• Title/Summary/Keyword: Constituent materials

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Analysis of quasi-brittle materials at mesoscopic level using homogenization model

  • Borges, Dannilo C;Pituba, Jose J C
    • Advances in concrete construction
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    • v.5 no.3
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    • pp.221-240
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    • 2017
  • The modeling of the mechanical behavior of quasi-brittle materials is still a challenge task, mainly in failure processes when fracture and plasticity phenomena become important actors in dissipative processes which occur in materials like concrete, as instance. Many homogenization-based approaches have been proposed to deal with heterogeneous materials in the last years. In this context, a computational homogenization modeling for concrete is presented in this work using the concept of Representative Volume Element (RVE). The material is considered as a three-phase material consisting of interface zone (ITZ), matrix and inclusions-each constituent modeled by an independent constitutive model. The Representative Volume Element (RVE) consists of inclusions idealized as circular shapes symmetrically and nonsymmetrically placed into the specimen. The interface zone is modeled by means of cohesive contact finite elements. The inclusion is modeled as linear elastic and matrix region is considered as elastoplastic material. A set of examples is presented in order to show the potentialities and limitations of the proposed modeling. The consideration of the fracture processes in the ITZ is fundamental to capture complex macroscopic characteristics of the material using simple constitutive models at mesoscopic level.

Evaluation of Metal-mold Reactions and Fluidity of TiAl Alloys (TiAl 합금의 주형계면반응 및 유동성 평가)

  • Lee, Sang-Hwa;Sung, Si-Young;Choi, Bong-Jae;Kim, Myoung-Gyun;Kim, Young-Jig
    • Journal of Korea Foundry Society
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    • v.26 no.2
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    • pp.98-103
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    • 2006
  • Metal-mold reactions between investment mold and TiAl alloys were investigated for the economic net-shape forming of TiAl alloys. The effect of mold preheating temperatures on the metal-mold reaction were investigated using a vacuum induction-melting furnace. In the case of TiAl alloys, there were no ${\alpha}$-case formation reactions. There were neither interstitial nor substitutional ${\alpha}$-case formations as TiAl alloys have both negligible solubility of oxygen and low activity in molten states. The fluidity of TiAl alloys increases with mold preheating temperature since they have a peritectic reaction that appears in the form of envelope, surrounding each particles of the primary constituent. The results of the investment casting of TiAl alloys confirm that the casting route in our study can be an effective approach for the economic net-shape forming of TiAl alloys.

Oligothiophene-based Semi-Conducting Nanostructures: from Solution to Solid-State Aggregates

  • Leclere, Ph.;Surin, M.;Lazzaroni, R.;Feast, W.J.;Schenning, A.P.H.J.;Meijer, E.W.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.304-304
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    • 2006
  • The possibility to develop optoelectronic devices with improved properties by controlling the degree of organization at the molecular level of organic materials has been driving the design of new ${\pi}-conjugated$ systems. In particular, the organization by self-assembling processes (${\tilde{\Box}}{\d{\Box}}}$ interactions, hydrogen bonding) of well-defined oligomeric systems such as disubstituted oligothiophene derivatives has been demonstrated as a promising approach to conjugated materials with a high degree of structural order of the constituent building blocks. The self-organization of conjugated building blocks in solution or on surfaces, leading to the construction of nanoscopic and mesoscopic architectures, represents a starting point for the construction of molecular electronics or even circuits, through surface patterning with nanometer-sized objects.

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The Vibration Analysis of Composite-VEM Thin-Walled Rotating Beam Using GHM Methodology (회전하는 복합재-VEM 박판보의 GHM 기법을 이용한 진동해석)

  • 박재용;나성수
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.05a
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    • pp.337-341
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    • 2004
  • This paper concerns the analytical modeling and dynamic analysis of advanced rotating blade structure implemented by a dual approach based on structural tailoring and viscoelastic materials technology. Whereas structural tailoring uses the directionality properties of advanced composite materials, the passive materials technology exploits the damping capabilities of viscoelastic material(VEM) embedded into the host structure. The structure is modeled as a composite thin-walled beam incorporating a number of nonclassical features such as transverse shear, warping restraint, anisotropy of constituent materials, and warping and rotary inertias. The VEM layer damping treatment is modeled by using the Golla-Mushes-McTavish(GHM) method, which is employed to account for the frequency-dependent characteristic o the VEM. The displayed numerical results provide a comprehensive picture of the synergistic implications of the application of both techniques, namely, the tailoring and damping technology on vibration response of thin-walled beam structure exposed to external time-dependent excitations.

