• 제목/요약/키워드: Coordination Mechanism

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Mechanism of Organogel Formation from Mixed-Ligand Silver (I) Carboxylates

  • Kim, Ji-Yeon;Park, Cheol-Hee;Kim, Sang-Ho;Yoon, Sung-Ho;Piao, Longhai
    • Bulletin of the Korean Chemical Society
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    • 제32권9호
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    • pp.3267-3273
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    • 2011
  • Ag(I) carboxylate gelators with mixed-ligands were systemically investigated to understand the mechanism of the organic gel formation. The gelators constructed 3-D networks of nanometer-sized thin fibers which facilitated gel formation in various aromatic organic solvents, even at very low concentrations. The loss of reflection peaks in the X-ray diffraction data indicated the reduction of strong interactions between the long alkyl chains as the Ag(I) carboxylates formed gels by maximizing their interactions with the organic solvents. The gelation temperature ($T_{gel}$) was measured to explore the interaction between the gelator molecules and solvents depending on their composition and concentration. Based on the gelation phenomena, a dissociation/re-association mechanism was proposed.

결명자 색소 추출액에 의한 견직물 염색 -매염 및 염착 mechanism을 중심으로- (Dyeing of Silk Fabric with Aqueous Extract of Cassia tora L. Seed - focusing on the mordanting and dyeing mechanisms -)

  • 도성국;강인아
    • 한국염색가공학회지
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    • 제17권2호
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    • pp.10-18
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    • 2005
  • Silk fabrics mordanted with $Fe^{2+},\;Ni^{2+},\;and\;Cu^{2+}$ were dyed with the aqueous extract of Cassia tora L. seed which was known to include water soluble colorant kaempferol, one of flavonol compounds. Kaempferol can react with free radicals and chelate transition metal ions, which is thought to catalyze processes leading to the appearance of free radicals and have antioxidant activity. In relation to the coordinating and chelating mechanism of the ions with the silk protein and kaempferol, reasonable conclusions should be made on the colorant uptake and the water fastness of the fabric. The amount of the colorant on the fabric was in the order of $Fe^{2+}>Ni^{2+}>Cu^{2+}$. In case of dyeing through coordinaiton bonds between transition metal ions and silk protein and colorants, it was thought that the ions with the smaller secondary hydration shell, the higher preference to the atoms of the ligand coordinated, and the suitable bonding stability for the substitution of primarily hydrated water molecules for colorants led to the higher colorant uptake. The water fastnsess of the fabric was in the order of $Fe^{2+}>Cu^{2+}>Ni^{2+}$. It should be reasonable to choose transition metal ions with weak and strong tendency to the ionic and the coordination bond, respectively, to the carboxylate anion of the silk protein. Although further research needs to be done, the conclusions above may be generally applied to the natural dyeing through the coordination bond mechanism between transition metal ions and colorants and substrates.

기업 정보화 핵심 성공요인과 정보화 성과 결정요인에 관한 실증 연구 - SER-M Framework을 중심으로 - (An Empirical Study on Key Success Factors of Company Informatization and Informatization Performance Determinants - Focused on SER-M Framework -)

  • 최해룡;구자원
    • 경영과정보연구
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    • 제36권2호
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    • pp.277-306
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    • 2017
  • 그동안의 기업 정보화 성공요인 관련 연구들은 정보화 자체의 구축 완성도 및 그 재무적 효과에 초점을 맞추고 있어, 정보화의 방향성이 경영전략을 지원할 수 있는지에 대한 연구가 미흡하였다. 기업의 정보화가 경영전략 이행을 주도할 수 있도록 초점이 맞추어져 있는지, 주요 메커니즘 요인이 정보화 성과에 어떠한 연관성을 갖는지에 대한 검증이 필요하며, 이는 기존의 정보화 성공요인들을 경영 전략적 패러다임으로 재해석하는 연구가 필요하다는 것을 시사한다. 본 연구는 국내 기업을 대상으로 주체, 환경, 자원 및 메커니즘 요인이 정보화 성과에 어떠한 영향력을 갖는지를 검증하고, 국내 대기업과 중소기업에 있어 정보화 성공요인이 정보화 성과에 미치는 영향도의 차이가 있는지에 대한 문제를 실증적으로 분석하였다. 본 연구를 통해 7개의 연구가설에 대한 검증 결과를 제시하였다. 기업에 있어 자원 요인의 확보는 정보화 성과에 유의미성이 있다는 것과 메커니즘 관점에서 학습 메커니즘과 조정 메커니즘의 모든 하부 요인들은 기업의 정보화 성과에 유의미하다는 것을 실증 분석을 통해 확인하였다. 또한, 기업 규모에 따른 통제효과분석을 통해 대기업과 중소기업의 정보화 성과에 대한 차이점을 지원 환경 요인, 선택 메커니즘 요인 및 학습 메커니즘 요인 등에 있음을 밝혔다. 본 연구의 시사점은 첫째, 메커니즘 요인 변수의(학습, 내부 조정, 외부 조정) 정보화 성과에 대한 유의미성이 다른 요인 변수에 비해 상대적으로 중요하게 활용되고 있음을 확인하였다. 둘째, 대기업과 중소기업의 정보화 성과에 대한 차이점을 밝혀 중소기업이 중점적으로 확보해야 하는 정보화 성과 요인을 제시 하였고, 셋째, 본 연구는 선행 연구에서 다루지 못한 정보화 성과 창출 메커니즘 요인에 대한 실증연구를 진행했으며, 이는 메커니즘 요인에 대한 보다 더 깊이 있는 이해를 가능하게 하였다. 또한, 본 연구의 사례를 기반으로 타 산업 영역과 기업군에도 적용할 수 있다.

