• Title/Summary/Keyword: Contact size effect

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Evaluation of nanoscale zero valent iron filled column for nitrate reduction (영가철 나노입자가 충진된 컬럼을 이용한 질산성 질소 환원 성능 평가)

  • Hong, Youngpyoe;Seo, Younggyo;Kim, Hyowon;Hwang, Yuhoon
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.3
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    • pp.243-251
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    • 2018
  • In this study, we compared the MZVI (Microscale Zero-Valent Iron) and NZVI (Nanoscale Zero-Valent Iron) for reactivity and mobility in a column to reduce nitrate, which is a major pollutant in Korea, and investigated the effect of operational parameters on the NZVI filled column. For the comparison of MZVI and NZVI, samples were collected for 990 minutes using fractionator in the similar operation conditions (MZVI 10g, NZVI 2g). The nitrate reduction efficiency of NZVI was about 5 times higher than that of MZVI, which was about 7.45% and 38.75% when using MZVI and NZVI, respectively. In the mobility experiment, the MZVI descended due to gravity while NZVI moved up with water flow due to its small size. Furthermore, the optimum condition of NZVI filled column was determined by changing the flow rate and pH. The amount of Fe ions was increased as the pH of the nitrate solution was lowered, and the nitrate removal rate was similar due to the higher yield of hydroxyl groups. The removal rate of nitrate nitrogen was stable while flow rate was increased from 0.5 mL/min to 2.0 mL/min (empty bed contact time: 2.26 min to 0.57 min). NZVI has a high reduction rate of nitrate, but it also has a high mobility, so both of reactivity and mobility need to be considered when NZVI is applied for drinking water treatment.

Nano-scale Friction Properties of SAMs with Different Chain Length and End Groups

  • R.Arvind Singh;Yoon Eui-Sung;Han, Hung-Gu;Kong, Ho-Sung
    • KSTLE International Journal
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    • v.6 no.1
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    • pp.13-16
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    • 2005
  • Friction characteristics at nano-scale of self-assembled monolayers (SAMs) having different chain lengths and end groups were experimentally studied.51 order to understand the effect of the chain length and end group on the nano-scalefriction: (1) two different SAMs of shorter chain lengths with different end groups such as methyl and phenyl groups, and (2)four different kinds of SAMs having long chain lengths (C10) with end groups of fluorine and hydrogen were coated on siliconwafer (100) by dipping method and Chemical Vapour Deposition (CVD) technique. Their nano-scale friction was measuredusing an Atomic Force Microscopy (AFM) in the range of 0-40 nN normal loads. Measurements were conducted at the scanning speed of 2 $mu$m/s for the scan size of 1$mu$m x 1 $mu$m using a contact mode type $Si_3N_4$ tip (NPS 20) that had a nominal spring constant0.58 N/m. All experiments were conducted at anlbient temperature (24 $pm$1$circ$C) and relative humidity (45 $pm$ 5%). Results showedthat the friction force increased with applied normal load for all samples, and that the silicon wafer exhibited highest frictionwhen compared to SAMs. While friction was affected by the inherent adhesion in silicon wafer, it was influenced by the chainlength and end group in the SAMs. It was observed that the nano-friction decreased with the chain length in SAMs. In the caseof monolayers with shorter length, the one with the phenyl group exhibited higher friction owing to the presence of benBenerings that are stiffer in nature. In the case of SAMs with longer chain length, those with fluorine showed friction values relativelyhigher than those of hydrogen. The increase in friction due to the presence of fluorine group has been discussed with respect tothe siBe of the fluorine atom.

A Study on the Watertightness Improvement of Cementitious Material for Durability Improvement of Concrete (콘크리트 내구성 향상을 위한 시멘트 재료의 수밀성 개선에 관한 연구)

  • Kang, Hyun-Ju;Song, Myong-Shin;Jeong, Eui-Dam
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.5
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    • pp.17-25
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    • 2010
  • We studied on the watertightness improvement of cementitious material for durability enhancement of concrete. For improvement of watertightness of OPC and OPC with fly ash, we used various materials with watertightness properties to OPC and OPC with fly ash. The performance of watertightness improvement of cementitious materials closely related to formation of CSH by pozzolanic reaction and to reducing of size of contact angle in cement pore by using organic fatty acid. And volume of CSH formation at early hydration have an influence of watertightness improvement and reduction of long-term water absorption rate. In using of fly ash, improvement of workability by using the spherical fly ash caused to densify on the structures of cement material and CSH formation by pozzolanic reaction and cement using fly ash also caused watertightness improvement of cementitious materials. For improvement of concrete durability by watertightness, cementitious materials need using watertightness materials and at using fly ash, also it have to the effect of improvement of watertightness of cementitious materials by pozzolanic reaction.

