• Title/Summary/Keyword: Constant rate model

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Modeling the effects of excess water on soybean growth in converted paddy field in Japan 1. Predicting groundwater level and soil moisture condition - The case of Biwa lake reclamation area

  • Kato, Chihiro;Nakano, Satoshi;Endo, Akira;Sasaki, Choichi;Shiraiwa, Tatsuhiko
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.315-315
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    • 2017
  • In Japan, more than 80 % of soybean growing area is converted fields and excess water is one of the major problems in soybean production. For example, recent study (Yoshifuji et al., 2016) suggested that in the fields of shallow groundwater level (GWL) (< 1m depth), rising GWL even in a short period (e.g. 1 day) causes inhibition of soybean growth. Thus it becomes more and more important to predict GWL and soil moisture in detail. In addition to conventional surface drainage and underdrain, FOEAS (Farm Oriented Enhancing Aquatic System), which is expected to control GWL in fields adequately, has been developed recently. In this study we attempted to predict GWL and soil moisture condition at the converted field with FOEAS in Biwa lake reclamation area, Shiga prefecture, near the center of the main island of Japan. Two dimensional HYDRUS model (Simuinek et al., 1999) based on common Richards' equation, was used for the calculation of soil water movement. The calculation domain was considered to be 10 and 5 meter in horizontal and vertical direction, respectively, with two layers, i.e. 20cm-thick of plowed layer and underlying subsoil layer. The center of main underdrain (10 cm in diameter) was assumed to be 5 meter from the both ends of the domain and 10-60cm depth from the surface in accordance with the field experiment. The hydraulic parameters of the soil was estimated with the digital soil map in "Soil information web viewer" and Agricultural soil-profile physical properties database, Japan (SolphyJ) (Kato and Nishimura, 2016). Hourly rainfall depth and daily potential evapo-transpiration rate data were given as the upper boundary condition (B.C.). For the bottom B.C., constant upward flux, which meant the inflow flux to the field from outside, was given. Seepage face condition was employed for the surrounding of the underdrain. Initial condition was employed as GWL=60cm. Then we compared the simulated and observed results of volumetric water content at depth of 15cm and GWL. While the model described the variation of GWL well, it tended to overestimate the soil moisture through the growing period. Judging from the field condition, and observed data of soil moisture and GWL, consideration of soil structure (e.g. cracks and clods) in determination of soil hydraulic parameters at the plowed layer may improve the simulation results of soil moisture.

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Adsorption Equilibrium, Kinetics and Thermodynamic Parameters Studies of Bismarck Brown R Dye Adsorption on Granular Activated Carbon (입상 활성탄에 대한 비스마르크 브라운 R 염료의 흡착평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.327-332
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    • 2013
  • Batch experiments were carried out for adsorption equilibrium, kinetics and thermodynamic parameters of the brilliant brown R onto granular activated carbon. The operating variables studied were the initial dye concentration, contact time and temperature. Experimental equilibrium adsorption data were fitted to Langmuir and Freundlich adsorption isotherm by linear regression method. The equilibrium process was well described by Freundlich isotherm model and from the determined separation factor (1/n), granular activated carbon could be employed as an effective treatment for the removal of bismarck brown R. From kinetic experiments, the adsorption processes were found to confirm the pseudo second order model with a good correlation and the adsorption rate constant ($k_2$) increased with increasing adsorption temperature. Thermodynamic parameters like the activation energy, change of Gibbs free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption in the temperature range of 298~318 K. The activation energy was determined as 8.73 kJ/mol for 100 mg/L. It was found that the adsorption of bismarck brown R on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G$ = -2.59~-4.92 kJ/mol) and the positive enthalpy change (${\Delta}H$ = +26.34 kJ/mol) are indicative of the spontaneous and endothermic nature of the adsorption process.

