• Journal of Korean Society of Environmental Engineers
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• v.36 no.8
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• pp.554-560
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• 2014

To investigate the applicability of montmorillonite to capping material for the remediation of contaminated marine sediment, adsorption characteristics of $PO{_4}{^{3-}}$ onto montmorillonite were studied in a batch system with respect to changes in contact time, initial concentration, pH, adsorbent dose amount, competing anions, adsorbent mixture, and seawater. Sorption equilibrium reached in 1 h at 50 mg/L but 3 h was required to reach sorption equilibrium at 300 mg/L. Freundlich model was more suitable to describe equilibrium sorption data than Langmuir model. The $PO{_4}{^{3-}}$ adsorption decreased as pH increased, due to the $PO{_4}{^{3-}}$ competition for favorable adsorption site with OH- at higher pH. The presence of anions such as nitrate, sulfate, and bicarbonate had no significant effect on the $PO{_4}{^{3-}}$ adsorption onto the montmorillonite. The use of the montmorillonite alone was more effective for the removal of the $PO{_4}{^{3-}}$ than mixing the montmorillonite with red mud and steel slag. The $PO{_4}{^{3-}}$ adsorption capacity of the montmorillonite was higher in seawater than deionized water, resulting from the presence of calcium ion in seawater. The water tank elution experiments showed that montmorillonite capping blocked well the elution of $PO{_4}{^{3-}}$, which was not measured up to 14 days. It was concluded that the montmirillonite has a potential capping material for the removal of the $PO{_4}{^{3-}}$ from the aqueous solutions.

• Korean Journal of Microbiology
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• v.49 no.4
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• pp.353-359
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• 2013

The objectives of this study were to investigate effectiveness of the Compressed Air Jet (CAJ) System for cleaning up shorelines contaminated with crude oils and to examine effects of the system on total petroleum hydrocarbon (TPH) removal and microbial community changes before and after remediation of the oil-contaminated shorelines. These data will lead to better understanding of optimized remediation process. About 66% of TPH reduction was observed when the contaminated site was treated with the CAJ System 2, 3, 4, and 5 times. This treatment system was more efficient than the seawater pumping system under similar treatment conditions (by 40%). By the way, little oil degrader communities were observed despite a potential function of the air jet system to stimulate aerobic oil degraders. The apparent low population density of the oil degraders might be as a result of low concentration of TPH as a carbon source and limiting nutrients such as nitrogen and phosphorus. It was proposed that the CAJ System would contribute significantly to removal of residual oils on the shorelines in combination with addition of these limiting nutrients.

• Journal of Wetlands Research
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• v.18 no.4
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• pp.363-377
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• 2016

This study was investigated the pollutant load, contamination properties, pollution condition of the fine parts of tributary, the influence of Nakdong river watershed and etc. in the tributaries. The contaminated tributaries were that among the Kumho and Nam river or were too far from site of water quality monitoring stations, regularly. As a result, the water quality level was almost similar between Nam and Kumho River, except for certain parameter including TN(Total Nitrogen), Chl-a(Chlorophyll-a) and SS(Suspended Solid) in which Kumho river were 20~120%. The point discharge load(kg/day) and load density ($kg/day/km^2$) of tributaries were different the pollution level according to the flow-rate ($m^3/sec$) and stream influence area($km^2$), and the difference of these was observed highly at Nam river. Specific contamination investigation of tributaries in Nam and Kumho river watershed was conducted from two to nine points of the fine parts of tributaries depending on the confluence sites and shapes. This result observed high at the Dalseocheon and Uriyeongcheon, respectively. Beside, the pollutant load contribution rate of Nakdong watershed was high about 10% at the Dalseocheon and Uiryeongcheon. This was due to the differences of the environments about the industrial complex, metropolis residence property, agricultural cultivation, livestock pen and the downstream of non-point source.

• Journal of Environmental Health Sciences
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• v.15 no.2
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• pp.11-23
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• 1989

