• Title/Summary/Keyword: Core polymer distribution

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Numerical Analysis of Mold Deformation Including Plastic Melt Flow During Injection Molding (플라스틱 유동을 고려한 사출성형 충전공정 중 금형의 변형 해석)

  • Jung, Joon Tae;Lee, Bong-Kee
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.7
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    • pp.719-725
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    • 2014
  • In the present study, a numerical analysis of an injection molding process was conducted for predicting the mold deformation considering non-Newtonian flow, heat transfer, and structural behavior. The accurate prediction of mold deformation during the filling stage is important to successfully design and manufacture a precision injection mold. While the local mold deformation can be caused by various factors, a pressure induced by the polymer melt is considered to be one of the most significant ones. In this regard, the numerical simulation considering both the melt filling and the mold deformation was carried out. A mold core for a 2D axisymmetric center-gated disk was used for the demonstration of the present study. The flow behavior inside the mold cavity and temperature distribution were analyzed along with the core displacement. Also, a Taguchi method was employed to investigate the influence of the relevant parameters including flow velocity, mold core temperature, and melt temperature.

Preparation and Characterization of Demineralized Bone Particle Impregnated Poly(L-lactide) Scaffolds

  • Gilson Khang;Park, Chong-Soo;John M. Rhee;Lee, Sang-Jin;Lee, Young-Moo;Park, Myoung-Kyu;Lee, Hai-Bang;Lee, Ilwoo
    • Macromolecular Research
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    • v.9 no.5
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    • pp.267-276
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    • 2001
  • In order to endow with new bioactive functionality from demineralized bone particle (DBP) as natural source to poly(L-lactide) (PLA) synthetic biodegradable polymer, porous DBP/PLA as natural/synthetic composite scaffolds were prepared and compared by means of the emulsion freeze drying and solvent casting/salt leaching methods for the possibility of the application of tissue engineered bone and cartilage. For the emulsion freeze drying method, it was observed that the pore size decreased in the order of 79$\mu\textrm{m}$ (PLA control) > 47$\mu\textrm{m}$ (20% of DBP) > 23 $\mu\textrm{m}$ (40% of DBP) > 15$\mu\textrm{m}$ (80% of DBP). Porosities as well as specific pore areas decreased with increasing the amount of DBR. It can be explained that DBP acts like emulsifier resulting in stabilizing water droplet in emulsion. For the solvent casting/salt leaching method, a uniform distribution of well interconnected pores from the surface to core region were observed the pore size of 80 ∼70 $\mu\textrm{m}$ independent with DBP amount. Porosities as well as specific pore areas also were almost same. For pore size distribution by the mercury intrusion porosimeter analysis between the two methods, the pore size distribution of the emulsion freeze drying method was broader than that of the solvent casting/salt leaching method due to the mechanism of emulsion formation. Scaffolds of PLA alone, DBP/PLA of 40 and 80%, and DBP powder were implanted on the back of athymic nude mouse to observe the effect of DBP on the induction of cells proliferation by hematoxylin and eosin staining for 8 weeks. It was observed that the effect of DBP/PLA scaffolds on bone induction are stronger than PLA scaffolds, even though the bone induction effect of DBP/PLA scaffold might be lowered than only DBP powder, that is to say, in the order of DBP only > DBP/PLA scaffolds of 40 and 80% DBP > PLA scaffolds only for osteoinduction activity. In conclusion, it seems that DBP plays an important role for bone induction in DBP/PLA scaffolds for the application of tissue engineering area.

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Using three-dimensional theory of elasticity for vibration analysis of laminated sectorial plates

  • Liyuan Zhao;Man Wang;Rui Yang;Meng Zhao;Zenghao Song;N. Bohlooli
    • Steel and Composite Structures
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    • v.48 no.1
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    • pp.1-17
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    • 2023
  • The main goal of this paper is to study vibration of damaged core laminated sectorial plates with Functionally graded (FG) face sheets based on three-dimensional theory of elasticity. The structures are made of a damaged isotropic core and two external face sheets. These skins are strengthened at the nanoscale level by randomly oriented Carbon nanotubes (CNTs) and are reinforced at the microscale stage by oriented straight fibers. These reinforcing phases are included in a polymer matrix and a three-phase approach based on the Eshelby-Mori-Tanaka scheme and on the Halpin-Tsai approach, which is developed to compute the overall mechanical properties of the composite material. Three complicated equations of motion for the sectorial plates under consideration are semi-analytically solved by using 2-D differential quadrature method. Using the 2-D differential quadrature method in the r- and z-directions, allows one to deal with sandwich annular sector plate with arbitrary thickness distribution of material properties and also to implement the effects of different boundary conditions of the structure efficiently and in an exact manner. The fast rate of convergence and accuracy of the method are investigated through the different solved examples. The sandwich annular sector plate is assumed to be simply supported in the radial edges while any arbitrary boundary conditions are applied to the other two circular edges including simply supported, clamped and free. Several parametric analyses are carried out to investigate the mechanical behavior of these multi-layered structures depending on the damage features, through-the-thickness distribution and boundary conditions.