Numerical Analysis of EPB TBM Driving using Coupled DEM-FDM Part II : Parametric Study (개별요소법과 유한차분법 연계 해석을 이용한 EPB TBM 굴진해석 Part II: 매개변수 해석)

  • Choi, Soon-wook;Lee, Hyobum;Choi, Hangseok;Chang, Soo-Ho;Kang, Tae-Ho;Lee, Chulho
    • Tunnel and Underground Space
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    • v.30 no.5
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    • pp.496-507
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    • 2020
  • A prediction of the performance of EPB TBM is significant for improving the constructability of tunnels. Thus, various attempts to simulate TBM excavation by the numerical method have been made until these days. In this paper, to evaluate the performance of TBM with different operating conditions, a parametric study was carried out using coupled discrete element method (DEM) and finite difference method (FDM) EPB TBM driving model. The analysis was conducted by changing the penetration rate (0.5 and 1.0 mm/sec) and the rotational speed of screw conveyor (5, 15, and 25 rpm) while the rotation velocity of the cutter head kept constant at 2 rpm. The torque, thrust force, chamber pressure, and discharging with different TBM operating conditions were compared. The result of parametric study shows that the optimum driving condition can be determined by the coupled DEM-FDM numerical model.

Experimental Investigation of Effects of Sediment Concentration and Bed Slope on Debris Flow Deposition in Culvert (횡단 배수로에서 토석류 퇴적에 대한 유사농도와 바닥경사 영향 실험연구)

  • Kim, Youngil;Paik, Joongcheol
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.5B
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    • pp.467-474
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    • 2011
  • Debris flow is one of the most hazardous natural processes in mountainous regions. The degradation of discharge capacity of drainage facilities due to debris flows may result in damages of properties and casualty as well as road. Understanding and accurate reproducing flow behaviour of debris flows at various conditions, such as sediment volume concentration and approaching channel and culvert slopes, are prerequisite to develop advanced design criteria for drainage facilities to prevent such damages. We carried out a series of laboratory experiments of debris flows in a rectangular channel of constant width with an abrupt change of bottom slope. The experimental flume consists of an approaching channel part with the bed slope ranging $15^{\circ}$ to $30^{\circ}$ and the test channel with slope ranging from $0^{\circ}$ to $12^{\circ}$ which mimics a typical drainage culvert. The experiments have been conducted for 22 test cases with various flow conditions of channel slopes and sediment volume concentration of debris flows to investigate those effects on the behaviour of debris flows. The results show that, according to sediment volume concentration, the depth of debris flow is approximately 50% to 150% larger than that of fresh water flow at the same flow rate. Experimental results quantitatively present that flow behaviour and deposit history of debris flows in the culvert depend on the slopes of the approaching and drainage channels and sediment volume concentration. Based on the experimental results, furthermore, a logistic model is developed to find the optimized culvert slope which prevents the debris flow from depositing in the culvert.

Characteristics of Isotherm, Kinetic, and Thermodynamic Parameters for Reactive Blue 4 Dye Adsorption by Activated Carbon (활성탄에 의한 Reactive Blue 4 염료의 흡착에 대한 등온선, 동력학 및 열역학적 특성)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.26 no.2
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    • pp.122-130
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    • 2020
  • The isotherm, kinetic, and thermodynamic parameters of reactive blue 4 adsorbed by activated carbon were investigated for activated carbon dose, pH, initial concentration, contact time, and temperature data. The adsorption of the RB 4 dye by activated carbon showed a concave shape in which the percentage of adsorption increased in both directions starting from pH 7. The isothermal adsorption data were applied to Langmuir, Freundlich, and Temkin isotherms. Both Freundlich and Langmuir isothermal adsorption models fit well. From determined Freundlich separation factor (1/n = 0.125 ~ 0.232) and Langmuir separation factor (RL = 1.53 ~ 1.59), adsorption of RB 4 by activated carbon could be employed as an effective treatment method. The constant related to the adsorption heat (BT = 2.147 ~ 2.562 J mol-1) of Temkin showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo second order model with good agreement. The results of the intraparticle diffusion model showed that the inclination of the first straight line representing the surface diffusion was smaller than that of the second straight line representing the intraparticle pore diffusion. Therefore, it was confirmed that intraparticle pore diffusion is the rate-controlling step. The negative Gibbs free energy change (ΔG = -3.262 ~ -7.581 kJ mol-1) and the positive enthalpy change (ΔH = 61.08 kJ mol-1) indicated the spontaneous and endothermic nature of the adsorption process, proving this process to be spontaneous and endothermic.

