• Journal of Forest and Environmental Science
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• 제32권3호
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• pp.253-261
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• 2016

Xanthoceras sorbifolia seed coat (XSSC) is a processing residue of the bioenergy crop. This work aimed to evaluate the applicability of using the steam explosion to modify the residue for dye biosorption from aqueous solutions by using methylene blue as a model cationic dye. Equilibrium, kinetic and thermodynamic parameters for the biosorption of methylene blue on the steam-exploded XSSC (SE-XSSC) were evaluated. The kinetic data followed the pseudo-second-order model, and the rate-limiting step was the chemical adsorption. Intraparticle diffusion was one of the rate-controlling factors. The equilibrium data agreed well with the Langmuir isotherm, and the biosorption was favorable. The steam-explosion pretreatment strongly affected the biosorption in some respects. It reduced the adsorption rate constant and the initial sorption rate of the pseudo-second-order model. It enhanced the adsorption capacity of methylene blue at higher temperatures while reduced the capacity at lower ones. It changed the biosorption from an exothermic process driven by both the enthalpy and the entropy to an endothermic one driven by entropy only. It increased the surface area and decreased the pH point of zero charge of the biomass. Compared with the native XSSC, SE-XSSC is preferable to MB biosorption from warmer dye effluents.

• Composites Research
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• 제13권5호
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• pp.10-17
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• 2000

계면상 조건과 단섬유 함유량 증가에 따른 강화고무의 피로특성에 대해 실험적 고찰을 하였다. 피로시험 후 기지고무의 스프링 상수는 약 21% 감소하였고, 강화고무는 반대로 증가하였다. 강화고무의 스프링 상수 변화율은 섬유함유량 증가에 따라 감소하였고, 계면상 조건이 우수할수록 변화율이 적었다. 피로시험 후 기지고무의 온도는 2.5배, 강화고무는 1.7∼2.0배 증가하였다. 강화고무의 온도 변화율은 섬유 함유량 증가에 따라 감소하였고, 동일한 섬유 함유량에서 계면상 조건이 우수할수록 변화율이 적었다. 이번 연구에서 접착제 402와 고무용액을 2번씩 도포한 경우가 가장 우수한 계면상 모델(C)이 되었다. 그리고 이러한 강화고무를 자동차의 Engine Mount Rubber, Bush 그리고 Stopper등의 적용을 검토하였다.

• 대한기계학회논문집
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• 제7권2호
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• pp.193-203
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• 1983

The mixed convective heat transfer problems are characterized by the relatively significant contribution of buoyancy force to the transport processes of momentum and heat. Past analytical studies on this kind of problems have been carried out by employing either the conventional R-.epsilon. turbulence model which includes constant turbulent Prandtl number .sigma.$_{+}$ 1 or an extended R-.epsilon. turbulence model which takes account of the buoyancy effect in appropriate length scale equations. But in the latter case, the temperature variance .the+a.$^{2}$ over bar is approximated by a model under local equilibrium condition and the time scale ratio between velocity and temperature is assumed to be constant. These approximation is known to break down when the buoyancy effect is dominant. The present study is aimed at development of new computational turbulence closure level which can be applied to this rather complex turbulent process. The temperature variance is obtained directly by solving its dynamic transport equation and the time scale ratio which is variable in space is computed by a solution of a dynamic equation for the rate of scalar dissipation .epsilon.$_{\thetod}$ It was found that the computational results are in good agreement with available experimental data of wide range of unstable conditions.

• Geomechanics and Engineering
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• 제15권4호
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• pp.973-986
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• 2018

The objective of this paper is to present abacuses obtained from a parametric study of deep-lined tunnels using a numerical finite element model. This numerical model was implemented in software GEOMEC91, which is a two-dimensional axisymmetric model that considers the progress of excavation and the placing of the lining through the activation and deactivation of elements. It is adopted a step of excavation constant (1/3 of radius), constant velocity and circular cross section along the tunnel axis. It is used for rock mass a viscoplastic constitutive law with von-Mises criterion of viscoplasticity without hardening whose deformation rate over time is given by the Bingham model. The lining uses a linear elastic constitutive law. In total are 1716 analysis presented in 60 abacuses that show the value of ultimate convergence ($U_{eq}$) due to tunneling speed. In addition, it is shown an example of the use of the abacuses to determine the ultimate convergence ($U_{eq}$) of the tunnel and pressure ($P_{eq}$) on the lining.