This study was performed to investigate present water quality and pollution characteristics of them in the basin area of the Mankyung river near Chonju urban stream. In order to obtain the pollution characteristics of this investigation, the physio-chemical water analysis as temperature, pH, DO, BOD, Cd, Cu, Pb and Zn, and coliform group and their correlation analysis were determined from March to August 1988. The main results were summarized as follows 1. Each chemical constituent detected in three streams has the following variation range as pH(6.7-7.3), DO(1.3-8.9 mg/l), BOD(1.6-162.5mg/l) and water temperature was dominated by atmospheric temperature. 2. In three streams, concentration range of heavy metal was Cd N.D.-2.8 $\mu$g/l, Cu 1.1-10.2 $\mu$g/l, Pb 2.1-13.2 $\mu$g/l and Zn 25.6-62.2 $\mu$g/l, and was shown the order of Zn, Pb, Cu and Cd. 3. In the investigation on the bacteriological pollution-in the three streams. 1) The average number of general bacteria contaminated in the Chonju urban stream was $1.7 \times 10^{5}$ numbers/ml, which was higher than $2.6 \times 10^{2}$ numbers/ml, in the Gosan stream and 1.6 $\times$ 10 numbers/ml in the Mankyung river. 2) The average number of total coliform, fecal coliform and fecal streptococcus contaminated in the Chonju urban stream which was the highest polluted site than those of the other sampling sites were respectively $2.1 \times 10^{5}$, $2.1 \times 10^{5}$ and $9.6 \times 10^{4}$ MPN/100ml. 4. Correlation coefficient between GB and TC in the Chonju stream, Gosan stream and Mankyung river was respectively 0.99, 0.96 and 0.99, Correlation coefficient between TC and FC in Chonju stream, Gosan stream and Mankyung river was respectively 0.99, 0.97 and 0.99 and correlation coefficient between FC and TC was respectively 0.99, 0.91 and 0.99. This results mean positively dose relationship between them. 5. The occupied percentage of FC of TC in the Chonju stream, Gosan stream and Mankyung river was respectively 88.1%, 68.4% and 77.9% and the percentage of Tc of TS was respectively 43.5%, 31.6% and 41.4%. These .results was considered indicative of pollution derived from domestic wastes which had been contaminated by the feces of inhabitants and domestic animals.

• Journal of the Korean GEO-environmental Society
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• v.17 no.11
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• pp.35-43
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• 2016

In this study, by using a Effective Microorganisms Brewing Cycle, it confirmed the purification effect of pollutants that are adsorbed on the basins stench removal and retarding soil. On the basis of on-site application test, a soil decontamination system will be suggested. Using a Effective Microorganisms Brewing Cycle, the odor concentration is reduced 2.5 times than that of natural purification treatment method. It was measured and found that the quality of the pore water discharged from the soil is improved. In addition, it was found that a composite of copper and lead with the fermentation microorganisms adsorbed on soil particles from the surface of the stirred experiments lagoon mixed soil is reduced to 65% and 66%, respectively, The TPH organic component was confirmed that the reduction effect of 85%. Restoration of reservoir contaminated soils using the effective microorganism brewing cycle needs to be more developed and implemented as a long-term purification system. This study may be a good reference of developing more complete microorganism brewing system which will efficiently reduce the odor and soil contamination based on optimal stirring and mixing ratio of the compound solutions and contaminated soils in reservoir.

• Applied Chemistry for Engineering
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• v.8 no.3
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• pp.357-364
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• 1997

The objective of this study was to find optimum nonionic surfactants for clean up of soils contaminated by hydrocarbon oils. PIT(phase inversion temperature) measurements in ternary systems containing pure hydrocarbons, pure nonionic surfactants, and water were carried out and interfacial tensions were measured as a function of time for n-hexadecane oil drops brought into contact with various mixtures of nonionic surfactant and water. Batch surfactant washing experiments were performed based on the measurement, results of PIT and interfacial tension and the results showed that maximum removal of n-hexadecane occurred at the PIT of the system. For the $C_{12}E_5(C_{12}H_{25}O(CH_2CH_2O)_5H)$ system, maximum n-hexadecane removal of 73.4% occurred at the PIT of $52^{\circ}C$. In contrast, n-hexadecane removal at $25^{\circ}C$ and at $60^{\circ}C$, each corresponding to the conditions of below PIT and above PIT of the system, was found to be 57.1% and 57.0% respectively. The maximum removal of a hydrocarbon at the PIT of a system, where the hydrophilic and hydrophobic properties are balanced, was found to be due to the existence of high oil solubilization into a middle-phase microemulsion and ultralow interfacial of the order of $10^{-2}$ to $10^{-3}$ dyne/cm between middle-phase microemulsion and excess oil phase.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.7
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• pp.690-698
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• 2010

Contamination of groundwater resources by organic chemicals has become an issue of increasing environmental concern. Surfactant-enhanced aquifer remediation (SEAR) is widely recognized as one of the most promising techniques to remediate organic contaminations in-situ. Solutions of surfactant or surfactant with polymer are used to dramatically expedite the process, which in turn, may reduce the treatment time of a site compared to use of water alone. In the design of surfactant-based technologies for remediation of organic contaminated aquifers, it is very important to have a considerable analysis using extensive numerical simulations prior to full-scale implementation. This study investigated the formation and flow of microemulsions during SEAR of organic-contaminated aquifer using the finite difference model UTCHEM, a three-dimensional, multicomponent, multiphase, compositional model. The remediation process variables considered in this study were the sequence of injection fluids, the injection and extraction rate, the concentrations of polymer in surfactant slug and chase water, and the duration of surfactant injection. For each variable, temporal changes in injection and production wells and spatial distributions of relative saturations in the organic phase were compared. Cleanup time and cumulative organic recovery were also quantified. The study would provide useful information to design strategies for the remediation of nonaqueous phase liquid-contaminated aquifers.