Development of Improvement Effect Prediction System of C.G.S Method based on Artificial Neural Network (인공신경망을 기반으로 한 C.G.S 공법의 개량효과 예측시스템 개발)

  • Kim, Jeonghoon;Hong, Jongouk;Byun, Yoseph;Jung, Euiyoup;Seo, Seokhyun;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.9
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    • pp.31-37
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    • 2013
  • In this study installation diameter, interval, area replacement ratio and ground hardness of applicable ground in C.G.S method should be mastered through surrounding ground by conducting modeling. Optimum artificial neural network was selected through the study of the parameter of artificial neural network and prediction model was developed by the relationship with numerical analysis and artificial neural network. As this result, C.G.S pile settlement and ground settlement were found to be equal in terms of diameter, interval, area replacement ratio and ground hardness, presented in a single curve, which means that the behavior pattern of applied ground in C.G.S method was presented as some form, and based on such a result, learning the artificial neural network for 3D behavior was found to be possible. As the study results of artificial neural network internal factor, when using the number of neural in hidden layer 10, momentum constant 0.2 and learning rate 0.2, relationship between input and output was expressed properly. As a result of evaluating the ground behavior of C.G.S method which was applied to using such optimum structure of artificial neural network model, is that determination coefficient in case of C.G.S pile settlement was 0.8737, in case of ground settlement was 0.7339 and in case of ground heaving was 0.7212, sufficient reliability was known.

Production of Activated Carbon from Waste Walnut Shell Using Phosphoric Acid and Its Adsorption Characteristics for Heavy Metal Ion (인산활성화제에 의한 폐호도껍질을 원료로 한 활성탄제조 및 이의 중금속 이온 흡착특성)

  • Lee Go-Eun;Ahn Ju-Hyun;Kim Dong-Su
    • Resources Recycling
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    • v.12 no.3
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    • pp.13-24
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    • 2003
  • The production characteristics of activated carbon from waste walnut shell have been investigated by taking activation temperature, activation time, amount of activating agent, and kind of activating agent as the major influential factors. The adsorption capacity of the activated carbon which was produced using phosphoric acid as the activating agent increased with activation temperature and showed its greatest value at about $550^{\circ}C$. Yield for activated carbon was observed to decrease continuously as the activation temperature was raised. The optimal activation time for the highest adsorption capacity was found to be about 2 hr, and as the activation time increased the yield for activated carbon was showed to decrease continuously. The increase in the amount of activating agent resulted in the increase of the yield for activated carbon, however, excessive amount of activating agent deteriorated its adsorption capacity reversely. The variations of the microstructure of activated carbon observed by SEM with several influential factors, correlated very well with its changes in the adsorbability with the same factors and the kind of activating agent was found to play an important role in the determination of the adsorption capacity of activated carbon. To investigate the adsorption characteristics of the produced activated carbon, the adsorption reactions of $Cu^{2+}$ ion were examined using the produced activated carbon as the adsorbent. In general, the kinetics of the adsorption of $Cu^{2+}$ ion was observed to follow a 2nd-order reaction and the rate constant for adsorption reaction increased as the initial concentration of adsorbate was diminished. The equilibrium adsorption of $Cu^{2+}$ was explained well with Freundlich model and its adsorption reaction was found to be endothermic. The activation energy for adsorption was calculated to be 13.07 kcal/mol, which implied that the adsorption reaction was very irreversible, and several thermodynamic parameters of adsorption reaction were estimated using van't. Hoff equation and thermodynamic relationships.

