• 제목/요약/키워드: Copper - red

검색결과 118건 처리시간 0.027초

천연염료에 관한 연구(11) -코치닐 색소의 양모섬유 염색성- (Studies on the Natural Dyes(11) -Dyeing Properties of Cochineal Colors for Wool Fibers-)

  • 조경래
    • 한국염색가공학회지
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    • 제11권4호
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    • pp.39-49
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    • 1999
  • In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

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대한민국 새만금 갯벌지역에 도래하는 도요류 3종의 중금속 농도 (Heavy Metal Concentrations in Three Shorebird Species in Saemankeum Mudflat, Korea)

  • 이화수;김정수;구태회
    • 한국환경생태학회지
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    • 제22권3호
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    • pp.241-248
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    • 2008
  • 본 연구는 대한민국 서해안 새만금 갯벌지역에서 $1999{\sim}2000$년에 도래한 섭금류 3종의 간에서 철(Fe), 아연(Zn), 구리(Cu), 납(Pb) 그리고 카드뮴(Cd) 농도를 측정하여 비교하고, 각 원소 사이의 상관관계를 분석하였다. 연구결과 철(ANOVA, p=0.018), 구리(ANOVA, p=0.043), 납(ANOVA, p<0.001) 그리고 카드뮴(ANOVA, p=0.016)은 종간에 유의한 차이가 나타났지만 아연에서는 유의한 차이가 나타나지 않았다. 본 연구에서 나타난 철, 아연 그리고 구리와 같은 필수원소는 조류의 체내 신진대사에 필요한 정상범위 내의 농도로 생각된다. 오염원소인 납 농도는 붉은어깨도요 Calidris tenuirostris $(5.76{\pm}2.14{\mu}g/dry\;g)$는 비오염수준이었지만 좀도요 Calidris ruficollis$(29.4{\pm}10.6{\mu}g/dry\;g)$와 뒷부리도요 Xenus sinereus$(15.9{\pm}11.9{\mu}g/dry\;g)$는 오염수준이었으며, 특히 좀도요는 중독수준에 근접하였다. 카드뮴 농도는 뒷부리도요$(0.82{\pm}12{\mu}g/dry\;g)$와 붉은어깨도요$(0.45{\pm}0.53{\mu}g/dry\; g)$는 비오염수준의 농도였으나, 좀도요$(17.5{\pm}22.1{\mu}g/dry\;g)$는 오염기준$(3{\mu}g/dry\;g)$을 초과하였다. 원소간의 상관관계에서는 납과 카드뮴에서만 유의한 관계가 나타났고 (r=0.067, p<0.01), 다른 원소는 상관관계가 나타나지 않았다.

에스필과 수산화동 혼용에 의한 오이, 토마토, 고추 흰가루병의 친환경 방제 효과 (Envrionment-Friendly Effects of Espil and Copper Hydroxide for Prevention of Powdery Mildew on Cucumber, Tomato, and Red Pepper)

  • 소재우;한경숙;이성찬;이중섭;박종한
    • 식물병연구
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    • 제20권2호
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    • pp.95-100
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    • 2014
  • 본 연구는 에스필과 수산화동의 혼용에 의한 오이, 토마토, 고추의 흰가루병에 대한 방제 효과를 구명하고자 수행하였다. 오이 흰가루병에서 에스필과 수산화동의 혼용 처리는 4 : 1 혼용처리구에서 발병엽률 18.9%와 방제효과 69.9%, 8 : 1 혼용 처리구에서 발병엽률 18.1%와 방제효과 71.1%로 가장 효과적이었다. 토마토 흰가루병에서 에스필과 수산화동의 혼용 처리는 4 : 1 혼용 처리구에서 발병엽률 12.4%와 방제효과 85.3%, 8 : 1 혼용 처리구에서 발병엽률 14.3%와 방제효과 83.0%로 가장 효과적이었다. 고추 흰가루병에서 에스필과 수산화동의 혼용 처리는 4 : 1 혼용 처리구에서 발병엽률 17.7%와 방제효과 76.4%로 가장 효과적이었다. 이상의 결과를 종합할 때 에스필과 수산화동 혼용처리에 의한 오이와 토마토 흰가루병에 대한 방제 효과는 4 : 1 혹은 8 : 1 혼용 처리가 가장 효과적이고, 고추 흰가루병에서는 4 : 1 혼용 처리가 가장 효과적인 방제 방법으로 구명되었다.

