• Title/Summary/Keyword: Continuous Scanning

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X-ray diffraction analysis of the effect of ball milling time on crystallinity of milled polyacrylonitrile-based carbon fiber

  • Lee, Sang-Hye;Kang, Dong-Su;Lee, Sang-Min;Roh, Jae-Seung
    • Carbon letters
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    • v.26
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    • pp.11-17
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    • 2018
  • Milled carbon fiber (mCF) was prepared by a ball milling process, and X-ray diffraction (XRD) diffractograms were obtained by a $2{\theta}$ continuous scanning analysis to study mCF crystallinity as a function of milling time. The raw material for the mCF was polyacrylonitrile-based carbon fiber (T700). As the milling time increased, the mean particle size of the mCF consistently decreased, reaching $1.826{\mu}m$ at a milling time of 18 h. The XRD analysis showed that, as the milling time increased, the fraction of the crystalline carbon decreased, while the fraction of the amorphous carbon increased. The (002) peak became asymmetric before and after milling as the left side of the peak showed an increasingly gentle slope. For analysis, the asymmetric (002) peak was deconvoluted into two peaks, less-developed crystalline carbon (LDCC) and more-developed crystalline carbon. In both peaks, Lc decreased and $d_{002}$ increased, but no significant change was observed after 6 h of milling time. In addition, the fraction of LDCC increased. As the milling continued, the mCF became more amorphous, possibly due to damage to the crystal lattices by the milling.

Test of a Multilayer Dose-Verification Gaseous Detector with Raster-Scan-Mode Proton Beams

  • Lee, Kyong Sei;Ahn, Sung Hwan;Han, Youngyih;Hong, Byungsik;Kim, Sang Yeol;Park, Sung Keun
    • IEIE Transactions on Smart Processing and Computing
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    • v.4 no.5
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    • pp.297-304
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    • 2015
  • A multilayer gaseous detector has been developed for fast dose-verification measurements of raster-scan-mode therapeutic beams in particle therapy. The detector, which was constructed with eight thin parallel-plate ionization chambers (PPICs) and polymethyl methacrylate (PMMA) absorber plates, is closely tissue-equivalent in a beam's eye view. The gas-electron signals, collected on the strips and pad arrays of each PPIC, were amplified and processed with a continuous charge.integration mode. The detector was tested with 190-MeV raster-scan-mode beams that were provided by the Proton Therapy Facility at Samsung Medical Center, Seoul, South Korea. The detector responses of the PPICs for a 190-MeV raster-scan-mode proton beam agreed well with the dose data, measured using a 2D ionization chamber array (Octavius model, PTW). Furthermore, in this study it was confirmed that the detector simultaneously tracked the doses induced at the PPICs by the fast-oscillating beam, with a scanning speed of 2 m s-1. Thus, it is anticipated that the present detector, composed of thin PPICs and operating in charge.integration mode, will allow medical scientists to perform reliable fast dose-verification measurements for typical dynamic mode therapeutic beams.

Ethanol Production by a New Method of Alginate-Immobilization (새로운 Alginate 고정화 방법에 의한 에탄올 생산)

  • Kim, Eun-Young;Kim, Seung-Wook;Kim, Keun
    • Microbiology and Biotechnology Letters
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    • v.21 no.4
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    • pp.373-380
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    • 1993
  • When the cells of yeast K35 were immobilized in Ca-alginate gel, cell concentration and viability decreased as alginate concentration increased. Considering the results, 2% (w/v) Ca-alginate concentration would be suitable. Among various concentrations of additives and cross-lin-king agent, the addition of 1.67% (w/v) of bentonite together with 0.33% (v/v) of glutaraldehyde (ABG bead) resulted in the highest ethanol production of 1.8%(w/v), using YPD medium containing 2% glucose. ABG bead seemed to be more resistant to phosphate ion than Ca-alginate bead. 0.33%(w/v) of phosphate was a proper concentration for the ethanol production by ABG bead. Scanning electron microscopic observation depicted that the immobilized cells on the bead surface were coated by alginate gel and that the cells in the internal bead were cross-linked with alginate matrix. When repeated-batch culture was performed with ABG bead for 40 days in a packed-bed reactor, ethanol concentration of about 90~110 g/l-gel was maintained. Cell viability was maintained around 70%, and outgrowing cell concentration was below 6.3% of total cell concentration. Consequently, the results showed that ABG head was a potential carrier for continuous production of ethanol compared to conventional Ca-alginate bead.

