• 한국유기농업학회지
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• 제19권4호
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• pp.529-541
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• 2011

Bordeaux mixture made with each grade of lime and copper sulfate was tested general property and disease control value. Bordeaux mixture was made by composition of each grade of lime (95%, 80%) with each grade of copper sulfate(98.5%, 95%). Phytotoxicity was evaluated to Bordeaux mixture made with each grade of lime and copper sulfate, and then low grade copper sulfate (95%) was more severely in the grapevine leaf. Bordeaux mixture, made with each grade lime and copper sulfate, were tried to evaluate control effects of downy mildew in field. As a result, Bordeaux mixture (95% of lime and 98.5% of copper sulfate, 6-6) applied 5 times at late in June was showed more effective disease control value than any other trials of Bordeaux mixture. There was no difference in nutrient status of petiole each treatment. But fruit characteristics were shown more slightly improved quality.

• 식물병연구
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• 제14권2호
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• pp.102-106
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• 2008

Bacillus subtilis QST713(BS QST713)의 단독, 살균제와 혼합 및 교호처리하여 인삼 점무늬병의 방제효과를 검정하였다. BS QST713를 10일 간격으로 단독으로 처리했을 때, 인삼 점무늬병에 대한 방제가는 83.3%, azoxystrobin, chlorothalonil copper sulfate basic, copper sulfate basic, kresoxim-methyl, difenoconazole, mancozeb 단독 처리구는 $80.4{\sim}83.7%$로 나타났다. BS QST713와 mancozeb를 혼합하여 14일 간격으로 처리하였을 때의 방제가는 83.6%, BS QST713와 azoxystrobin 혼합 처리구는 82.6%이었으나, difenoconazole, kresoxim-methyl, copper sulfate basic 및 chlorothalonil copper sulfate basic와 혼합 처리구는 $61.1{\sim}76.4%$로 방제효과가 약간 감소하였다. 대전에서 BS QST713와 copper sulfate basic를 10일 간격으로 교호처리시 방제가가 85.9%이었으나, 다른 살균제와의 교호처리 시는 $55.5{\sim}78.2%$로 낮아 졌다. 그러나 무주에서 모든 교호처리에서 방제가가 90% 이상으로 나타났다. 이상의 결과에 의하면 BS QST713의 단독, 혼합 및 교호처리는 살균제의 사용량을 줄일 수 있는 방제법으로 이용될 것이다.

• 한국가구학회지
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• 제19권5호
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• pp.358-364
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• 2008

Wood-inorganic material composite (WIC) was prepared by impregnating wood with copper sulfate ($CuSO_4\;5H_2O$) solution and by immersed wood in sodium carbonate($Na_2CO_3$) solution in order to introduce insoluble copper compounds {copper carbonate hydroxide, $CuCO_3\;Cu(OH)_2$} into the wood to give fungicidal effects in treated-wood. The weight percent gains (WPGs) of treated wood reached maximum value by impregnation of 20% copper sulfate solution and immersion in about 15% sodium carbonate solution for 24 hrs. Inorganic substances were present mainly in the lumina and cross-field pitting of tracheides. These substances were proved to be the insoluble copper carbonate hydroxide against water by the energy dispersive X-ray analyzer in conjunction with a scanning electron microscope (SEM-EDXA). The treated specimens showed high preservative effectiveness because the weight losses were hardly occurred by the fungi degradation test.

• 한국초지조사료학회지
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• 제20권4호
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• pp.259-264
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• 2000

오차드그래스의 완숙 종자배양에서 배지 내에 첨가되는 copper의 농도가 캘러스 형성과 식물체 재분화율에 미치는 영향을 조사하였다. 캘러스의 유도는 $2\;mg/{\ell}$의 2,4-D와 $0.1-100\;{\mu}mol$의 copper sulfate를 첨가한 MS 배지를 이용하였으며, 식물체 재분화는 $1\;mg/{\ell}$의 NAA, $5\;mg/{\ell}$의 kinetin 및 $0.1-100\;{\mu}mol$의 copper sulfate가 첨가된 N6 배지를 이용하였다.그 결과, copper의 첨가는 캘러스 형성능력에는 유의성있는 차이를 나타내지 않았으나, copper가 첨가된 배지에서 생성된 캘러스에서 백색이면서 조직이 치밀한 즉, 식물체 재분화에 적합한 캘러스의 비율이 높게 나타났다. 식물체 재분화율은 copper가 첨가된 배지에서 생성된 캘러스가 첨가되지 않은 배지에서 생성된 캘러스보다 높게 나타났으며, 특히 $70\;{\mu}mol$의 copper가 첨가된 백지에서 생성된 캘러스가 대구조에 비해 2.5배 이상 증가된 가장 높은 재분화 능력을 나타내었다. 또한, 캘러스당 재분화된 식물체의 수는 $70\;{\mu}mol$의 copper가 첨가된 배지에서 생성된 캘러스에서 대조구에 비해 2.6배 이상 증가된 것으로 나타났다.