코치닐 추출물에 의한 견섬유 염색 (Dyeing of Silk Fabrics by Cochineal Extracts)

  • 한명희
    • 한국염색가공학회지
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    • 제12권2호
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    • pp.129-137
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    • 2000
  • Silk fabrics were dyed by Cochineal extracts after mordanted with various mordants and their properties of dyeing, fastness and change of surface color were investigated. Silk fabrics were mordanted with aluminum potassium sulfate, copper acetate, tin chloride, iron sulfate or chromium potassium sulfate at $60^\circ{C}$ for 30 minutes and subsequently dyed at $60^\circ{C}$ for 60 minutes unless mentioned otherwise. The dye-uptake of silk fabrics increased with the concentration of Cochineal extracts and mordants used. Maximum dye-uptake was obtained at pH 3.5-4, regardless of the type of mordants used. Surface color of silk fabrics changed from red purple to purple when mordanted with Al or Cu mordant, from purple to purple blue with Fe mordant and showed red purple with Sn or Cr mordant, respectively. It also changed according to pH of dyeing bath. Dyed silk fabrics showed poor light fastness but good dry-cleaning, perspiration and rubbing fastness.

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부식억제제에 의한 상수도관의 피막 형성 및 수질개선 효과 (Coating formation of water supply pipes by inhibitor and water quality improvement effect)

  • 임재철;김진근;구자용
    • 상하수도학회지
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    • 제26권1호
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    • pp.97-106
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    • 2012
  • To investigate the application of corrosion inhibitor on water supply pipes, turbidity, magnitude of corrosion, composition of scale and concentration of metals from an old steel pipe were analysed under inhibitor addition. The concentration of turbidity, iron and copper from the pipes under inhibitor application was 12 ~ 14% of the case which no inhibitor was applied, which suggests the application of inhibitor was very effective for internal corrosion control. In addition, SEM, EDX, XRD and XRF test results showed that application of inhibitor was effective for the decrease of iron concentration and increase of oxygen, phosphorus and calcium concentration, which suggested the existence of protective layer. Therefore, the occurrence of red water will be significantly decreased when inhibitor was applied to the old steel pipes.

부 채널 신호에 대한 박막의 영향 (Thin Film Effects on Side Channel Signals)

  • 선용빈
    • 반도체디스플레이기술학회지
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    • 제12권2호
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    • pp.51-56
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    • 2013
  • Even if transmissions through normal channel between ubiquitous devices and terminal readers are encrypted, any extra sources of information retrieved from encrypting module can be exploited to figure out the key parameters, so called side channel attack. Since side channel attacks are based on statistical methods, making side channel signal weak or complex is the proper solution to prevent the attack. Among many countermeasures, shielding the electromagnetic signal and adding noise to the EM signal were examined by applying different thicknesses of thin films of ferroelectric (BTO) and conductors (copper and gold). As a test vehicle, chip antenna was utilized to see the change in radiation characteristics: return loss and gain. As a result, the ferroelectric BTO showed no recognizable effect on both shielding and adding noise. Cu thin film showed increasing shielding effect with thickness. Nanometer Au exhibited possibility in adding noise by widening of bandwidth and red shifting of resonating frequencies.

네오니코치드계 목재보존제가 집성재 제조용 레조르시놀 수지의 접착력에 미치는 영향 (Effect of Neonicochid Type Wood Preservative on Adhesive Properties of Resorcinol Resin for Lminated Wood)

  • 이동흡;이종신
    • Journal of the Korean Wood Science and Technology
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    • 제42권1호
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    • pp.34-40
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    • 2014
  • 흰개미 방제 및 방곰팡이 효력이 입증된 저독성 네오티코치드계 목재보존제가 집성재 제조용 레조르시놀계 접착제의 접착력에 미치는 영향을 조사하였다. ACQ, CUAZ, 네오니코치드계 약제를 도포 처리한 다음 건조시킨 소나무 판재를 사용하였으며, 집성 접착 후에 블록 전단시험편을 채취하여 상태 및 촉진 열화 시험 후의 전단접착력과 목파율을 측정하여 비교하였다. ACQ 및 CUAZ 처리 집성재는 무처리 및 네오니코치드계 목재보존제 처리 집성재에 비하여 낮은 전단접착력을 보여 접착력 저하가 인정되었다. 이것은 이들 방부제 중에 함유되어 있는 구리화합물에 기인하는 것으로 판단되었다. 네오니코치드계 목재보존제 처리 집성재는 상태 및 촉진열화 시험 후에도 가장 우수한 전단접착력을 나타내 레조르시놀계 접착제의 접착성능에는 영향을 미치지 않는 것으로 판단하였다.