A Study on Orbital Forming Analysis of Automotive Hub Bearing using the Explicit Finite Element Method (외연적 유한요소법을 이용한 자동차 Hub Bearing의 Orbital Forming해석에 관한 연구)

  • Cho, Hyun-Jik;Koo, Jeong-Seo;Bae, Won-Rak;Lim, Jong-Soon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.1
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    • pp.29-36
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    • 2008
  • In this paper, the orbital forming analysis of an automotive hub bearing was studied to predict forming performances using the explicit finite element method. To find an efficient solution technique for the orbital forming, axisymmetric finite element models and 3D solid element models were solved and numerically compared. The time scaling and mass scaling techniques were introduced to reduce the excessive computational time caused by small element size in case of the explicit finite element method. It was found from the numerical simulations on the orbital forming that the axisymmetric element models showed the similar results to the 3D solid element models in forming loads whereas the deformations at the inner race of bearing were quite different. Finally the strains at the inner race of bearing and the forming forces to the peen were measured for the same product of the numerical model by test, and were compared with the 3D solid element results. It was founded that the test results were in good agreements with the numerical ones.

Design Optimization of M8 Blind Rivet Nut Geometry using Finite Element Analysis (유한요소해석을 이용한 M8 블라인드 리벳 너트 형상 최적 설계)

  • Gu, B.;Choi, J.M.;Hong, S.
    • Transactions of Materials Processing
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    • v.29 no.3
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    • pp.157-162
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    • 2020
  • Blind rivet nuts are increasingly used in automotive for the joining of sheets. Their application, however, requires appropriate design guides to prevent catastrophic events arising from the failure of joints. In this study, the shaft shape of a frequently used M8 blind rivet nut is optimized based on 3D numerical analysis of the blind rivet nut considering the characteristics of thread. The thread needs to be modeled to suitably consider the fastening of the M8 bolt after the crimping process. FE analysis showed that while the friction in the contact between crimp flange and plate has no significant effect on the crimp geometry, shaft thickness (t) and shaft height (h) are the most significant design variables. The parameter study including various combinations of t and h reveals that they affect the gap (the distance between the crimped flange and the plate that develops through riveting) and the load acting on the plate. The gap is an indicator of the tightening force. It is found that t is inversely proportional to the gap, and proportional to the load, whereas h is proportional to the gap and inversely proportional to the load. Based on our FE analysis results, we propose the range 0.062 < t/h < 0.1 to ensure sufficient fastening (high clamping load, small gap) of the M8 blind rivet nut. The design guide for determining the t/h ratio proposed in this study can be used for general quantitative analysis of the size and the t/h ratio of blind rivet nuts.

Elastic Properties Evaluation of Thin Films on Flexible Substrates with Consideration of Contact Morphology in Nanoindentation (나노압입시험에서의 접촉형상 보정을 통한 유연소자 박막의 탄성특성 평가)

  • Kim, Won Jun;Hwang, Gyeong-Seok;Kim, Ju-Young;Kim, Young-Cheon
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.3
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    • pp.83-88
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    • 2020
  • The evolution of smartphones has led to numerous researches in the mechanical behavior of flexible devices. Due to the nano-size of the thin flexible film, nanoindentation is widely used to evaluate its mechanical behaviors, such as elastic modulus, and hardness. However, the commonly used Oliver-Pharr method is not suited for analyzing the indentation force-depth curves of hard films on soft substrates, as the effects of soft substrate is not considered theoretically. In this study, the elastic modulus of the thin film was evaluated with references to other reported models which include the substrate effect, and with calibration of the indentation depth for the pile-ups between the indenter and test surface. We fabricated test samples by deposition of amorphous metal film on polyimide and silicon wafers for verification of modified models.

Electrochemical Etching of Silicon in Porous Silicon Layer Transfer Process for Thin Film Solar Cell Fabrication (초박형 태양전지의 Porous Si Layer Transfer 기술 적용을 위한 전기화학적 실리콘 에칭)

  • Lee, Ju-Young;Han, Wone-Keun;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.4
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    • pp.55-60
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    • 2009
  • Porous silicon film is fabricated by electrochemical etching in a chemical mixture of HF and ethanol. Effects of Si type, Si resistivity, ultrasonic frequency, current density and etching time on surface morphology of PS film were studied. Electrochemical etching in ultrasonic bath promotes the uniformity of porous layer of Si. Frequency of ultrasonic was increased from 40 kHz to 130 kHz to obtain uniform pores on the Si surface. When current density was higher, the sizes of pores were larger. The new etching cell using back contact metal and current shield help to overcome nonhomogeneity and current crowding effect, and then leads to fabricate uniform pores on the Si surface. The distribution of pore size shows no notable tendency with etching time.

