• 제목/요약/키워드: Controlling of Properties

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Nanostructured Photoelectrode Materials for Improving Light-Harvesting Properties in DSSCs

  • 정현석
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.7.2-7.2
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    • 2011
  • Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11~12%, in contrast to their theoretical value of 33%. The majority of research has focused on improving energy conversion efficiency of DSSC by controlling nanostructure and exploiting new materials in photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO). In this presentation, we introduce monodisperesed TiO2 nanoparticles prepared by forced hydrolysis method and their superiority as photoelectrode materials was characterized with aids of optical and electrochemical analysis. Inverse opal-based scattering layers containing highly crystalline anatase nanoparticles are also introduced and their feasibility for use as bi-functional light scattering layer is discussed in terms of optical reflectance and charge generation properties as a function of optical wavelength.

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플라이애쉬 대체율별 강모래.깬자갈을 사용한 고유동콘크리트의 각종 유동특성 및 공학적 특성에 관한 실험적 연구 (The Experimental Study on the High Flowing and Engineering Properties of High Flowing Concrete using River and Crushed Stone according to the Replacement Percentage of Fly-ash)

  • 최희용;조성현;최세진;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 가을 학술발표회 논문집
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    • pp.308-315
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    • 1996
  • The utilization of high flowing concrete in construction sites is a world wide trend, and it will be increase to need for high flowing concrete in our construction sites. While it is quite easy to make high-flowing concrete in the laboratory, controlling slump in the field long enough to ensure easy placement once the concrete arrives at job site can be difficult. This study is the experimental study on the high-flowing and engineering properties of high flowing concrete using river sand and crushed stone according to the replacement percentage of fly-ash. As a results of this study is the mix proportion of replacement percentage of fly-ash 30% better than the others. And it is confirm to possibility of manufacture of the high flowing concrete.

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도공층 구조 및 도공지의 인쇄적성에 관한 연구 (I) - 이온성 단량체가 도공용 라텍스의 물성에 미치는 영향 - (A study on the Coating Structure and Printability of Coated Paper (I) - Effect of Ionic Monomer on Paper-coating Latex Properties -)

  • 이용규
    • Journal of the Korean Wood Science and Technology
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    • 제25권3호
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    • pp.75-82
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    • 1997
  • To improve the quality of coated paper, the continuous research to the coating components and development of alternative latices is required. Recently, amphoteric latex is getting a great concern due to their changable properties of surface charge through controlling pH and some methods have been tried to prepare amphoteric latices. This study was carried out to synthesize amphoteric latex using seeding polymerization method with low concentration emulsifier. Styrene was used as a main monomer in addition to acrylonitrile for a hydrophilic comonomer. acrylic acid for a anionic comonomer and N,N-dimethylaminoethyl methacrylate for a cationic comonomer. Particle size and viscosity of latex were greatly affected by addition of acrylic acid and ammonium persulfate as an initiator. Negative charge of latex in alkali condition was changed to zero to positive charge in around pH 4.

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Retention and Drainage Characteristics with Inverse Emulsion Type C-PAM

  • Son, Dong-Jin;Kim, Bong-Yong
    • 펄프종이기술
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    • 제38권5호
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    • pp.24-30
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    • 2006
  • This study was performed to characterize inverse emulsion type cationic polyacrylamide (PAM) and to compare with powder and salt dispersion type PAMs as a retention and drainage aid. Salt dispersion type PAM has defects of high amount of salt which increases conductivity of white water, low active polymer contents and relatively worse retention and drainage properties than others because of its low molecular weight. Powder type PAM has benefit of high active polymer contents and good retention and drainage properties, but defects of low dissolution speed and insoluble particle generation were observed. However, inverse emulsion type showed the best retention and drainage aids among them by controlling molecular weight and morphology easily and it had relatively higher active polymer contents and better solubility.

Nanoarchitectures for Enhancing Light-harvesting and Charge-collecting Properties in Dye-sensitized Solar Cells

  • 정현석
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.13.1-13.1
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    • 2011
  • Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11~12%, in contrast to their theoretical value of 33%. The majority of research has focused on improving energy conversion efficiency of DSSC by controlling nanostructure and exploiting new materials in photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO) [1-5]. In this presentation, we introduce inverse opal-based scattering layers containing highly crystalline anatase nanoparticles and their feasibility for use as bi-functional light scattering layer is discussed in terms of optical reflectance and charge generation properties as a function of optical wavelength. A new ITO nanowire-based photoelecrode is also introduced and its unique charge collection property is presented, demonstrating potential use for highly efficient charge collection in DSSC.