다중회귀분석법에 의한 소나무, 곰솔 및 리기다소나무의 상대성장 비교 (Comparisons on Relative Growth of Red Pine, Black Pine and Pitch Pine by Means of Multiple Regression)

  • 박만춘;이윤근;최기룡
    • 한국환경과학회지
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    • 제19권3호
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    • pp.305-312
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    • 2010
  • The purpose of this study is to compare the relative growth of annual ring width of red pine(Pinus densiflora), black pine(Pinus thunbergii) and pitch pine(Pinus rigida) by means of multiple regression method according to Graybill hypothesis. The obtained results are as follows. 1. The changes of rainfall have affected to tree growth during the periods of 1975 through 1978. 2. Among these pine trees, red pine was mostly influenced by environmental factors. 3. The growth of annual ring width was sensitively responded to the changes of rainfall and air temperature. 4. Among the heavy metals analyzed, the concentrations(ppm) of Lead(Pb) and Copper(Cu) were negatively effected on the growth of annual ring width of pine trees. 5. The analytical technique of annual ring width may be useful for estimation of the pollution in forest areas near industrial complexes.

파인 오일과 수산화동 혼합물에 의한 고추 세균점무늬병과 탄저병의 방제 효과 (Protective Activity of the Mixtures of Pine Oil and Copper Hydroxide against Bacterial Spot and Anthracnose on Red Pepper)

  • 소재우;한경숙;이성찬;이중섭;박종한
    • 식물병연구
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    • 제20권3호
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    • pp.211-215
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    • 2014
  • 본 연구는 파인 오일과 수산화동의 혼용에 의한 고추의 세균성 점무늬병과 탄저병에 대한 방제 효과를 구명하고자 수행하였다. 세균성 점무늬병에 대한 방제 효과는 파인 오일만 단독 처리한 경우 발병엽률 59.6%와 방제 효과 28.9%로 나타났지만 파인 오일과 수산화동을 4:1로 혼용 처리하였을 때 발병엽률 20.0%와 방제효과 76.1%로 가장 효과적이었다. 탄저병에 대한 방제 효과는 파인 오일만 단독 처리한 경우 발병률 79.1%와 방제 효과 7.4%로 나타났지만 파인 오일과 수산화동을 4:1로 혼용 처리하였을 때 발병률 49.9%와 방제 효과 41.7%로 가장 효과적이었다. 이상의 결과는 고추의 세균성 점무늬병과 탄저병의 발병을 파인 오일과 수산화동을 4:1로 혼용 처리함으로서 친환경적으로 방제할 수 있음을 나타낸다.

녹차 염색 견포의 카테킨 함량 및 색상변화 (Catechins Content and Color Values of Silk Fabrics Dyed with Korean Green Tea Extracts)

  • 손지현;이명선;천태일
    • 한국염색가공학회지
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    • 제18권1호
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    • pp.10-19
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    • 2006
  • Despite several recent attempts to measure the concentration of individual catechins by HPLC, it has not been so easy to separate catechins accurately. The aim of the present work is to provide a proper condition for separating each component of catechins by HPLC analysis, and also to evaluate the experimental variables including color differences, and metal ion contents after dyeing and mordanting. Four kinds of Catechins, (-)-epicatechin(EC), (-)-epicatechin gallate(ECG), (-)-epigallocatechin(EgC), (-)-epigallocatechin gllate(EgCG) were isolated from the residues after dyeing. Catechins in Korean green tea leaves are richer when e tea leaves are younger. Higher concentration of catechins owes it to e way it is processed. The contents of catechins adsorbed in silk fabrics after dyeing were in order of EGCG>ECG>EGC>EC. We have found $68\%$ uptake of EGCG, and 116.8mg of EGCG in the silk fabrics after it was dyed with $1\%$ Korean green tea extracts. The absorbance intensity and K/S values of dyed silk fabrics were increased with dyeing temperature and time. Only the surface color of the silk fabric dyed with green tea extracts was yellowish red, but it changed from yellowish red to red with an increase in the mordant concentration. Post-mordanted silk fabrics with ferrous sulfate changed from yellowish red to red and purple color shade. In a practical evaluation, there is no significant change in color after twenty times of the continuous dry cleaning process. However, post-mordanted fabrics with ferrous sulfate faded the brightness of color after dry cleaning. Dyeing silk fabrics with a Korean tea extract reduced the metal ion contents in the silk fabrics when compared to the untreated silk fabrics. Metal contents in silk fabrics dyed and post-mordanted with $1\%$ each metal solution were 0.194 ppm for Aluminum, 1.601ppm for Copper, and 0.334 ppm for Iron. After the post-mordanting process, the heavy metal ion absorption increased, which was mainly attributed to the catechins and polyphenols in dyed silk fabrics.