• Journal of Soil and Groundwater Environment
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• v.7 no.2
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• pp.3-11
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• 2002

The objective of this study was to survey the oil contamination around the Mountain Baegun at Uiwang city to obtain the preliminary data for bioremediation. For measuring the oil concentrations and physical properties from soil, we analyzed BTEX. TPH and pH, organic content, water content, pormeability coefficient, gravity, porosity and used the purge & trap method for analyzing BTEX. Using the Accelerated Solvent Extractor, we pretreated the samples and then analyzed TPH using GC-FID as soon as possible. From the analysis results, maximum concentration of TPH was 24.773mg/kg and BTEX was 101.7mg/kg. The results of TPH at the Mountain Baegun were higher than the enforcement standard of soil contamination(Korea) and the BTEX concentrations were also higher than the advisory standard of soil contamination(Korea). From these results, the Mountain Baegun may requires to remedy the oil-contaminated soil. In addition, we performed the field bioremediation test for five weeks at the Mountain Baegun using the microbial additives that were developed by our laboratory. From the results of the field test, we could find the about 95% of the oil was removed from the contaminated soil in five weeks. So we consider that it is the one of the useful solutions to remedy the oil-polluted site.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.44-52
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• 2002

Low temperature thermal desorption (LTTD) has become one of the cornerstone technologies used for the treatment of contaminated soils and sediments in the United States. LTTD technology was first used in the mid-1980s for soil treatment on sites managed under the Comprehensive Environmental Respones, Compensation and Liability Act (CERCLA) or Superfund. Implementation was facilitated by CERCLA regulations that require only that spplicable regulations shall be met thus avoiding the need for protracted and expensive permit applications for thermal treatment equipment. The initial equipment designs used typically came from technology transfer sources. Asphalt manufacturing plants were converted to direct-fired LTTD systems, and conventional calciners were adapted for use as indirect-fired LTTD systems. Other innovative designs included hot sand recycle technology (initially developed for synfuels production from tar sand and oil shale), recycle sweep gas, travelling belts and batch-charged vacuum chambers, among others. These systems were used to treat soil contaminated with total petroleum hydrocarbons (TPH), polycyclic aromatic hydrocarbons (PAHs), pesticides, polychlorinated biphenyls (PCBs) and dioxin with varying degrees of success. Ultimately, performance and cost considerations established the suite of systems that are used for LTTD soil treatment applications today. This paper briefly reviews the develpoment of LTTD systems and summarizes the design, performance and cost characteristics of the equipment in use today. Designs reviewed include continuous feed direct-fired and indirect-fired equipment, batch feed systems and in-situ equipment. Performance is compared in terms of before-and-after contaminant levels in the soil and permissible emissions levels in the stack gas vented to the atmosphere. The review of air emissions standards includes a review of regulations in the U.S. and the European Union (EU). Key cost centers for the mobilization and operation of LTTD equipment are identified and compared for the different types of LTTD systems in use today. A work chart is provided for the selection of the optmum LTTD system for site-specific applications. LTTD technology continues to be a cornerstone technology for soil treatment in the U.S. and elsewhere. Examples of leading-edge LTTD technologies developed in the U.S. that are now being delivered locally in global projects are described.

• Journal of Soil and Groundwater Environment
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• v.11 no.3
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• pp.1-11
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• 2006

Attempts were made to analyze the national policy of soil contamination prevention and management of inactive or abandoned metal (IAM) mines in Korea. This approach focused on legal systems and legislation, remediation technology development, and the arrangement or distribution of budgets pertaining to national policy since the mid 1990's. Prevention of Mining Damage and Recovery Act enacted. Defines the roles, responsibility and budget of the government when recovering mine damages. However, in 2005 there still remains to improve the national policy of soil contamination prevention and management of IAM mines. Analysis of national and industrialized foreign countries including the United States, the United Kingdom, and the Netherlands suggest the following improvements: i) arranging distinct regulations between strict and non-strict liability criteria for potentially responsible parties; limiting innocent and non-strict liability depending on the period of incurred mining activity, ii) enhancing participation of local communities by enforcing law and legislation, iii) establishing a national database system of (potentially) IAM contaminated sites based on the Website-Geographic Information System, iv) carrying out site-specific risk assessments and remediation of IAM contaminated sites, v) preparation and distribution of clean-up fund at mine sites adequately, and vi) technology development for the cleaning of IAM contaminated sites; awarding positive incentives of a legal nature for participants applying newly developed technology in IAM mines.