• Title/Summary/Keyword: Contrast phase

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Effect of Coagulation Heat Capacity on the PVDF Membrane via TIPS Method (열유도상분리법을 이용한 응고조의 열용량에 따른 PVDF 분리막의 구조 분석)

  • Lee, Jeong Woo;Nam, Sang Yong
    • Membrane Journal
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    • v.27 no.4
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    • pp.350-357
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    • 2017
  • In this study, we used TIPS (thermally induced phase separation) for the application of water treatment membrane, and observed the change in morphology of separation membrane due to the change of solidification temperature and heat capacity. For manufactured membrane, PVDF and silica with excellent mechanical properties and chemical resistance were used, and DOP (dioctyl phthalate), DBP (dibutyl phthalate) were used as the diluent. Using the SEM (scanning electron microscope), the morphology of each different coagulation solutions of heat capacity change was observed. As the heat capacity increased, the crystallization rate of PVDF was decreased and showed large pore. In contrast, It also confirmed that the smaller heat capacity, the faster the crystallization rate and make smaller pores.

Characterization of Subsurface Damage in Si3N4 Ceramics with Static and Dynamic Indentation

  • Kim, Jong-Ho;Kim, Young-Gu;Kim, Do-Kyung
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.537-541
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    • 2005
  • Silicon nitride is one of the most successful engineering ceramics, owing to a favorable combination of properties, including high strength, high hardness, low thermal expansion coefficient, and high fracture toughness. However, the impact damage behavior of $Si_3N_4$ ceramics has not been widely characterized. In this study, sphere and explosive indentations were used to characterize the static and dynamic damage behavior of $Si_3N_4$ ceramics with different microstructures. Three grades of $Si_3N_4$ with different grain size and shape, fine-equiaxed, medium, and coarse-elongated, were prepared. In order to observe the subsurface damaged zone, a bonded-interface technique was adopted. Subsurface damage evolution of the specimens was then characterized extensively using optical and electron microscopy. It was found that the damage response depends strongly on the microstructure of the ceramics, particularly on the glassy grain boundary phase. In the case of static indentation, examination of subsurface damage revealed competition between brittle and ductile damage modes. In contrast to static indentation results, dynamic indentation induces a massive subsurface yield zone that contains severe micro-failures. In this study, it is suggested that the weak glassy grain boundary phase plays an important role in the resistance to dynamic fracture.

Preparations of Polymer Dispersed Liquid Crystals Using the Liquid Crystals with negative dielectric anisotropy

  • Hwang, Sung-Ho;Woo, Sung-Ho;Jeon, Chan-Wook;Yang, Kee-Jeong;Choi, Byeong-Dae;Kim, Byung-Kyu;Kim, Eun-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1394-1397
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    • 2006
  • Polymer Dispersed Liquid Crystal (PDLC) films, of which the liquid crystal has negative dielectric anisotropy, were prepared from the phase separation between MJ001317 and a variety of compositions of resins by common polymerization induced phase separation method. In this work, the effects of resin compositions have been systematically investigated and it was found that the morphology and size of droplet, which is closely related to electro-optic properties, mainly depend on the rate of polymerization and cross-linking density for each resin composition. The reverse mode PDLC films from this newly developed formulation containing TPGDA/EHA/HMPPO showed the good off-state transmittance, contrast ratio (19/1), and relatively low driving voltage(10V).

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Dielectric and Piezoelectric Properties of Low Temperature Sintering PMW-PNN-PZT Substituted with CeMnO3 (CeMnO3가 치환된 저온소결 PMW-PNN-PZT 세라믹스의 유전 및 압전 특성)

  • Kim, Yong-Jin;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.3
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    • pp.160-164
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    • 2015
  • In this study, $(1-x)Pb(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3+xCeMnO_3$ (x= 0~0.02) ceramics were prepared by Columbite precursor method. The phase structure, ferroelectric and piezoelectric properties were systematically investigated. It was found that PMW-PNN-PZT possessed superior electrical properties due to its composition close to the MPB (morphotropic phase boundary). Coercive electric field of 10.05 [kV/cm] and density of 7.88 [$g/cm^3$] were obtained when the substitution amount of $CeMnO_3$ is x=0.02. In contrast, specimens with x=0.01 showed the mechanical quality factor($Q_m$) of 1,091 and the electromechanical coupling factor($k_p$) of 0.613.

Near-infrared Subwavelength Imaging and Focusing Analysis of a Square Lattice Photonic Crystal Made from Partitioned Cylinders

  • Dastjerdi, Somayeh Rafiee;Ghanaatshoar, Majid;Hattori, Toshiaki
    • Journal of the Optical Society of Korea
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    • v.17 no.3
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    • pp.262-268
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    • 2013
  • We study the focusing properties of a two-dimensional square-lattice photonic crystal (PC) comprising silica and germanium partitioned cylinders in air background. The finite difference time domain (FDTD) method with periodic boundary condition is utilized to calculate the dispersion band diagram and the FDTD method incorporating the perfectly matched layer boundary condition is employed to simulate the image formation. In contrast to the common square PCs in which the negative refraction effect occurs in the first photonic band without negative phase propagation, in our suggested model system, the frequency with negative refraction exists in the second band and in near-infrared region. In this case, the wave propagates with a negative phase velocity and the evanescent waves can be supported. We also discuss the dependency of the image resolution and its location on surface termination, source location, and slab thickness. According to the simulation results, spatial resolution of the proposed PC lens is below the radiation wavelength.