• 수산해양기술연구
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• 제55권4호
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• pp.411-418
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• 2019

In this study, to investigate the effect of physical and chemical properties of butanol on the engine performance and combustion characteristics, the coefficient of variations of IMEP (indicated mean effective pressure) and fuel conversion efficiency were obtained by measuring the combustion pressure and the fuel consumption quantity according to the engine load and the mixing ratio of diesel oil and butanol. In addition, the combustion pressure was analyzed to obtain the pressure increasing rate and heat release rate, and then the combustion temperature was calculated using a single zone combustion model. The experimental and analysis results of butanol blending oil were compared with the those of diesel oil under the similar operation conditions to determine the performance of the engine and combustion characteristics. As a result, the combustion stabilities of D.O. and butanol blending oil were good in this experimental range, and the indicated fuel conversion efficiency of butanol blending oil was slightly higher at low load but that of D.O. was higher above medium load. The premixed combustion period of D.O. was almost constant regardless of the load. As the load was lower and the butanol blending ratio was higher, the premixed combustion period of butanol blending oil was longer and the premixed combustion period was almost constant at high load regardless of butanol blending ratio. The average heat release rate was higher with increasing loads; especially as butanol blending ratio was increased at high load, the average heat release rate of butanol blending oil was higher than that of D.O. In addition, the calculated maximum. combustion temperature of butanol blending oil was higher than that of D.O. at all loads.

• 한국환경과학회지
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• 제26권7호
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• pp.859-868
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• 2017

In this study, the reductive dechlorination of triclosan using zero-valent iron (ZVI, $Fe^0$) and modified zero-valent iron (i.e., acid-washed iron (Aw/Fe) and palladium-coated iron (Pd/Fe)) was experimentally investigated, and the reduction characteristics were evaluated by analyzing the reaction kinetics. Triclosan could be reductively decomposed using zero-valent iron. The degradation rates of triclosan were about 50% and 67% when $Fe^0$ and Aw/Fe were used as reductants, respectively, after 8 h of reaction. For the Pd/Fe system, the degradation rate was about 57% after 1 h of reaction. Thus, Pd/Fe exhibited remarkable performance in the reductive degradation of triclosan. Several dechlorinated intermediates were predicted by GC-MS spectrum, and 2-phenoxyphenol was detected as the by-product of the decomposition reaction of triclosan, indicating that reductive dechlorination occurred continuously. As the reaction proceeded, the pH of the solution increased steadily; the pH increase for the Pd/Fe system was smaller than that for the $Fe^0$ and Aw/Fe system. Further, zero-order, first-order, and second-order kinetic models were used to analyze the reaction kinetics. The first-order kinetic model was found to be the best with good correlation for the $Fe^0$ and Aw/Fe system. However, for the Pd/Fe system, the experimental data were evaluated to be well fitted to the second-order kinetic model. The reaction rate constants (k) were in the order of Pd/Fe > Aw/Fe > $Fe^0$, with the rate constant of Pd/Fe being much higher than that of the other two reductants.

