• Title/Summary/Keyword: Copper - red

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Studies on the Natural Dyes(11) -Dyeing Properties of Cochineal Colors for Wool Fibers- (천연염료에 관한 연구(11) -코치닐 색소의 양모섬유 염색성-)

  • 조경래
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.39-49
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    • 1999
  • In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

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Heavy Metal Concentrations in Three Shorebird Species in Saemankeum Mudflat, Korea (대한민국 새만금 갯벌지역에 도래하는 도요류 3종의 중금속 농도)

  • Lee, Hwa-Su;Kim, Jung-Soo;Koo, Tae-Hoe
    • Korean Journal of Environment and Ecology
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    • v.22 no.3
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    • pp.241-248
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    • 2008
  • We studied concentrations of trace elements such as iron, zinc, copper, lead and cadmium in three shorebird species from Saemankeum mudflat, Korea$(1999{\sim}2000)$, and also analysed correlations between elements in livers. Iron(ANOVA, p=0.018), copper(ANOVA, p=0.043), lead(ANOVA, p=<0.001) and cadmium (ANOVA, p=0.016) concentrations significantly differed among shorebird species, but zinc concentrations wasn't different among species. We suggested that iron, zinc, and copper concentrations were within a range for normal and are maintained by normal homeostatic mechanisms for wild birds. Lead concentrations in Great Knots Calidris tenuirostris$(5.76{\pm}2.14{\mu}g/dry\;g)$ were at the background level but Red-necked Stints Calidris ruficollis$(29.4{\pm}10.6{\mu}g/dry\;g)$ and Terek Sandpipers Xenus sinereus$(15.9{\pm}11.9{\mu}g/dry\;g)$ were within the exposed level for wild birds. In particular, Red-necked Stints were nearly poisoned level. Cadmium concentrations in Terek Sandpipers and Great Knots were at the background concentration, but Red-necked Stints were greater than the poisoned level$(3{\mu}g/dry\;g)$. We found significantly correlations between lead and cadmium concentrations, but other elements didn't find.

Envrionment-Friendly Effects of Espil and Copper Hydroxide for Prevention of Powdery Mildew on Cucumber, Tomato, and Red Pepper (에스필과 수산화동 혼용에 의한 오이, 토마토, 고추 흰가루병의 친환경 방제 효과)

  • Soh, Jae-Woo;Han, Kyung-Sook;Lee, Seong-Chan;Lee, Jung-Sup;Park, Jong-Han
    • Research in Plant Disease
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    • v.20 no.2
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    • pp.95-100
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    • 2014
  • This research was performed to examine the effects of mixed espil and copper hydroxide for powdery mildew prevention on cucumber, tomato and pepper. On prevention effect for powdery mildew on cucumber, results revealed that mixed espil and copper hydroxide with a ratio of 4 : 1, disease incidence rate was 18.9% and prevention effect was 69.9%. Another treatment with a ratio of 8 : 1 showed an disease incidence rate of 18.1% and prevention effect of 71.1%, thus, showed great effectiveness. For powdery mildew on tomato, espil and copper hydroxide were mixed using the ratio 4 : 1, results showed an disease incidence rate of 12.4% and prevention effect of 85.3%. Treatment using the ratio of 8 : 1, results showed an disease incidence rate of 14.3% and prevention effect of 83.0%, thus, showed great effectiveness. For powdery mildew on redpepper, espil and copper hydroxide were mixed using the ratio of 4 : 1 with results showed disease incidence rate of 17.7% and prevention effect of 83.0%. From the results, this treatment is the most effective with the lowest attack rate and highest prevention effect. Deducing from the study, it was found out that using mixed espil and copper hydroxide using the ratios 4 : 1 or 8 : 1 are the most effective method for powdery mildew prevention. Mixed ratio of 4 : 1 or 8 : 1 was most effective for preventing powdery mildew on cucumber and tomato, while the espil and copper hydroxide ratio of 4 : 1 was the most effective method for powdery mildew prevention on pepper.