[Retraction] Preparation of Methyl methacrylate/styrene Core-shell Latex by Emulsion Polymerization ([논문 철회] 유화중합에 의한 Methyl methacrylate/styrene계 Core-shell 라텍스 입자 제조에 관한 연구)

  • Kang, Don-O;Lee, Nae-Woo;Seul, Soo-Duk;Lee, Sun-Ryong
    • Elastomers and Composites
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    • v.37 no.1
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    • pp.21-30
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    • 2002
  • Core-shell polymers of methyl methacrylate/styrene pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl benzene sulfonate(SDBS) as an emulsifier using ammonium persulfate(APS) as an initiator. The characteristics of these core-shell polymers were evaluated. Core-shell composite latex has the both properties of core and shell components in a particle, where as polymer blonds or copolymers show a combined properties from the physical properties or two homopolymers. This unique behavior of core-shell composite latex can be used in many industrial fields. However, in preparation of core-shell composite latex, several unexpected phenomina are observed, such as, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve the disadvantages, we studied the effects of surfactant concentrations, initiator concentrations, and reaction temperature on the tore-shell structure or PMMA/PSt and PSt/PMMA. Particle size and particle size distribution were measured by using particle size analyzer, and the morphology of the core-shell composite latex was observed by using transmission electron microscope. Glass transition temperature($T_g$) was also measured by using differential scanning calorimeter. To identify the core-shell structure, pH of the composite latex solutions were measured.

Vibration analysis of damaged core laminated curved panels with functionally graded sheets and finite length

  • Zhao, Li-Cai;Chen, Shi-Shuenn;Xu, Yi-Peng;Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.38 no.5
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    • pp.477-496
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    • 2021
  • The main objective of this paper is to study vibration of sandwich open cylindrical panel with damaged core and FG face sheets based on three-dimensional theory of elasticity. The structures are made of a damaged isotropic core and two external face sheets. These skins are strengthened at the nanoscale level by randomly oriented Carbon nanotubes (CNTs) and are reinforced at the microscale stage by oriented straight fibers. These reinforcing phases are included in a polymer matrix and a three-phase approach based on the Eshelby-Mori-Tanaka scheme and on the Halpin-Tsai approach, which is developed to compute the overall mechanical properties of the composite material. Three complicated equations of motion for the panel under consideration are semi-analytically solved by using 2-D differential quadrature method. Several parametric analyses are carried out to investigate the mechanical behavior of these multi-layered structures depending on the damage features, through-the-thickness distribution and boundary conditions. It is seen that for the large amount of power-law index "P", increasing this parameter does not have significant effect on the non-dimensional natural frequency parameters of the FG sandwich curved panel. Results indicate that by increasing the value of isotropic damage parameter "D" up to the unity (fully damaged core) the frequency would tend to become zero. One can dictate the fiber variation profile through the radial direction of the sandwich panel via the amount of "P", "b" and "c" parameters. It should be noticed that with increase of volume fraction of fibers, the frequency parameter of the panels does not increase necessarily, so by considering suitable amounts of power-law index "P" and the parameters "b" and "c", one can get dynamic characteristics similar or better than the isotropic limit case for laminated FG curved panels.

Development of Signal Coupler for Power Line Communication over Medium Voltage Distribution Line (고압 배전선로 전력선 통신 신호결합장치 개발)

  • Lee Jae-Jo;Park Young-Jin;Oh Hui-Myoung;Kim Kwan-Ho;Lee Dae-Young
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.54 no.6
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    • pp.409-416
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    • 2005
  • For broadband high-data-rate power line communication with the allocated frequency bandwidth from 2 to 30 MHz on medium voltage (MV) distribution power lines, a signal coupling unit is developed. The coupling unit is composed of a coupling capacitor for coupling communication signal, a drain coil, and an impedance matching part. The coupling capacitor made of ceramic capacitor is designed for transmission property of better than 1 dB in the frequency range. The drain coil is used for preventing low frequency high voltage from junction of medium voltage power line in case that a coupling capacitor is not working properly any more. Also, using ferrite core, a novel broadband impedance matching transformer is developed. A complete coupling unit with a coupling capacitor, a drain coil, and a matching transformer is housed by polymer for good isolation and distinguishing from high voltage electric facilities. Each is fabricated and its frequency behavior is tested. Finally, complete signal couplers are equipped in a MV PLC test bed and their performance are measured. The measurement shows that the coupling capacitor works excellently.

