• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.265-266
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• 2006

The chemical conversion coating formed on magnesium alloy investigated for low cost and harmless in environment by using the colloidal silica as the main component. The film formed in 298 K is thick, the film, which was thought combination of Si-O, was formed. The film formed in 313 K is thinner than that in 298 K. The quantity of film formed at high temperature such as 333 K and 353 K is smaller than dissolved quantity. At the anodic polarization experiment, corrosion resistance in sealing by hot water after chemical conversion treatment in basic solution condition get worse than that in comparison with basic solution condition. In salt spray test, the ratio of black rust on specimen that did not conducted chemical conversion treatment was five times or more compared with those of chemical conversion treated specimen. The film thickness of chemical conversion coating produced by alkali treatment process is thinner than in comparison with that of specimen produced in basic chemical conversion treatment solution condition. It is thought, however, that it showed good corrosion resistance during salt spray test because the area of microcracks is small.

• Journal of Korean Society for Atmospheric Environment
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• v.9 no.2
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• pp.160-167
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• 1993

As the major methanol fueled vehicle exhaust components, formaldehyde & methanol conversion over the existing commercial 3-way catalyst was examined in a labolatory tains different Ag loadings on commercial 3-way catalyst, and german commercial catalysts for methanol engine exhaust manufactured by a commercial manufacturer. Silver catalysts were prepared by the wet impregnation of silver nitrate solution on commercial 3-way catalyst. These catalysts were characterized with BET Surface area and pore size distribution. In general, the formaldehyde(HCHO) conversion of the tested catalysts was similar to that of methanol$(CH_3OH)$. At 100$^\circ$C, which is equivalent to the cold start condition, 5wt% Ag cat. showed the most excellent HCHO and $CH_3OH$ conversion. The order of activity for conversion of HCHO & $CH_3OH$ to carbon dioxide and water vapor was as follows ; 5wt% Ag/3-way cat.>2wt% Ag/3-way cat.>german cat. front(1) > german cat. rear(2) > 10wt% Ag/3-way cat.> commercial 3-wat catalyst. However there was no significant activity difference between those tested catalysts in the hot run condition of 400$^\circ$C. Therefore, it could be concluded that the Ag-modified 3-way catalyst was the most effective and practical catalyst system which could be capable of removal the HCHO and methanol at the special condition of low temperature such as cold start condition.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.50 no.6
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• pp.387-393
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• 2005

The effect of cattle manure with the rates of 2 and 4 ton $l0a^{-1}$ for winter rye and summer corn cultivation, respectively, on the dry matter (DM) yield and nitrogen (N) uptake were investigated during successive three­year conversion period from paddy to upland condition in paddy field. The changes in soil properties and soil N sup­plying capacity during repetitive manure application were a1so examined. Growth and DM yield of upland forage crops, especially. winter rye were hindered highly by poor soil condition in the first year after conversion from paddy to upland condition, so apparent recovery of cattle manure N by crops was very low in the first conversion year. But, DM yield and N uptake of upland forage crops were increased linearly by accumulative input of cattle manure along with mineral N enrichment in soil, which also increased apparent recovery of cattle manure-No It seemed that those increases were mainly due to the improvement of soil properties such as soil mineral N, soil organic matter (soil carbon), potentially mineralizable N and bulk density by accumulative input of cattle manure rather than the increase of soil N supply according to accumulative conversion period from paddy to upland condition. It was derived that conversion period from paddy to upland condition over 2 years is needed to obtain proper DM yield in paddy field and accumulative inputs of cattle manure during the conversion period is more influential to the continuous increment of DM yield and N uptake of upland crop as well as of potential N supplying capacity of soil.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.54-61
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• 2004

The engine-out flow is highly transient and hot, and may place tremendous thermal and inertial loads on a closed-coupled catalyst. Therefore, time-dependent and detailed flow and thermal field simulation may be crucial. The aim of this study is to develop combined chemical reaction and multi-dimensional fluid dynamic mathematical model and to study the effect of unsteady pulsating thermal and flow characteristics on thermal reliability of closed-coupled catalyst. The effect of cell density on the conversion performance under real running condition is also investigated. Unlike previous studies, the present study focuses on coupling between the problems of pulsating flow pattern and catalyst thermal response and conversion efficiency. The results are expressed in terms of temporal evolution of flow, pollutant and temperature distribution as well as transient characteristics of conversion efficiency. Fundamental understanding of the flow and thermal phenomena of closed-coupled catalyst under real running condition is presented. It is shown that instants of significantly low values of flow uniformity and conversion efficiency exist during exhaust blowdown and the temporal varaition of flow uniformity is very similar in pattern to one of conversion efficiency. It is also found that the location of hot spot in monolith is directly affected by transient flow pattern in closed-coupled catalyst.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.5
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• pp.503-512
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• 2012