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Electromigration in Molten-phase Ge2Sb2Te5 and Effects of Doping on Atomic Migration Rate

  • Joo, Young-Chang;Yang, Tae-Youl;Cho, Ju-Young;Park, Yong-Jin
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.43-47
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    • 2012
  • Electromigration in molten $Ge_2Sb_2Te_5$ (GST) was characterized using pulsed DC stress to an isolated line structure. When an electrical pulse was applied to the GST, GST lines were melted by Joule heating, and Ge and Sb atoms migrate to the cathode, whereas Te atoms migrate to the anode. This elemental separation in the molten GST was caused by an electrostatic force-induced electromigration. The effects of O-, N-, and Bi-doping on the electromigration were also investigated, and atomic mobility changes by the doping were investigated by quantifying $DZ^*$ values. The Bi -doping did not affect the $DZ^*$ values of the constituent atoms in the molten GST, but the D$DZ^*$ values decreased by O-doping and N-doping.

An Investigation into the Characteristics of the Burial Ground Materials around Mummies in Andong (안동 미이라 지역 매장지반재료의 특성규명)

  • 황지호;김성수;박형동
    • Economic and Environmental Geology
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    • v.33 no.5
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    • pp.435-442
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    • 2000
  • Although the mummies of Lee Myeong-Jung and his wife who were a member of the Moon family, were buried in similar sites in around 1560, the degree of decay of the dead bodies and antiquities between two people were quite different. This study was focused on the cause of-those differences in terms of engineering geology. Cranular soil found several metered depth around the study site has good drainage ability and such characteristic could be a factor of excellent conservation of dead body. From the physical characteristics of the lime-containing material that is considered to be a barrier from water and air, it was observed that the material around dead body of wife was more compact and denser than that of husband. Such results could be a clear evidence that the lime containing material around dead body of wife was excellent barrier for keeping away from water and air. To investigate those differences of physical characteristics and constituent materials between two lime-containing materials, minerals had to be identified from the two materials. It was revealed that lime-containing material around dead body of wife contains gypsum and more calcite, which could be the reason for better barrier preventing from water and air than those around husband.

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Pharmacological Effects of Asaronaldehyde Isolated from Acorus gramineus Rhizome

  • Kim, Hyo-Gyung;Jeon, Ju-Hyun;Kim, Moo-Key;Lee, Hoi-Seon
    • Food Science and Biotechnology
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    • v.14 no.5
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    • pp.685-688
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    • 2005
  • Antibacterial and antiplatelet activities of Acorus gramineus rhizome-derived asaronaldehyde and asaron were analyzed using platelet aggregometer and six human intestinal bacteria. Active constituent of A. gramineus rhizome was isolated and characterized as asaronaldehyde by spectral analyses. At 2 and 1 mg/disk, asaronaldehyde exhibited strong inhibition of Clostridium perfringens and C. difficile without adverse effects on growth of beneficial bacteria such as Bifidobacterium bifidum, Lactobacillus acidophilus, and L. casei. Asaron also revealed moderate growth inhibition against C. perfringens and C. difficile at 2 mg/disk, no growth-inhibiting activity was observed on B. bifidum, L. acidophilus, L. casei, and E. coli. At 50% inhibitory concentration ($IC_{50}$) value, asaronaldehyde was effective in inhibiting platelet aggregation induced by collagen ($IC_{50}$, $27.6\;{\mu}M$) and arachidonic acid ($IC_{50}$, $53.7\;{\mu}M$). These results suggest asaronaldehyde may be useful as lead compound for inhibiting platelet aggregation induced by collagen and arachidonic acid.