Physical Properties of Environment-friendly Insulating Composite Materials Using Natural Cellulose as a Core Material (천연섬유질을 심재로 사용한 친환경 복합단열재의 물성)

  • Hwang, Eui-Hwan;Cho, Soung-Jun;Kim, Jin-Man
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.120-127
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    • 2011
  • For the development of the environment-friendly insulating composite materials, natural cellulose (wood chip and sawdust) was used as a core material and activated Hwangtoh was used as a binder. Various specimens were prepared with the water/binder ratio and natural cellulose/binder ratio. The physical properties of these specimens were then investigated through compressive and flexural strength test, absorption test, hot water resistance test, thermal conductivity, measurement of pore distribution and observation of micro-structures using scanning electron microscope (SEM). Results showed that the absorption ratio increased with the increase of natural cellulose/binder ratio but decreased remarkably with the increase of polymer/binder ratio. The compressive and flexural strength development varied appreciably with the increase of water/binder ratio and natural cellulose/binder ratio. On the other hand, thermal conductivity decreased with the increase of natural cellulose/binder ratio and polymer/binder ratio. Through SEM, it was found that activated Hwangtoh that reacted with water formed a hydrate crystal leading to the compact structure and the total pore volume of the specimen using activated Hwangtoh was smaller than that of the non-activated Hwangtoh.

Synthesis and Characterization of Cellulose-Hybrid Polystyrene Nanoparticles by Using Reactive Hydroxypropyl Methylcellulose Phthalate (반응형 히드록시프로필 메틸셀룰로오스 프탈레이트를 이용한 셀룰로오스 혼성 폴리스티렌 나노입자의 합성 및 특성 분석)

  • Cheong In-Woo
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.437-444
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    • 2006
  • Reactive hydroxypropyl methylcellulose phthalate (reactive HPMCP) was synthesized by using a stepwise urethane reaction with isophorone diisocyanate (IPDI) and 2-hydroxyethyl moth acrylate (HEMA). Molecular weight, acid number, and critical micelle concentration (CMC) of the synthesized reactive HPMCP and pristine HPMCP were measured and used as a polymeric surfactant in the emulsion polymerizations of styrene. In the preparation of HPMCP-hybrid poly styrene nanoparticles, 6, 9, 12, 18, and 24 wt% of HPMCPs were introduced, and the maximum rate of polymerization ($R_{p,max}$), the average number of radicals per particle (n), particle size distribution were investigated. In addition, core - shell morphology of the nanoparticles were observed by using TEM and their thermal stabilities were measured by using TGA. Reactive HPMCP showed higher $R_{p,max}$, smaller particle size, larger values of n and gel contents as compared with pristine HPMCP, due to the vinyl groups from HEMA, which can be reacted with styrene oligomers, in the reactive HPMCP.

The Prediction of Phase Morphology of Injection Molded Polymer Blends (사출성형된 고분자 블렌드의 형태학적 상구조 예측)

  • Son, Young-Gon
    • Elastomers and Composites
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    • v.39 no.3
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    • pp.193-208
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    • 2004
  • Morphology of injection molded polymer blend was investigated by experimental and theoretical approach. In experiments, the effects of injection speed and injection temperature on the morphology of injection molded MPPO/Nylon 6 blend were investigated. The morphology distribution across the part thickness was clearly observed in injection molded blend. We could observe several distinct regions across the thickness of molded part: skin layer, subskin layer and core region. The skin layer where the dispersed phase is fine and highly deformed to the flow direction is observed to be located near the part surface. The subskin layer located at inner region of the skin layer also observed. In the subskin layer, the dispersed phase is coarser than that of skin layer and deforms to the flow direction. Based on the experimental results, the calculation scheme to predict the morphology of injection molded polymer blend was suggested. The morphology of injection molded polymer blend could be predicted in corporation with the result of flow analysis obtained from commercial software for injection molding process and the theory of drop behavior under the flow. The suggested calculation scheme could predict the effect of injection conditions on the morphology of injection molded parts.

The Structrual Behavior of Eccentrically Loaded Hybrid FRP-Concrete Composite Columns (편심재하된 하이브리드 FRP-콘크리트 합성 기둥의 구조적 특성)

  • Choi, Jin-Woo;Seo, Su-Hong;Park, Joon-Soek;Joo, Hyung-Joong;Yoon, Soon-Jong
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.4 no.4
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    • pp.1-8
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    • 2013
  • Pile foundations constructed by the fiber reinforced polymer plastic piles have been used in coastal and oceanic regions in many countries. Generally, fiber reinforced polymer plastic piles are consisted of filament winding FRP which is used to wrap the outside of concrete pile to increase the axial load carrying capacity or pultruded FRP which is located in the core concrete to resist the bending moment arising due to eccentric loading. In this paper, the analytical procedures of hybrid concrete filled FRP tube flexural members are suggested based on the CFT design method. Moreover, the analytical results are compared with the experimental results to obtained by the previous researches. The results of comparison analyses are performed to estimate the accuracy of the analytical procedure for hybrid FRP-concrete composite compression test, members under eccentrical loading.