There is a new power generation system such as direct coal fuel cell (DCFC) with a solid oxide electrolyte operated at relatively high temperature. In the system, it is of great importance to feed coal continuously into anodic electrode surface for its better contact, otherwise it would reduce electrochemical conversion of coal. For that purpose, it is required to improve the electrochemical conversion efficiency by using either rigorous mixing condition such as fluidized bed condition or just by recirculating coal particle itself successively into the reaction zone of the system. In this preliminary study, we followed the second approach to investigate how significantly particle recycle would affect the coal conversion efficiency. As a first phase, coal conversion was analyzed and evaluated from the thermochemical reaction of carbon with air under particle recirculating condition. The coal conversion efficiency was obtained from raw data measured by two different techniques. Effects of temperature and fuel properties on the coal conversion are specifically examined from the thermochemical reaction.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.51 no.1
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• pp.15-21
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• 2002

We investigated effects of electrical, physical, and chemical parameters on energy transfer, NO conversion, and light emission in the dielectric barrier discharge (DBD) process. As gap distance between electrodes increased, discharge onset voltage increased. However, as gap distance between electrodes increased, electric field which initiates discharge showed approximately the same value, 30kV/cm. The discharge onset voltage of the coarse surface electrode was lower than that of the smooth surface electrode. And, energy transfer was slightly enhanced in the coarse electrode condition. However, NO conversion rate decreased with the coarse surface electrode because more uniform discharge can be obtained on the smooth surface electrode. The NO conversion rate increased with decreasing the initial concentration, so the DBD process is more feasible in the lower concentration condition. The variation of gas residence time tested at the same energy density in the experiment did not affect on the NO conversion. The result shows that the NO conversion rate mainly depends on the energy density. The DBD process is able to adjust on plasma-photocatalyst process because it emits the short wavelength light in the range of ultraviolet. The intensity of light emission increased with the increase of the energy transfer to the reactor and the gas flow rate.

• Proceedings of the KIPE Conference
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• 2016.11a
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• pp.39-40
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• 2016

Power conversion system comes with a twenty-year warranty commonly. Life test requires a long time. The life of power conversion system that especially sensitive to temperature can be expected within a short time by using Arrhenius technique with worst stress condition than actual working condition. This paper researches reliability analysis and environment test of power conversion system.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.337-345
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• 2012

To check effects of operating variables on reaction characteristics of WGS catalyst for SEWGS process, water gas shift reaction tests were carried out in a pressurized fluidized bed reactor using commercial WGS catalyst and sand(as a substitute for $CO_2$ absorbent) as bed materials. Simulated syngas(mixed with $N_2$) was used as a reactant gas. Operating temperature was $210^{\circ}C$ and operating pressure was 20 bar. WGS catalyst content, steam/CO ratio, gas velocity, and syngas concentration were considered as experimental variables. CO conversion increased as the catalyst content and steam/CO ratio increased. CO conversion at fluidized bed condition was higher than that of fixed bed condition. However, CO conversion were maintained almost same value within the fluidized bed condition. CO conversion decreased as the syngas concentration increased. The optimum operation condition was confirmed and long time water gas shift reaction test up to 24 hours at the optimum operating conditions was carried out.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.4
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• pp.355-363
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• 2014

Thermal shock or overheating of WGS catalyst for SEWGS system during hydrogen pre-treatment can cause reactivity decay of the catalyst. To select appropriate pre-treatment condition, temperature profiles of catalyst bed (or outside fluidized particle bed of bed insert) during pre-treatment were measured and then CO conversions of those catalysts during WGS reaction were also measured and compared. Drastic overheating of catalyst took place when we reduce catalyst at fixed bed condition and these catalysts showed low CO conversion during WGS reaction. On the contrary, there was no overheating of catalyst at fluidized bed condition not only physical mixing case but also bed insert case. Spring type bed insert showed acceptable CO conversion even at low WGS content. Consequently, feasibility of high CO conversion without decay of reactivity of catalyst and holding the WGS catalyst inside the SEWGS reactor as tablet shape were confirmed using spring type bed insert.

• Journal of Microbiology and Biotechnology
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• v.19 no.12
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• pp.1596-1602
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• 2009

A lipase-catalyzed esterification reaction of (S)-naproxen ethyl ester by CALB (Candida antarctica lipase B) enzyme was performed in supercritical carbon dioxide. Experiments were performed in a high-pressure cell for 10 h at a stirring rate of 150 rpm over a temperature range of 313.15 to 333.15 K and a pressure range of 50 to 175 bar. The productivity of (S)-naproxen ethyl ester was compared with the result in ambient condition. The total reaction time and conversion yields of the catalyzed reaction in supercritical carbon dioxide were compared with those at ambient temperature and pressure. The experimental results show that the conversion and reaction rate were significantly improved at critical condition. The maximum conversion yield was 9.9% (216 h) at ambient condition and 68.9% (3 h) in supercritical state. The effects of varying amounts of enzyme and water were also examined and the optimum condition was found (7 g of enzyme and 2% water content).