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본사 자원과 메커니즘의 유사성과 격차가 합작투자기업의 학습효과에 미치는 영향 (The Effect of Resource, Mechanism Relatedness and Gap on International Knowledge Transfer)

  • 조형기
    • 지식경영연구
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    • 제11권4호
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    • pp.41-66
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    • 2010
  • This research examines the effect of the relatedness and the gap between Resources and mechanisms on effectiveness of inter-organizational knowledge transfer. According to the literature, there has been a competing theory between two claims; one is that inter-organizational knowledge transfer will be more effective due to the reduction of the transaction cost as the relatedness increases. And the other is that the mutual complementarity of different organizational characteristics will increase synergy. In total, the relatedness and the gap of the Resource and mechanism makes the inverted U-shaped relationship with the inter-organizational knowledge transfer. As the result of empirical analysis about 109 Korean-based Joint Ventures entered country, it shows that the relatedness of parent company's production Resources, learning mechanisms, and coordination mechanisms made the inverted U-shaped relations with the inter-organizational knowledge transfer and the gap of production Resources and adjustment mechanism formed the same relationship. However, the U-shaped relationship has been established in the relatedness of market Resources, but the gap of market Resources and the learning mechanism was not statistically significant. Through this study, I can draw a best conclusion that the inter-organizational knowledge transfer will be more effective when the relatedness and the gap of management resources and mechanisms is in optimal level. However, when it comes to market Resources, it can be inferred that the result could be the opposite because the partner country's market environment would be different.

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Integration of Strategic Issue Management and Knowledge Management in View of Strategic Information Process

  • 염지환
    • 한국디지털정책학회:학술대회논문집
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    • 한국디지털정책학회 2004년도 춘계학술대회
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    • pp.383-400
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    • 2004
  • Knowledge management is an essential part for gaining competitive advantage. The knowledge management system deals with information gathering, process, and implementation for the organizational performance advantage. The study integrates knowledge management in view of an internal organizational information processing structure and external strategic issue management system. This means that the coordination between internal systematic process and external scanning mechanism is essential for organizational success.

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The Mechanism of the Investment Resources Involvement in Order to Introduce Innovations at Enterprises in the Conditions of Digitalization

  • Karpenko, Oksana;Bonyar, Svitlana;Tytykalo, Volodymyr;Belianska, Yuliia;Savchenko, Serhii
    • International Journal of Computer Science & Network Security
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    • 제21권11호
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    • pp.81-88
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    • 2021
  • The presented scientific research substantiates the principles of the mechanism of the investment resources involvement in order to introduce innovations at enterprises in the context of digitalization using a resource-functional approach. The importance of attracting investment resources, which contributes to the modernization of production systems, the creation of a stable economic field of development of economic entities, is justified. The expediency of application of the resource-functional approach on research of the mechanism of attraction of investment resources for introduction of innovations at the enterprises in the conditions of digitalization is proved. The investment process is presented in the form of a chain of interdependent processes which include: attraction of investment resources, investments, increase of investment value, profit. It is proved that the mechanism of attracting investment resources for the introduction of innovations in enterprises in the context of digitalization cannot be considered in isolation from the process, due to the fact that the mechanism is aimed at performing specific functions. The functions of the mechanism include management, complex, coordination, monitoring, performance and control functions. Functions of the mechanism of attraction of investment resources for introduction of innovations at the enterprises in the conditions of digitalization are caused by the purposes of attraction of investment resources for innovative development; the presence of an objective nature; relative independence and homogeneity; implementation of functions in the process of investing in innovative activities of the enterprise.