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제트 질량 변수 조절에 의한 성형작약 관통성능 증대 연구 (A Study on the Improvement of Penetration Capability of a Shaped Charge by Controlling the Jet Mass Parameters)

  • 소병관
    • 한국군사과학기술학회지
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    • 제18권5호
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    • pp.566-573
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    • 2015
  • The most important factor for the penetration performance of shaped charge is the liner design. By designing the liner to have properties of both high jet tip velocity and long jet break-up time, the better penetration performance could be acquired. Usually it is very difficult to satisfy above two conditions simultaneously. In this study, the liner with the shape of ogive was developed to have relatively larger jet mass compared to the conventional trumpet liner. The designed shaped charge showed jet properties with high jet tip velocity and long jet break-up time by using ogive liner and wave shaper. A commercially available hydro-dynamic code AUTODYN-2D was used for numerical analysis of jet formation. The flash X-ray test and the static penetration test were conducted to verify the results of numerical analysis.

Micromechanical 시험법을 이용한 Kenaf와 Ramie 섬유강화 에폭시 복합재료의 계면 물성 평가 (Interfacial Evaluation of Kenaf and Ramie Fibers/Epoxy Composites using Micromechanical Technique)

  • 트란콩손;박종만;황병선
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 추계학술발표대회 논문집
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    • pp.92-95
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    • 2004
  • Interfacial shear strength (IFSS) of environmentally- friend natural fiber reinforced polymer composites playa very important role in controlling the overall mechanical properties. In this work the IFSS of Ramie and Kenaf fibers/epoxy systems were evaluated using the combination of micromechanical technique, microdroplet test to find out an optimal condition in accordance with final purpose by comparing to each other. Clamping effect on fiber elongation was determined as well. In addition, the mechanical properties of the natural fibers were investigated using single fiber tensile test and analyzed statistically by both uni- and bimodal Weibull distributions. Microfailure modes of different natural fiber structures were observed using optical microscope.

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나노입자 기반 발광 소재 연구동향 (Technology Trend of Luminescent Nanomaterials)

  • 정혜원;손재성
    • 한국분말재료학회지
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    • 제25권2호
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    • pp.170-177
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    • 2018
  • Colloidally synthesized luminescent nanocrystals (NCs) have attracted tremendous attention due to their unique nanoscale optical and electronic properties. The emission properties of these NCs can be precisely tuned by controlling their size, shape, and composition as well as by introducing appropriate dopant impurities. Nowadays, these NCs are actively utilized for various applications such as optoelectronic devices including light emitting diodes (LEDs), lasers, and solar cells, and bio-medical applications such as imaging agents and bio-sensors. In this review, we classify luminescent nanomaterials into quantum dots (QDs), upconversion nanoparticles (UCNPs), and perovskite NCs and present their intrinsic emission mechanism. Furthermore, the recently emerging issues of efficiency, toxicity, and durability in these materials are discussed for better understanding of industry demands. As well, the future outlook will be offered for researchers to guide the direction of future research.

기판온도 변화에 따른 ZnO:Al 투명 전도막의 특성 변화 (A study on the properties of transparent conductive ZnO:Al films on variation substrate temperature)

  • 양진석;성하윤;금민종;손인환;신성권;김경환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.525-528
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    • 2001
  • ZnO:Al thin film can be used as a transparent conducting oxide(TCO) which has low electric resistivity and high optical transmittance for the front electrode of amorphous silicon solar cells and display devices. This study of electrical, crystallographic and optical properties of Al doped ZnO thin films prepared by Facing Targets Sputtering (FTS), where strong internal magnets were contained in target holders to confine the plasma between the targets, is described. Optimal transmittance and resistivity was obtained by controlling flow rate of O$_2$ gas and substrate temperature. When the of gas rate of 0.3 and substrate temperature 200$^{\circ}C$ , ZnO:Al thin film had strongly oriented c-axis and lower resistivity(<10$\^$-4/Ω-cm).

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Preparation and Characterization of Metal-containing Activated Carbon Derived from Phenolic Resin

  • Oh, Won-Chun
    • Carbon letters
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    • 제4권2호
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    • pp.86-92
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    • 2003
  • A series of micro- and mesoporous activated carbons were prepared from two kinds of phenolic resin using a metal treated chemical activation methodology. $N_2$-adsorption data were used to characterize the surface properties of the produced activated carbons. Results of the surface properties and pore distribution analysis showed that phenolic resin can be successfully converted to micro- and mesoporous activated carbons with specific surface areas higher than 973 $m^2/g$. Activated carbons with porous structure were produced by controlling the amount of metal chlorides ($CuCl_2$). Pore evolvement depends on the amount of additional metal chloride and precursors used. From the SEM and EDX data, copper contents were shown to be most effected by the incremental addition of metal chloride.

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