Dyeing of Silk Fabrics by Cochineal Extracts (코치닐 추출물에 의한 견섬유 염색)

  • 한명희
    • Textile Coloration and Finishing
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    • v.12 no.2
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    • pp.129-137
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    • 2000
  • Silk fabrics were dyed by Cochineal extracts after mordanted with various mordants and their properties of dyeing, fastness and change of surface color were investigated. Silk fabrics were mordanted with aluminum potassium sulfate, copper acetate, tin chloride, iron sulfate or chromium potassium sulfate at $60^\circ{C}$ for 30 minutes and subsequently dyed at $60^\circ{C}$ for 60 minutes unless mentioned otherwise. The dye-uptake of silk fabrics increased with the concentration of Cochineal extracts and mordants used. Maximum dye-uptake was obtained at pH 3.5-4, regardless of the type of mordants used. Surface color of silk fabrics changed from red purple to purple when mordanted with Al or Cu mordant, from purple to purple blue with Fe mordant and showed red purple with Sn or Cr mordant, respectively. It also changed according to pH of dyeing bath. Dyed silk fabrics showed poor light fastness but good dry-cleaning, perspiration and rubbing fastness.

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Coating formation of water supply pipes by inhibitor and water quality improvement effect (부식억제제에 의한 상수도관의 피막 형성 및 수질개선 효과)

  • Lim, Jae-Cheol;Kim, Jin-Keun;Koo, Ja-Yong
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.97-106
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    • 2012
  • To investigate the application of corrosion inhibitor on water supply pipes, turbidity, magnitude of corrosion, composition of scale and concentration of metals from an old steel pipe were analysed under inhibitor addition. The concentration of turbidity, iron and copper from the pipes under inhibitor application was 12 ~ 14% of the case which no inhibitor was applied, which suggests the application of inhibitor was very effective for internal corrosion control. In addition, SEM, EDX, XRD and XRF test results showed that application of inhibitor was effective for the decrease of iron concentration and increase of oxygen, phosphorus and calcium concentration, which suggested the existence of protective layer. Therefore, the occurrence of red water will be significantly decreased when inhibitor was applied to the old steel pipes.

Thin Film Effects on Side Channel Signals (부 채널 신호에 대한 박막의 영향)

  • Sun, Y.B.
    • Journal of the Semiconductor & Display Technology
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    • v.12 no.2
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    • pp.51-56
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    • 2013
  • Even if transmissions through normal channel between ubiquitous devices and terminal readers are encrypted, any extra sources of information retrieved from encrypting module can be exploited to figure out the key parameters, so called side channel attack. Since side channel attacks are based on statistical methods, making side channel signal weak or complex is the proper solution to prevent the attack. Among many countermeasures, shielding the electromagnetic signal and adding noise to the EM signal were examined by applying different thicknesses of thin films of ferroelectric (BTO) and conductors (copper and gold). As a test vehicle, chip antenna was utilized to see the change in radiation characteristics: return loss and gain. As a result, the ferroelectric BTO showed no recognizable effect on both shielding and adding noise. Cu thin film showed increasing shielding effect with thickness. Nanometer Au exhibited possibility in adding noise by widening of bandwidth and red shifting of resonating frequencies.

Effect of Neonicochid Type Wood Preservative on Adhesive Properties of Resorcinol Resin for Lminated Wood (네오니코치드계 목재보존제가 집성재 제조용 레조르시놀 수지의 접착력에 미치는 영향)

  • Lee, Dong Heub;Lee, Jong Shin
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.1
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    • pp.34-40
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    • 2014
  • The effect of neonicochid type wood preservatives on adhesive properties of resorcinol-formaldehyde resin for laminated wood manufacture was examined. By the previous studies, it was verified that the neonicochid type preservative has a high termite-proofing and anti-mold effectiveness. Commercial ACQ (ammoniacal copper quaternary compounds) and CUAZ (copper azol compounds) were used as comparison preservatives of effects on adhesive properties. The wood specimens used japanese red pine (Pinus densifrora) after application with preservatives and then bonded with resorcinol-formaldehyde resin. Adhesive properties were evaluated by shearing strength of adhesive bond and wood failure to dry condition or after accelerated aging test. Of all laminated woods, the wood specimens spread with ACQ or CUAZ showed the lowest shearing strength of adhesive bond. We estimated that the decrease of shearing strength was caused by copper in the ACQ or CUAZ preservatives. On the application of the neonicochid type preservatives, the wood specimens showed the highest shearing strength even after accelerated aging test. From these results, it is concluded that the copper-free neonicochid type preservative not affected the curing of resorcinol-formaldehyde resin.