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Electrochemical Performance of Li4Ti5O12 Particles Manufactured Using High Pressure Synthesis Process for Lithium Ion Battery (초고압 합성법으로 제조한 리튬이온전지 음극활물질 Li4Ti5O12의 전기화학적 특성)

  • Ji, Sung Hwa;Jo, Wan Taek;Kim, Hyun Hyo;Kim, Hyojin
    • Korean Journal of Materials Research
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    • v.28 no.6
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    • pp.337-342
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    • 2018
  • Using a high pressure homonizer, we report on the electrochemical performance of $Li_4Ti_5O_{12}(LTO)$ particles manufactured as anode active material for lithium ion battery. High-pressure synthesis processing is performed under conditions in which the mole fraction of Li/Ti is 0.9, the synthesis pressure is 2,000 bar and the numbers of passings-through are 5, 7 and 10. The observed X-ray diffraction patterns show that pure LTO is manufactured when the number of passings-through is 10. It is found from scanning electron microscopy analysis that the average size of synthesized particles decreases as the number of passings-through increases. $LiCoO_2-based$ active cathode materials are used to fabricate several coin half/full cells and their battery characteristics such as lifetime, rate capability and charge transfer resistance are then estimated, revealing quite good electrochemical performance of the LTO particles as an effective anode active material for lithium secondary batteries.

Effect of Process Condition on Tensile Properties of Carbon Fiber

  • Lee, Sung-Ho;Kim, Ji-Hoon;Ku, Bon-Cheol;Kim, Jun-Kyong;Chung, Yong-Sik
    • Carbon letters
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    • v.12 no.1
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    • pp.26-30
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    • 2011
  • For polyacrylonitrile (PAN) based carbon fiber (CF) process, we developed a lab scale wet spinning line and a continuous tailor-made stabilization system with ten columns for controlling temperature profile. PAN precursor was spun with a different spinning rate. PAN spun fibers were stabilized with a total duration of 45 to 110 min at a given temperature profile. Furthermore, a stabilization temperature profile was varied with the last column temperature from 230 to $275^{\circ}C$. Stabilized fibers were carbonized in nitrogen atmosphere at $1200^{\circ}C$ in a furnace. Morphologies of spun and CFs were observed using optical and scanning electron microscopy, respectively. Tensile properties of resulting CFs were measured. The results revealed that process conditions such as spinning rate, stabilization time, and temperature profile affect microstructure and tensile properties of CFs significantly.

Analysis of Surface Morphology and Optical Transmission Features in LB Films by SNOAM (SNOAM에 의한 LB막의 표면모폴로지 및 광투과상 해석)

  • Lee, Seung-Jun;Jung, Sang-Burm;Yoo, Seung-Yeop;Sin, Hun-Gyu;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.108-111
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    • 2000
  • We will illustrate the topographical structure and optical structure of the merocyanine dye LB films obtained by the scanning near-field optical/atomic force microscopy (SNOAM). SNOAM was recognized as a powerful tool to modify the surface as well as to characterize the topography of the surface at atomic resolution, especially for optical reaction materials. SNOAM images showed that the topographical and optical structures of these films were not only depended on the chemical property but also physical property. In the continuous measurement on these dyes, the appearance of near-field optical transmission images showed a certain dependence on the kinds of dyes and the mutual mixing ratios of dyes. These experimental results suggest that there is a certain kind of interaction between these two dyes.

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The Effects of Laser Irradiation on Human Plasma $\beta-endorphin$ Levels (Laser가 정상인의 혈장내 $\beta-endorphin$ 농도에 미치는 영향)

  • Seo Yeon-Soon;Park Rae-Joon;Park Young-Han
    • The Journal of Korean Physical Therapy
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    • v.9 no.1
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    • pp.157-166
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    • 1997
  • The purpose of this study was to determine the effects of laser Irradiation on Human plasma $\beta-endorphin$ levels, by treating with low level helium-neon (He-Ne) and Infrared(lR) laser. The Laser was fixed frequency of 2400Hz by continuous scanning and irradiating time was 8 minutes each point. Blood samples were taken at before, after, after 15min's treatment and Plasma $\beta-endorphin$ was measured by radioimmunoassay. The samples for this study were 6 normal subjects(3male, 3female). The data were analyzed by paired t-test, one-way ANOVA and simple regression. The results of this study were as follows : 1. The human plasma $\beta-endorphin$ levels were noted as significant increase in after-treatment $(22.84{\pm}10.63pg/ml)$ as compared with before-treatment $(16.96{\pm}9.23pg/ml)$ and significant increase in after 15min's $(27.27{\pm}8.81pg/ml)$ as compared with after-treatment (p<0.05). 2. There were no significant changes in plasma g-endorphin levels between male and female. 3. The human plasma $\beta-endorphin$ levels were high associated in between session reliability (p<0.05).