Fabrication of YBCO films in MOD processing via chemically modified precursor solution (화학적으로 변형된 전구용액을 이용한 YBCO 박막 제조)

  • Kim, Y.K.;Yoo, J.M.;Chung, K.C.;Ko, J.W.;Kim, Y.J.;Han, B.S.
    • Progress in Superconductivity
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    • v.7 no.2
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    • pp.158-161
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    • 2006
  • Superconducting YBCO films were successfully fabricated by MOD process using chemically modified precursor solution. In this study, a chemically modified precursor solution for MOD processing was synthesized using metal-organic salts and organic additives. It was shown that crack-free and uniform precursor films were formed after calcination in humidified Oxygen atmosphere. Less than 3 hours are required to finish the calcination process. XRD measurement shows that $BaF_2,\;CuO,\;Y_2O_3$ are major constituent of precursor films. Furthermore, YBCO films without any secondary phases were successfully fabricated after annealing in wet $Ar/O_2$ atmosphere. The YBCO film prepared on a $LaAlO_3$ single crystal substrate ($10mm{\times}10mm$) gives transport $I_c$ of 10A at 77K. This chemical modification approach is a possible candidate for improving MOD-processing of YBCO coated conductor.

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Rapid Synthesis and Consolidation of Nanostructured Ti-TiC Composites from TiH2 and CNT by Pulsed Current Activated Heating

  • Park, Na-Ra;Shon, In-Jin
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.48-53
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    • 2015
  • $TiH_2$ nanopowder was made by high energy ball milling. The milled $TiH_2$ and CNT powders were then simultaneously synthesized and consolidated using pulsed current activated sintering (PCAS) within one minute under an applied pressure of 80 MPa. The milling did not induce any reaction between the constituent powders. Meanwhile, PCAS of the $TiH_2$-CNT mixture produced a Ti-TiC composite according to the reaction ($0.92TiH_2+0.08CNT{\rightarrow}0.84Ti+0.08TiC+0.92H_2$, $0.84TiH_2+0.16CNT{\rightarrow}0.68Ti+0.16TiC+0.84H_2$). Highly dense nanocrystalline Ti-TiC composites with a relative density of up to 99.7% were obtained. The hardness and fracture toughness of the dense Ti-8 mole% TiC and Ti-16 mole% TiC produced by PCAS were also investigated. The hardness of the Ti-8 mole% TiC and Ti-16 mole% TiC composites was higher than that of Ti. The hardness value of the Ti-16 mole% TiC composite was higher than that of the Ti-8 mole% TiC composite without a decrease in fracture toughness.

Surface Tension of Molten Ag-Sn and Au-Cu Alloys at Different Oxygen Partial Pressures (다양한 산소분압에 따른 용융 Ag-Sn 및 Ag-Cu 합금의 표면장력)

  • Min, Soon-Ki;Lee, Joon-Ho
    • Korean Journal of Materials Research
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    • v.19 no.1
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    • pp.13-17
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    • 2009
  • A semi-empirical method to estimate the surface tension of molten alloys at different oxygen partial pressures is suggested in this study. The surface tension of molten Ag-Sn and Ag-Cu alloys were calculated using the Butler equation with the surface tension value of pure substance at a given oxygen partial pressure. The oxygen partial pressure ranges were $2.86{\times}10^{-12}$$1.24{\times}10^{-9}$ Pa for the Ag-Sn system and $2.27{\times}10^{-11}$$5.68{\times}10^{-4}$ Pa for the Ag-Cu system. In this calculation, the interactions of the adsorbed oxygen with other metallic constituents were ignored. The calculated results of the Ag-Sn alloys were in reasonable accordance with the experimental data within a difference of 8%. For the Ag-Cu alloy system at a higher oxygen partial pressure, the surface tension initially decreased but showed a minimum at $X_{Ag}$ = 0.05 to increase as the silver content increased. This behavior appears to be related to the oxygen adsorption and the corresponding surface segregation of the constituent with a lower surface tension. Nevertheless, the calculated results of the Ag-Cu alloys with the present model were in good agreement with the experimental data within a difference of 10%.