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Product Analysis and Development of Amblyopia Eye Patch for Children

  • Lim, Hosun;Sung, Juyoung
    • Fashion, Industry and Education
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    • v.14 no.2
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    • pp.1-10
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    • 2016
  • In the present study, the materials, sizes, and designs of blind eye patch products of skin-adhesive type and glass-attachment type currently available in the market will be analyzed and ergonomically appropriate blind eye patches will be developed. Although these skin-adhesive type eye patches were easy to use, they had shortcomings such as skin troubles due to the adhesive used on the weak and sensitive skin of children and the fact that eyebrows are pulled out and the skin is irritated when the eye patches are detached after being attached. The non-adhesive type eye patches were blind patches to be worn by putting into glasses. These products were made using diverse materials such as neoprene, non-woven fabrics, and felt and showed differences in tactile impressions and irritation to the skin depending on material characteristics. In addition, most products were efficient in blocking light with three-dimensional oval designs comprising darts. In the present study, blind eye patches were designed to reduce skin troubles by using sweat-absorbing and quick-drying functional materials with soft tactile impressions. In addition, to increase the effect to block light and the degree of tight contact with the skin when the blind eye patches are worn compared to existing eye patch designs, the sides of the wings of the blind eye patches were widened, glass frame fixing plates were added, and the darts were made to be curved thereby making an ergonomic design reflecting the shape of the face. The non-adhesive type blind eye patches developed in the present study are considered to enhance the wearing sensation with the use of the material without skin irritation but with cushioning feelings and the ergonomic design reflecting the contour of the face.

Rigid-Plastic Explicit Finite Element Formulation for Two-Dimensional Analysis of Sheet Metal Forming Processes (2차원 박판성형공정 해석을 위한 강소성 외연적 유한요소 수식화)

  • An, Dong-Gyu;Jeong, Dong-Won;Jeong, Wan-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.1
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    • pp.88-99
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    • 1996
  • The explicit scheme for finite element analysis of sheet metal forming problems has been widely used for providing practical solutions since it improves the convergency problem, memory size and computational time especially for the case of complicated geometry and large element number. The explicit schemes in general use are based on the elastic-plastic modeling of material requiring large computataion time. In the present work, a basic formulation for rigid-plastic explicit finite element analysis of plain strain sheet metal forming problems has been proposed. The effect of some basic parameters involved in the dynamic analysis has been studied in detail. Thus, the effective ranges of parameters have been proposed for numerical simultion by the rigid-plastic explicit finite element method. A direct trial-and-error method is introduced to treat contact and friction. In computation, sheet material is assumed to possess normal anisotropy and rigid-plastic workhardening characteristics. In order to show the validity and effectiveness of the proposed explicit scheme, computations are carried out for cylindrical punch stretching and the computational results are compared with those by the implicit scheme as well as with a commercial code. The proposed rigid-plastic exlicit finite element method can be used as a robust and efficient computational method for analysis of sheet metal forming.

Synthesis of Multiwall Carbon Nanotube/Graphene Composite by Aerosol Process and Its Characterization for Supercapacitors (에어로졸 공정에 의한 Multiwall carbon nanotube/Graphene 복합체 제조 및 슈퍼커패시터 특성평가)

  • Jo, Eun Hee;Kim, Sun Kyung;Chang, Hankwon;Lee, Chong Min;Park, Su-Ryeon;Choi, Ji-hyuk;Jang, Hee Dong
    • Particle and aerosol research
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    • v.12 no.4
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    • pp.127-134
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    • 2016
  • A multiwall carbon nanotube (MWCNT)/graphene (GR) composite was synthesized for an enhanced supercapacitor. Aerosol spray pyrolysis (ASP) was employed to synthesize the MWCNT/GR composites using a colloidal mixture of MWCNT and graphene oxide (GO). The effect of the weight ratio of the MWCNT/GO on the particle properties including the morphology and layered structure were investigated. The morphology of MWCNT/GR composites was generally the shape of a crumpled paper ball, and the average composite size was about $5{\mu}m$. MWCNT were uniformly dispersed in GR sheets and the MWCNT not only increase the basal spacing but also bridge the defects for electron transfer between GR sheets. Thus, it was increasing electrolyte/electrode contact area and facilitating transportation of electrolyte ion and electron in the electrode. Electrochemical data demonstrate that the MWCNT/GR (weight ratio=0.1) composite possesses a specific capacitance of 192 F/g at 0.1 A/g and good rate capability (88% capacity retention at 4 A/g) using two-electrode testing system.