• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.285-285
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• 2013

Recently, hexagonal boron nitride (h-BN), which is III-V compound of boron and nitride by strong covalent sp2 bonds has gained great interests as a 2 dimensional insulating material since it has honeycomb structure with like graphene with very small lattice mismatch (1.7%). Unlike graphene that is semi-metallic, h-BN has large band gap up to 6 eV while providing outstanding properties such as high thermal conductivity, mechanical strength, and good chemical stability. Because of these excellent properties, hBN can potentially be used for variety of applications such as dielectric layer, deep UV optoelectronic device, and protective transparent substrate. Low pressure and atmospheric pressure chemical vapor deposition (LPCVD and APCVD) methods have been investigated to synthesize h-BN by using ammonia borane as a precursor. Ammonia borane decomposes to polyiminoborane (BHNH), hydrogen, and borazine. The produced borazine gas is a key material that is a used for the synthesis of h-BN, therefore controlling the condition of decomposed products from ammonia borane is very important. In this paper, we optimize the decomposition of ammonia borane by investigating temperature, amount of precursor, and other parameters to fabricate high quality monolayer h-BN. Synthesized h-BN is characterized by Raman spectroscopy and its absorbance is measured with UV spectrophotometer. Topological variations of the samples are analyzed by atomic force microscopy. Scanning electron microscopy and Scanning transmission Electron microscopy are used for imaging and analysis of structures and surface morphologies.

• Geomechanics and Engineering
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• v.8 no.6
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• pp.757-767
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• 2015

Rock mass is an important engineering material. In hydropower engineering, rock mass of bank slope controlled the stability of an arch dam. However, mechanical characteristics of the rock mass are not only affected by lithology, but also joints. On the basis of field geological survey, this paper built rock mass material containing parallel concentrated joints with different dip angle, different number under different stress conditions by PFC (Particle Flow Code) numerical simulation. Next, we analyzed mechanical property and fracture features of this rock mass. The following achievements have been obtained through this research. (1) When dip angle of joints is $15^{\circ}$ and $30^{\circ}$, with the increase of joints number, peak strength of rock mass has not changed much. But when dip angle increase to $45^{\circ}$, especially increase to $60^{\circ}$ and $75^{\circ}$, peak strength of rock mass decreased obviously with the increase of joints number. (2) With the increase of confining stress, peak strengths of all rock mass have different degree of improvement, especially the rock mass with dip angle of $75^{\circ}$. (3) Under the condition of no confining stress, dip angle of joints is low and joint number is small, existence of joints has little influence on fracture mode of rock mass, but when joints number increase to 5, tensile deformation firstly happened at joints zone and further resulted in tension fracture of the whole rock mass. When dip angle of joints increases to $45^{\circ}$, fracture presented as shear along joints, and with increase of joints number, strength of rock mass is weakened caused by shear-tension fracture zone along joints. When dip angle of joints increases to $60^{\circ}$ and $75^{\circ}$, deformation and fracture model presented as tension fracture zone along concentrated joints. (4) Influence of increase of confining stress on fracture modes is to weaken joints' control function and to reduce the width of fracture zone. Furthermore, increase of confining stress translated deformation mode from tension to shear.

• Journal of the Korean Geotechnical Society
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• v.31 no.3
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• pp.27-38
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• 2015

Triaxial tests on sand-silt mixture specimens under low and high confining pressures were performed to understand their shear behaviors. The fines content in the mixture is lower than the threshold value. A series of tests under different conditions including fines contents (0%, 9.8%, 14.7%, 19.6%), density of specimen (controlled by different compaction energies of $E_c=22kJ/m^3$, $E_c=504kJ/m^3$), confining pressure (100 kPa, 1 MPa, 3 MPa, 5 MPa) were performed to investigate influences of these factors. Based on the test results, the threshold fines content, where the dominant structure of mixture changes from sand-matrix to fines-matrix, decreases with the increase of confining pressure. Under very high confining pressures, as a result of sand particle crushing, the behavior of the dense specimen is similar to that of the loose specimen which shows hardening, compression behavior, and shear strength increases with increase of fines content. In conclusion, silt is granular material like sand, and its influence on shear behavior of sand-silt mixture is very different from that of plastic fines on sand-fines mixture.

• Journal of the Korea Institute of Building Construction
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• v.18 no.1
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• pp.25-31
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• 2018

In this study, the Controlled Low Strength Material (CLSM) was investigated to utilize the bottom ash and fly ash generated in the Circulating Fluidized Bed Combustor (CFBC). It was confirmed that the CFBC fly ash (CFBC-F) and CFBC bottom ash (CFBC-B) had an irregular particle shape through SEM measurement. According to the results of the hazard analysis, it was also confirmed that they were environmentally safe. In the case of mixing with CFBC-F, the unit quantity was increased. Regarding the rate of change of length, shrinkage in the range of -0.05~0.50% occurred in the air dry curing condition and expansion in the range of 0.1~0.6% in the sealed curing condition. Compressive strength was increased in the sealed curing condition compared to the air dry curing condition because there was enough moisture for hydration reaction in the long term. Therefore, the results of this study are likely be used as basic research data of mine filler materials.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.295-301
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• 2011

Recently, the use of UHPC made of superplasticizers, silica fume, and steel fibers has been increasing worldwide. Although UHPC has a very high strength as well as an excellent durability performance due to its dense microstructures, earlyage cracks may occur due to the high heat of hydration and autogenous shrinkage caused by low W/B and high unit cement content. The early-age shrinkage cracking of UHPC can be controlled by using the shrinkage reducers and expansive admixtures having autogenous shrinkage compensation effect. In this paper, ultrasonic pulse velocity of UHPC containing shrinkage reducers and expansive agents was measured to predict its stiffness change. Also, the effect of shrinkage reducers and expansive agents on the autogenous shinkage of UHPC was investigated through the shrinkage test of UHPC specimens. Furthermore, the material coefficients of autogenous shrinkage prediction model were determined using the autogenous shrinkage values of UHPC with age. Consequently, the test results showed that, by adding shrinkage reducers and expansive agents, the stiffness of UHPC was rapidly developed at early-ages and the autogenous shrinkage was considerably reduced.

• Membrane Journal
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• v.16 no.4
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• pp.268-275
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• 2006

Novel SILEMs were prepared by multi-stage phase separation process combined by the low temperature phase separation (LTPS) and the high temperature phase separation (HTPS) using room temperature ionic liquids (RTILs) which have a high ionic conductivity. PVDF and imidazolium series ionic liquids were used as membrane material and electrolyte, respectively. To study the ion conducting properties, the SILEMs were tested using LCR meter at temperature controlled from 30 to $130^{\circ}C$. Under humid conditions, with increasing temperature from 30 to $100^{\circ}C$, the ion conductivity of the cast $Nafion^{(R)}$ membrane increased linearly, but then started to decrease after $100^{\circ}C$. However, in the case of the SILEMs, with increasing operating temperature, the ion conductivity increased. Also, the ion conductivity behaviors of the SILEMs were almost same, regardless of humidity. The ion conductivity of the SILEMs was $2.7{\times}10^{-3}S/cm$ and increased almost linearly up to $2.2{\times}10^{-2}S/cm$ with increasing temperature to $130^{\circ}C$. The effects of an inorganic filler on the physical properties of the SILEMs were studied using the $SiO_2$. The addition of $SiO_2$ could improve the mechanical strength of the SILEMs, though the ionic conductivity was decreased slightly.