조작적 구성주의와 사회적 구성주의에서 구성의 의미와 과정 (The Meaning and Mechanism of the 'Construction' in the Operational Constructivism and the Social Constructivism)

  • 임재훈;홍진곤
    • 대한수학교육학회지:수학교육학연구
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    • 제8권1호
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    • pp.299-312
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    • 1998
  • In this study, we have investigated the meaning and mechanism of the 'construction' in the operational constructivism and the social constructivism. According to Piaget, a mathematical concept is the operational sch me, which is constructed through the reflective abstraction from a general coordination of activities and operations. The process of the reflective abstraction consists of 'reflechissement'and 'reflexion'. The reflechissement starting from 'intriorisation' concludes with 'thematisation', and the reflexion consists in the 'equilibration' of the result of reflechissement. The 'construction' in the social constructivism includes two process. One is the process from the individual, subjective knowledge of mathematics to the social, objective knowledge of mathematics, and the other is vice versa. The emphases is placed on the 'social interaction' and the 'representation' in this two processes. In this context, if we want to apply the social constructivism, we should clarify the meaning of 'society', and consider the difference between the society of mathematicians and the society of students.

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802.11 Ad­-Hoc 네트웍에서 Power Save Mechanism을 개선한 DAPSM 알고리즘 (DAPSM algorithm that improve Power Save Mechanism in 802.11 Ad­-Hoc Networks)

  • 박재현;김성천
    • 한국정보과학회:학술대회논문집
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    • 한국정보과학회 2003년도 가을 학술발표논문집 Vol.30 No.2 (3)
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    • pp.109-111
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    • 2003
  • 최근 무선 네트워킹 장치들이 등장 하면서 제한된 배터리에 의존하는 무선 호스트들의 전력 절감은 중요한 이슈가 되었다. 특히 Ad­Hoc에서 배터리는 제한된 에너지를 제공하기 때문에 무선 호스트에 의해서 소모되어지는 에너지의 양을 감소시키기 위한 기술은 대단히 중요하다. 특히 MAC 과 라우팅 에서 전력 절감을 이루기 위한 논문들이 기존에 발표 되었다. 이 논문에서는 IEEE 802.11 표준의 DCF (Distributed Coordination Function) 에서의 전력 절감 메카니즘을 향상 시킨 논문 이다. DCF를 위한 IEEE 802.11 전력 절감 메카니즘에서는 비콘 간격 이라는 시간으로 나누어지며 또한 이러한 각각의 비콘 간격이 시작될 때 각각의 노드들은 ATIM 창 동안 깨어 있어야 한다. 물론 모든 노드는 같은 시간에 깨어 있기 위해서는 동기화 되는 것이 필요하다. ATIM 창 동안 노드들은 비콘 기간 동안 깨어 있는 상태로 있을 것인지를 결정하기 위해서 control packet을 교환 한다. 이러한 ATIM 창 크기는 각각의 노드들의 전력절감에 상당한 영향을 미친다. 따라서 이 논문은 ATIM 창 크기를 동적으로 증감시켜서 보다 에너지 효율을 발휘 하고자 하는 논문이다.

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실행 공동체 구성원의 흡수능력과 공동체 성과간의 관계 (Absorptive Capacities of CoP Members and Their Performances)

  • 서현주
    • 지식경영연구
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    • 제15권1호
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    • pp.1-19
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    • 2014
  • Absorptive capacity is an ability to acquire, assimilate, transform, and apply external knowledge. Since the objectives of communities of practice(CoPs) are to share task-related knowledge and to apply it to operations, individual absorptive capacities of CoP members are one of the most important success factors of CoPs. The study examined the structural relationship among three groups; antecedents of absorptive capacity, absorptive capacity, and the performance of CoPs. The findings are as follows; Goal interdependence, reciprocal altruism, coordination mechanism and socialization mechanism had significant and positive effects on absorptive capacity. In addition absorptive capacity had significant and positive effects on goal attainment and knowledge application of CoP.

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A combined auction mechanism for online instant planning in multi-robot transportation problem

  • Jonban, Mansour Selseleh;Akbarimajd, Adel;Hassanpour, Mohammad
    • Advances in robotics research
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    • 제2권3호
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    • pp.247-257
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    • 2018
  • Various studies have been performed to coordinate robots in transporting objects and different artificial intelligence algorithms have been considered in this field. In this paper, we investigate and solve Multi-Robot Transportation problem by using a combined auction algorithm. In this algorithm each robot, as an agent, can perform the auction and allocate tasks. This agent tries to clear the auction by studying different states to increase payoff function. The algorithm presented in this paper has been applied to a multi-robot system where robots are responsible for transporting objects. Using this algorithm, robots are able to improve their actions and decisions. To show the excellence of the proposed algorithm, its performance is compared with three heuristic algorithms by statistical simulation approach.