• 식물병과 농업
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• 제5권2호
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• pp.95-99
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• 1999

Chemical control of bacterial canker of kiwifruit caused by Pseudomonas syringae pv. actinidiae was attempted by spraying of streptomycin sulfate ·oxytetracycline WP streptomycin WP streptomycin ·copper hydroxide WP kasugamycin SL kasugamycin·copper oxychloride WP and copper hydroxide WP. The control efficacies of the bactericides were variable depending upon the spraying schedule,. Application of streptomycin WP and streptomycin sulfate·oxytetracycline WP from middle April to early May was found to be the most effective in controlling the bacterial canker. For copper hydroxide WP the spraying from middle January to early February showed the highest control efficacy. Kasugamycin SL was the most effective in controlling the disease by spraying from middle April to early May but it was still relatibvely effective during other spray periods. Foliar application of copper hydroxide WP and copper-antibiotic formulaions after middle April caused severe phytotoxicity. Kasgamycil SL streptomycin WP streptomycin·copper hydroxide WP and copper hydroxide WP were potential bactericides which could substitute streptomycin sulfate·oxytetracycline WP. Selective applications of the bactericides according to their optimum spray time can enhance the control efficacies against bacterial canker of kiwifruit and retard the emergency of resistant strains of P. syringae pv. actinidiae to the bactericides. The optimum spray number of streptomycin sulfate·oxytetracycline WP was 3 times with 15-day-intervals or 4 times with 10-day-intervals. The result suggested that the potential bactericides to bacterial canker of kiwifruit should be also used according to their optimum spray schedules in order to get their highest control efficacies.

• 농약과학회지
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• 제7권2호
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• pp.149-154
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• 2003

Erwinia carotovora subsp. atroseptica 에 의하여 발생하는 감자 흑각병은 국내의 감자생산에 큰 피해를 주고 있다. 감자흑각병에 대하여 효과적인 방제약제를 선발하기 위한 선행 실내시험에서 억제효과가 높은 것으로 보고된 4종의 혼합제 [streptomycin(9.3 ppm) + copper oxide(171.6 ppm)/copper hydroxide(146.3 ppm), streptomycin sulfate(7.0 ppm) + copper oxide(171.6 ppm)/copper hydroxide(146.3 ppm)]와 2 종의 항생제 streptomycin(11.6 ppm)과 streptomycin sulfate(8.75 ppm)에 대한 포장에서의 감자흑각병 방제효과를 조사하였다. 감자 이병 종서에 대한 방제효과 시험결과 streptomycin(81.4 ppm)과 streptomycin sulfate(61.3 ppm) 가 각각 상이한 토양조건에서 높은 방제효과가 나타나, 이들 약제를 이병 종서에 대한 종자소독제로 사용할 수 있는 것으로 확인되었다. 감자 식물체에 대한 방제효과 시험에서는 streptomycin(27.9 ppm)+copper oxide(514.8 ppm) 혼합제와 streptomycin sulfate(21.0 ppm) + copper hydroxide(438.9 ppm) 혼합제가 다른 기상조건에서 높은 방제효과를 나타내었는데, 이들 약제를 경엽 처리제로 사용한다면 감자흑각병 방제에 효과적일 것으로 사료된다.

• 한국재료학회지
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• 제18권3호
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• pp.163-168
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• 2008

The morphology of three-dimensional (3D) cross-linked electrodeposits of copper and tin was investigated as a function of the content of metal sulfate and acetic acid in a deposition bath. The composition of copper sulfate had little effect on the overall copper network structure, whereas that of tin sulfate produced significant differences in the tin network structure. The effect of the metal sulfate content on the copper and tin network is discussed in terms of whether or not hydrogen evolution occurs on electrodeposits. In addition, the hydrophobic additive, i.e., acetic acid, which suppresses the coalescence of evolved hydrogen bubbles and thereby makes the pore size controllable, proved to be detrimental to the formation of a well-defined network structure. This led to a non-uniform or discontinuous copper network. This implies that acetic acid critically retards the electrodeposition of copper.