• 한국결정성장학회지
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• 제14권5호
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• pp.226-232
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• 2004

One predicts the crystal growth rate of ZnSe with a low vapor pressure system in a horizontal configuration based on one dimensional advection-diffusion and two-dimensional diffusion-convection model. The present results show that for the ratios of partial pressures, s = 0.2 and 2.9, the growth rate increases with the temperature differences between the source and crystal. As the ratio of partial pressure approaches the stoichiometric value, s = 2 from s = 1.5 (zinc-deficient case: s < 2) and 2.9 (zinc-rich case: s > 2), the rate increases sharply. For the ranges from 1.5 to 1.999 (zinc-deficient case: s < 2) and from s = 9 to 2.9 (zinc-rich case: s > 2), the rate are slightly varied. From the viewpoint of the order of magnitude, the one-dimensional model for low vapor pressure system falls within the 2D predictions, which indicates the flow fields would be advective-diffusive. For the effects of gravitational accelerations on the rate, the gravitational constants are varied from 1 g to $10^{-6}$ g for $\Delta$T = 50 K and s = 1.5, the rates remain nearly constant, i.e., 211 mg/hr, which indicates Stefan flow is dominant over convection.

• 디지털산업정보학회논문지
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• 제7권4호
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• pp.7-14
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• 2011

Infinite failure NHPP models presented in the literature exhibit either constant, monotonic increasing or monotonic decreasing failure occurrence rate per fault (hazard function). This infinite non-homogeneous Poisson process is model which reflects the possibility of introducing new faults when correcting or modifying the software. In this paper, polynomial hazard function have been proposed, which can efficiency application for software reliability. Algorithm for estimating the parameters used to maximum likelihood estimator and bisection method. Model selection based on mean square error and the coefficient of determination for the sake of efficient model were employed. In numerical example, log power time model of the existing model in this area and the polynomial hazard function model were compared using failure interval time. Because polynomial hazard function model is more efficient in terms of reliability, polynomial hazard function model as an alternative to the existing model also were able to confirm that can use in this area.

• 한국정밀공학회지
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• 제21권4호
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• pp.39-47
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• 2004

In mold machining, there are many concave machining regions where chatter and tool deflection occur since MRR(material removal rate) increases as curvature increases even though cutting speed and depth of cut are constant. Boolean operation between stock and tool model is widely used to compute MRR in NC milling simulation. In finish cutting, the side step is reduced to about 0.3mm and tool path length is sometimes over loom, so Boolean operation takes long computation time and includes much error if the resolution of stock and tool model is larger than the side step. In this paper, curvature of CL (cutter location) surface and side step of tool path is used to compute the feedrate for constant MRR machining. The data structure of CL surface is Z-map generated from NC tool path. The algorithm to get local curvature from discrete data was developed and applied to compute local curvature of CL surface. The side step of tool path was computed by point density map which includes cutter location point density at each grid element. The feedrate computed from curvature and side step is inserted to new tool path to regulate MRR. The resultants were applied to feedrate optimization system which generates new tool path with feedrate from NC codes for finish cutting. The system was applied to the machining of speaker and cellular phone mold. The finishing time was reduced to 12.6%, tool wear was reduced from 2mm to 1.1mm and chatter marks and over cut on corner were reduced, compared to the machining by constant feedrate. The machining time was shorter to 17% and surface quality and tool was also better than the conventional federate regulation using curvature of the tool path.

• Environmental Analysis Health and Toxicology
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• 제16권3호
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• pp.139-142
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• 2001

Acetanilide is a High Production Volume Chemical, which is produced about 2,300 tons/year in Korea as of 1998 survey. Most is used as an intermediate for synthesis of pharmaceuticals and dyes, and the chemical is one of seven chemicals of which human and environmental risk are being assessed by National Institute of Environmental Research under the frame of OECD SIDS program. The Atmospheric Oxidation Program for Microsoft Windows (AOPWIN) is used to estimates the rate constant for the atmospheric, gas－phase reaction between photochemically produced hydroxyl radicals and organic chemicals. It is also used to estimates the rate constant for the gas－phase reaction between ozone and olefinic/acetylenic compounds. The rate constants estimated by the program are then used to calculate atmospheric half－lives for organic compounds based upon average atmospheric concentrations of hydroxyl radicals and ozone. AOPWIN requires only a chemical structure to make these predictions. Structures are entered into AOPWIN by SMILES (Simplified Molecular Input Line Entry System) notations. In this study, one of environmental fate/distribution of the chemical elements, photodegradation of acetanilide was estimated using AOPWIN model based on SMILES notation and chemical name data.