. In the present study, we adsorbed ethanol on $TiO_2$(001) at room temperature (RT) and the corresponding bonding state of ethanol was systematically studied by x-ray photoemission spectroscopy (XPS) using synchrotron radiation. Especially, we compared $TiO_2$(001) surfaces prepared in ultra-high vacuum (UHV) with different surface treatments such as $Ar^+$-sputtering and oxidation with molecular $O_2$, respectively. We find that the saturation coverage of ethanol at RT varies depending on the amount of reduced surface defects (e.g., $Ti^{3+}$) which are introduced by $Ar^+$-sputtering. We also find that the oxidized $TiO_2$(001) surface has other type of surface defects (not related to Ti 3d state) which can dissociate ethanol for further reaction above 600 K. Our C 1s core level spectra indicate clearly resolved features for the two chemically distinct carbon atoms from ethanol adsorbed on $TiO_2$(001), showing the adsorption of ethanol proceeds without C-C bond dissociation. No other C 1s feature for a possible oxidized intermediate was observed up to the substrate temperature of 650 K.

• Research in Community and Public Health Nursing
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• v.12 no.2
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• pp.317-328
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• 2001

The purposes of this study were to develop the empowerment education program, to describe the experiences of diabetes patient's empowerment process and to develop a theoretical model of the diabetes patient's empowerment process. Method 1. : The development of the empowerment program for the diabetes patients: The strategies of the empowerment education program were enhancement of problem - solving, decision making, self-efficacy, self-control. participation and mutual support. Method 2. : According to the grounded theory methodology of Strauss and Corbin, the qualitative data was collected with in depth interviews and participants observations until its saturation when the 25 consented subjects were participating and interacting with the other subjects in the empowerment education program. Results: With the analysis of the data, 29 categories were generated. The core category generated, which was a central phenomenon of the empowerment process, was named powerlessness. The intervening conditions facilitating or impeding the empowerment process were discovered as supportive systems through the participation of group meeting, problem solving dialogue, and the knowledge deficit of self-care. The action/interaction strategies were developed as the paricipating, dialoguing, questioning, supporting system, self-controlling, self efficacy, enhancing self-esteem. stress relaxing and instillation of hope.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.257-258
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• 2008

The inrush current of a transformer is a high-magnitude and harmonic-rich current generated when the transformer core is driven into saturation during energizing. The inrush current usually leads to undesirable effects, for example potential damage to the transformer, misoperation of a protective relay, and power quality deterioration in the distribution power system. Inrush current reduction is therefore important for power system operation. In this paper, to reduce the inrush current, the insertion resistance of the Superconducting Fault Current Limiter (SFCL) that is connected in series with the transformer in the distribution system is used. This paper implements the SFCL by using the Electromagnetic Transient Program-Restructured Version (EMTP-RV) to model the SFCL in the distribution system. The simulation results show the beneficial effects of the SFCL for reduction of the inrush current.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.756-757
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• 2008

Interior permanent magnet synchronous motor (IPMSM) which has high power density is usually applied to traction motor for hybrid electric vehicle. In order to analyze characteristics of IPMSM, d- and q-axis equivalent circuit analysis is generally used. However, the line current of IPMSM calculated by d- and q-axis equivalent circuit analysis differ from measured value. This error is mainly appeared under the flux weakening control. In order to reduce the error between calculated and measured line current, no-load linkage flux which is calculated with considering saturation of magnetic core and armature reaction is applied to characteristic analysis. The result of line current calculated by the method dealt with in this paper is verified by comparison with experimental results.