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Wind load estimation of super-tall buildings based on response data

  • Zhi, Lun-hai;Chen, Bo;Fang, Ming-xin
    • Structural Engineering and Mechanics
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    • v.56 no.4
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    • pp.625-648
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    • 2015
  • Modern super-tall buildings are more sensitive to strong winds. The evaluation of wind loads for the design of these buildings is of primary importance. A direct monitoring of wind forces acting on super-tall structures is quite difficult to be realized. Indirect measurements interpreted by inverse techniques are therefore favourable since dynamic response measurements are easier to be carried out. To this end, a Kalman filtering based inverse approach is developed in this study so as to estimate the wind loads on super-tall buildings based on limited structural responses. The optimum solution of Kalman filter gain by solving the Riccati equation is used to update the identification accuracy of external loads. The feasibility of the developed estimation method is investigated through the wind tunnel test of a typical super-tall building by using a Synchronous Multi-Pressure Scanning System. The effects of crucial factors such as the type of wind-induced response, the covariance matrix of noise, errors of structural modal parameters and levels of noise involved in the measurements on the wind load estimations are examined through detailed parametric study. The effects of the number of vibration modes on the identification quality are studied and discussed in detail. The made observations indicate that the proposed inverse approach is an effective tool for predicting the wind loads on super-tall buildings.

The Chemical Nature of Individual Size-resolved Raindrops and Their Residual Particles Collected during High Atmospheric Loading for PM2.5

  • Ma, Chang-Jin;Sera, Koichiro
    • Asian Journal of Atmospheric Environment
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    • v.11 no.3
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    • pp.176-183
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    • 2017
  • Although it is well known that rain plays an important role in capturing air pollutants, its quantitative evaluation has not been done enough. In this study, the effect of raindrop size on pollutant scavenging was investigated by clarifying the chemical nature of individual size-resolved raindrops and their residual particles. Raindrops as a function of their size were collected using the raindrop collector devised by our oneself in previous study (Ma et al., 2000) during high atmospheric loading for $PM_{2.5}$. Elemental analyses of solid residues and individual residual particles in raindrops were subsequently analyzed by Particle Induced X-ray Emission (PIXE) and Scanning Electron Microscopy (SEM) with Energy Dispersive X-Ray Analysis (EDX), respectively. The raindrop number concentration ($m^{-2}h^{-1}$) tended to drastically decrease as the drop size goes up. Particle scavenging rate, $R_{sca.}$ (%), based on the actual measurement values were 38.7, 69.5, and 80.8% for the particles with 0.3-0.5, 0.5-1.0, and $1.0-2.0{\mu}m$ diameter, respectively. S, Ca, Si, and Al ranked relatively high concentration in raindrops, especially small ones. Most of the element showed a continuous decrease in concentration with increasing raindrop diameter. The source profile by factor analysis for the components of residual particles indicated that the rainfall plays a valuable role in scavenging natural as well as artificial particles from the dirty atmosphere.

A Study on the Stability of Carpet by Thermal Decomposition (열분해에 의한 카펫의 안정성에 관한 연구)

  • Park, Keun-Ho;Lee, Ki-Cheol
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.147-152
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    • 2006
  • The accidents occurred by unstable material which is easily exploded or burnt up were caused by heat and collision under the condition of relatively low temperature without oxygen, have been reported frequently. However, the amount of the unstable material is getting higher by development of fine ceramic research area even though its dangerous characteristic is disregarded. This research studied a heat stability and measured boiling point of various carpet material. Carpet has been used in home as well as general indoor usage. Now a day, carpet material which is hardly burnt has been on commercial, but its detailed unstable conditions is not mentioned. This research reports the measurement of the initial temperature of generation heat and heat-radiation change on differential scanning calorimeter (DSC). The DSC data of nylon bulked continuous filament (N-BCF) yam 100%, nylon (NY), poly propylene (PP), and a new material named polytrimethylene terephthalate (PTT) are studied and researched about the effect of them using TGA, furnace, and direct-burning experiment.