Pillar Width of Twin Tunnels in Horizontal Jointed Rock Using Large Scale Model Tests (대형모형실험을 통한 수평 절리암반에서의 병설터널 이격거리)

  • Lee, Yong-Jun;Lee, Sang-Duk
    • Tunnel and Underground Space
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    • v.20 no.5
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    • pp.352-359
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    • 2010
  • Stability of twin tunnels depends on the pillar width and the ground condition. In this study, large scale model tests were conducted for investigating the influence of the pillar width of twin tunnels on their behavior in the regular horizontal jointed rock mass. Jointed rocks was composed of concrete blocks. Pillar width of twin tunnels varied in 0.29D, 0.59D, 0.88D and 1.18D, where D is the tunnel width. During the test, pillar stress, lining stress, tunnel distortion, and ground displacement were measured. Lateral earth pressure coefficient was kept in a constant value 1.0. As a result, it was found that the pillar stress and the displacement of the ground and tunnel were increased by decreasing pillar width. The maximum displacement rate was measured just after the upper excavation in each construction sequence. And the maximum influence position was the right shoulder of the preceeding tunnel at the pillar side. It was also found that for the stability assessment the inner displacement was more critical than the crown displacement. The influence zone was formed at the pillar width 0.59D~0.88D that was smaller than 0.8D~2.0D, which was proposed by experience for a good ground condition. And it would be concluded that horizontal joints could also influence on the stability of the twin tunnels.

Equilibrium, Kinetics and Thermodynamic Parameters Studies on Metanil Yellow Dye Adsorption by Granular Activated Carbon (입상활성탄에 의한 메타닐 옐로우 염료의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.96-102
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    • 2014
  • Adsorption of metanil yellow onto granular activated carbon were studied in a batch system. Various operation parameters such as adsorbent dosage, pH, initial concentration, contact time and temperature were optimized. Experimental equilibrium adsorption data were analyzed by Langmuir and Freundlich adsorption isotherm. The equilibrium process was described well by Freundlich isotherm model. From determined separation factor (1/n), adsorption of metanil yellow by granular activated carbon could be employed as effective treatment method. By analysis of kinetic experimental data, the adsorption process were found to confirm to the pseudo second order model with good correlation and the adsorption rate constant ($k^2$) decreased with increasing initial concentration. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The activation energy was determined as 23.90 kJ/mol. It was found that the adsortpion of metanil yellow on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G=-2.16{\sim}-6.55kJ/mol$) and the positive enthalpy change (${\Delta}H=+23.29kJ/mol$) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

Effect of Osmotic Dehydration and Vacuum Impregnation on the Quality of Dried Apple (삼투건조와 진공주입이 사과 건조제품의 품질에 미치는 영향)

  • Choi, Hee-Don;Lee, Hae-Chang;Kim, Yun-Sook;Choi, In-Wook;Park, Yong-Kon;Seog, Ho-Moon
    • Korean Journal of Food Science and Technology
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    • v.40 no.2
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    • pp.178-183
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    • 2008
  • This study investigated the effects of osmotic dehydration (OD) and vacuum impregnation (VI) on the quality of dried apple products. Weight reduction and water loss increased during OD, but these decreased in the apples during VI. In particular, VI's effect on increasing solid gain was superb. For apples in 40% sucrose solution, OD and VI were followed by hot-air drying at 50$^{\circ}C$. The experimental data were fitted successfully using the modified Page model. OD and VI increased drying time and decreased the drying rate constant of these apples as compared to the control. Shrinkage and rehydration capacity greatly decreased in the apples dried by OD and increased in the apples dried by VI as compared to the control. OD also decreased titratable acidity and ascorbic acid content considerably. Sensory evaluations of the products indicated that the apples prepared by OD had higher palatability in their rehydrated form in yoghurt, and the apple products prepared by VI had higher palatability in their dried form.