Comparisons on Relative Growth of Red Pine, Black Pine and Pitch Pine by Means of Multiple Regression (다중회귀분석법에 의한 소나무, 곰솔 및 리기다소나무의 상대성장 비교)

  • Park, Man-Choon;Lee, Yun-Keun;Choi, Kee-Ryong
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.305-312
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    • 2010
  • The purpose of this study is to compare the relative growth of annual ring width of red pine(Pinus densiflora), black pine(Pinus thunbergii) and pitch pine(Pinus rigida) by means of multiple regression method according to Graybill hypothesis. The obtained results are as follows. 1. The changes of rainfall have affected to tree growth during the periods of 1975 through 1978. 2. Among these pine trees, red pine was mostly influenced by environmental factors. 3. The growth of annual ring width was sensitively responded to the changes of rainfall and air temperature. 4. Among the heavy metals analyzed, the concentrations(ppm) of Lead(Pb) and Copper(Cu) were negatively effected on the growth of annual ring width of pine trees. 5. The analytical technique of annual ring width may be useful for estimation of the pollution in forest areas near industrial complexes.

Protective Activity of the Mixtures of Pine Oil and Copper Hydroxide against Bacterial Spot and Anthracnose on Red Pepper (파인 오일과 수산화동 혼합물에 의한 고추 세균점무늬병과 탄저병의 방제 효과)

  • Soh, Jae-Woo;Han, Kyung-Sook;Lee, Seong-Chan;Lee, Jung-Sup;Park, Jong-Han
    • Research in Plant Disease
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    • v.20 no.3
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    • pp.211-215
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    • 2014
  • This research was performed to examine the protective activities of the mixtures of pine oil and copper hydroxide against bacterial spot and anthracnose on pepper plants. As for bacterial spot, the treatment of pine oil alone displayed high disease incidence (59.6%) and low protective effect (28.9%). In comparison, the treatments of mixtures and copper hydroxide alone showed protective activities of 66.8-76.1%. The mixture of pine oil and copper hydroxide (4:1) suppressed the most effectively bacterial spot on pepper. On the other hand, the mixture of pine oil and copper hydroxide (4:1) also showed the strongest protective effect against pepper anthracnose among the 4 treatments tested; its disease incidence and disease control value were 49.8% and 41.7%, respectively. The other treatments showed low protective activities with control values of 7.4-17.1%. These results suggested that the mixture of pine oil and copper hydroxide (4:1) can be used for the environmental-friendly disease control of bacterial spot and anthracnose on pepper.

Catechins Content and Color Values of Silk Fabrics Dyed with Korean Green Tea Extracts (녹차 염색 견포의 카테킨 함량 및 색상변화)

  • Son, Ji-Hyon;Lee, Myung-Sun;Chun, Tae-Il
    • Textile Coloration and Finishing
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    • v.18 no.1
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    • pp.10-19
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    • 2006
  • Despite several recent attempts to measure the concentration of individual catechins by HPLC, it has not been so easy to separate catechins accurately. The aim of the present work is to provide a proper condition for separating each component of catechins by HPLC analysis, and also to evaluate the experimental variables including color differences, and metal ion contents after dyeing and mordanting. Four kinds of Catechins, (-)-epicatechin(EC), (-)-epicatechin gallate(ECG), (-)-epigallocatechin(EgC), (-)-epigallocatechin gllate(EgCG) were isolated from the residues after dyeing. Catechins in Korean green tea leaves are richer when e tea leaves are younger. Higher concentration of catechins owes it to e way it is processed. The contents of catechins adsorbed in silk fabrics after dyeing were in order of EGCG>ECG>EGC>EC. We have found $68\%$ uptake of EGCG, and 116.8mg of EGCG in the silk fabrics after it was dyed with $1\%$ Korean green tea extracts. The absorbance intensity and K/S values of dyed silk fabrics were increased with dyeing temperature and time. Only the surface color of the silk fabric dyed with green tea extracts was yellowish red, but it changed from yellowish red to red with an increase in the mordant concentration. Post-mordanted silk fabrics with ferrous sulfate changed from yellowish red to red and purple color shade. In a practical evaluation, there is no significant change in color after twenty times of the continuous dry cleaning process. However, post-mordanted fabrics with ferrous sulfate faded the brightness of color after dry cleaning. Dyeing silk fabrics with a Korean tea extract reduced the metal ion contents in the silk fabrics when compared to the untreated silk fabrics. Metal contents in silk fabrics dyed and post-mordanted with $1\%$ each metal solution were 0.194 ppm for Aluminum, 1.601ppm for Copper, and 0.334 ppm for Iron. After the post-mordanting process, the heavy metal ion absorption increased, which was mainly attributed to the catechins and polyphenols in dyed silk fabrics.