Sex Characterization of Wrasses Inhabiting in the Coastal Waters of Jeju, Korea (제주 연안에 서식하는 놀래기류의 성 특성)

  • Lee, Chi-Hoon;Kim, Yoon-Seok;Lee, Young-Don
    • Development and Reproduction
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    • v.10 no.2
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    • pp.79-84
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    • 2006
  • We reviewed sex-change patterns in the wrasses Halichoeres poecilopterus, H. tenuispinis, Pteragogus flagellifer, and Pseudolabrus sieboldi inhabiting the coastal waters of Jeju, Korea, based on the sex distribution according to standard length and sex characteristics of the gonads. Halichoeres poecilopterus, H. tenuispinis, Pt. flagellifer, and Ps. sieboldi are protogynous hermaphroditic fish. Histological observations revealed that these wrasses are undelimited type 2 species because testicular tissue(spermatogenesis area) appears in most parts of the gonads during ovary of degenerative stage. Both initial- and terminal-phase males were present in the investigated populations, indicating that Halichoeres poecilopterus, H. tenuispinis, and Ps. sieboldi are of the diandric type. In contrast, Pt. flagellifer is considered a monandric type, because all males in the investigated populations were terminal-phase males produced via sex change from functional females.

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Formation Process and Structure of Lamellar Grain Boundaries in Titanium Rich TiAl Intermetallics

  • Han, Chang-Suk;Lim, Sang-Yeon
    • Korean Journal of Materials Research
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    • v.26 no.1
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    • pp.13-16
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    • 2016
  • Morphology and formation processes of lamellar grain boundaries in titanium rich binary TiAl intermetallics were studied. TiAl alloys containing aluminum content of 44 to 48 at.% were induction-heated to 1723 K followed by helium-gas-quenching at various temperatures. For the Ti-44%Al, few lamellae were observed in samples quenched from higher than 1473 K. Although small peaks of beta phase were detected using X-ray diffraction, only the ordered hexagonal phase (${\alpha}_2$) with clear APB contrast was observed in TEM observation. For the Ti-48 at.%Al alloy, almost no lamellar structure, and straight grain boundaries were observed in samples quenched from higher than 1623 K. The formation of lamellae along grain boundaries was observed in the sample quenched from 1573 K. The fully lamellar microstructures with serrated boundaries were observed in samples quenched from lower than 1473 K. It was found that the formation of ${\gamma}$ platelets took place at higher temperatures in Ti-48 at.%Al than in Ti-44 at.%Al. Although the size of the serration is different, serrated lamellar grain boundaries could be obtained for all alloy compositions employed. The serration appeared to be due to the grain boundary migration induced by precipitation and growth of ${\gamma}$. Differences in transformation characteristics with aluminum content are discussed.

Surface Structure Image of Stearic acid Organic Thin Films (Stearic acid 유기박막의 표면주고 Image)

  • Chang, Hun;Song, Jin-Won;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.562-564
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    • 2001
  • Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic matter thin film that accumulate molecular film in archaism board only that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. The stable images are probably due to a strong interaction between the monolayer film and glass substrate. We are unable to obtain molecule resolution in images of the films but did see a marked contrast between images of the bare substrate and those with the network structure film deposited onto it. Formation that prevent when gas phase state and liquid phase state measure but Could know organic matter that molecules form equal and stable film when molecules were not distributed evenly. and accumulated in solid state only.

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A Study on the Image and Surface Structure analysisthat Manufacture by LB Method of LB Thin Film (LB박막의 이미지와 표면구조분석에 관한 연구)

  • Song, Jin-Won;Lee, Kyung-Sup;Choi, Young-Il;Chung, Hun-Sang;Gu, Hal-Bon;Kim, Young-Keun;Lee, Young-Gil
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1618-1620
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    • 2002
  • Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic matter thin film that accumulate molecular film in archaism board only that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. The stable images are probably due to a strong interaction between the monolayer film and glass substrate. We are unable to obtain molecule resolution in images of the films but did see a marked contrast between images of the bare substrate and those with the network structure film deposited onto it. Formation that prevent when gas phase state and liquid phase state measure but Could know organic matter that molecules form equal and stable film when molecules were not distributed evenly, and accumulated in solid state only.

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Piezoelectric Properties in ZnO Dopped (Na,K)NbO3 Ceramics (ZnO가 첨가된 (Na,K)NbO3계 세라믹스의 압전 특성)

  • Ryu Sung-Lim;Kweon Soon-Yong;Ur Soon-Chul;Kim Si-Chul;Yoo Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.8
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    • pp.707-711
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    • 2006
  • ZnO was doped up to 0.3 wt% for improving the electrical properties of lead-free $[Li_{0.04}(Na_{0.44}Ko_{0.52})-(Nb_{0.86}\;Ta_{0.10}\;Sb_{0.04})]O_3$ piezoelectric ceramics. The ceramics were fabricated with the conventional sintering processes. Crystal structure of the samples was tetragonal phase regardless of ZnO amount. However, the piezoelectric properties were varied with the ZnO amount. The electro-mechanical coupling factor $(k_p)$ was with the ZnO amount up to 0.2 wt% but decreased with the further addition. the maximum value of $k_p$ was 0.475. Density, piezoelectric charge constant and relative dielectric constant was also showed maximum value at 0.2 wt%. The maximum values are $4.75g/cm^3$, 275 pC/N, 1403, respectively. In contrast, the mechanical quality factor $(Q_m)$ was not varied with increasing the ZnO addition up to 0.2 wt% but rapidly increased at 0.3 wt%.