• 대한임상독성학회지
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• 제13권1호
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• pp.36-39
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• 2015

Copper sulfate is a copper compound used widely in the chemical and agriculture industries. Most intoxication occurs in developing countries of Southeast Asia particularly India, but rarely occurs in Western countries. The early symptoms of intoxication are nausea, vomiting, diarrhea, and abdominal cramps, and the most distinguishable clue is bluish vomiting. The clinical signs of copper sulfate intoxication can vary according to the amount ingested. A 75-year old man came to our emergency room because he had taken approximately 250 ml copper sulfate per oral. His Glasgow Coma Scale (GCS) score was 14 and vital signs were blood pressure 173/111 mmHg, pulse rate 24 bpm, respiration rate 24 bpm, and body temperature $36.1^{\circ}$ .... Arterial blood gas analysis (ABGa) showed mild hypoxemia and just improved after 2 L/min oxygen supply via nasal cannula. Other laboratory tests and chest CT scan showed no clinical significance. Three hours later, the patient's mental status showed sudden deterioration (GCS 11), and ABGa showed hypercarbia. He was arrested and his spontaneous circulation returned after 8 minutes CPR. However, 22 minutes later, he was arrested again and returned after 3 minutes CPR. The family did not want additional resuscitation, so that he died 5 hours after ED visit. In my knowledge, early deaths are the consequence of shock, while late mortality is related to renal and hepatic failure. However, as this case shows, consideration of early definite airway preservation is reasonable in a case of supposed copper sulfate intoxication, because the patients can show rapid deterioration even when serious clinical manifestation are not presented initially.

• 한국염색가공학회지
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• 제7권1호
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• pp.72-79
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• 1995

The effect of copper sulfate/thiourea on the diffusion and the dye exhaustion of two dyes, C. I. Acid Orange 7 and C. I. Food Yellow 3 in nylon 6 fiber has been studied. The results obtained from the experimetal are as follows : 1) Copper sulfate reacted with thiourea at constant temperature and then generated the colorless trasparent coordination compound, and then combinated end group of carboxyl of nylon 6 fiber. 2) The coordination compound [$Cu_{2}$($TU_{6}$)] ($(SO_{4})_2$) is conducted at pH 5-6 in solution intensity and repulsed the sulfonic acid group of dyes, and therefore the diffusion of dyes is restraint. 3) Dye uptake and diffusion coefficient were decreased in the order of untreated > copper sulfate/thiourea-treated > tannin-treated.

• 한국가축번식학회지
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• 제25권1호
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• pp.35-42
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• 2001

본 연구는 Cu중독이 rat의 생리현상에 미치는 영향을 구명하고자 연속적인 Cu투여가 사료와 물섭취량, 증체량, 혈액치 및 장기내 무기물 잔류수준의 변동을 측정하였다. 1. 황산Cu 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 사료섭취량은 정상대조군에 비해 점차 감소하였고 용량이 증가할수록 사료 섭취량은 유의하게 감소하였다. 2. 황산Cu 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 음수량은 정상대조군에 비해 점차 감소하였고 황산Cu 용량이 증가할수록 음수량은 감소하는 경향을 나타냈으나 유의한 변화는 인정되지 않았다. 3, 황산Cu 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 증체량은 정상대조군에 비해 약간의 감소를 나타냈으나 황산Cu용량이 증가할수록 증체량은 점차 감소하였다. 4. 황산Cu 1,000, 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 정상대조군에 비해 혈액치중 RBC 및 WBC치는 유의한 증가경향을 나타냈고, Hb량과 PCV치는 약간 감소하는 경향을 나타냈다. 한편, PLT치는 정상대조군에 비해 유의한 증가경향을 나타냈다. 5. 황산Cu 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 간내 Cu, Mn, Fe, Pb 및 Zn의 잔류함량은 정상대조군에 유의한 증가를 나타냈다. 황산Cu 2,000 및 4,000 ppm/kg을 rat에 투여했을 때 신장내 Cu의 함량은 대조군에 비해 감소하였고, Mn, Fe, Pb, Zn의 함량은 정상 대조군에 비해 증가를 나타냈다.