• Mass Spectrometry Letters
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• v.15 no.1
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• pp.54-61
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• 2024

An improved voltage modulation method (VMM) was used to control the heat release and adsorption properties of the adsorbent. In this work, the voltage and flux modulation methods were considered under unified experimental conditions of dissociative surface ionization (SI) of polyatomic organic molecules, the criteria were found when under VMM conditions the current relaxation of SI carries information about the kinetic properties of thermal desorption of ionizable dissociation particles arriving on the surface of polyatomic molecules. Conditions were found under which the relaxation of the ionic current in the flux modulation method is determined by the kinetics of the heterogeneous dissociation reaction of the original polyatomic molecules. The values of the thermal desorption rate constant K⁺ and the activation energy E⁺ obtained with VMM for desorption of (CH₃)₂NCH⁺₂ ions with m/z 58 by adsorption of imipramine and amitriptyline molecules agree well with each other and with the results for the desorption of the same ions by adsorption of other molecules. This confirms one of the basic conditions for the equilibrium process SI - the a degree (β coefficient) of the same particles SI on the same emitter surface is the same and does not depend on the way these particles are formed on the emitter surface.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.6
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• pp.1679-1688
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• 1990

The method of nonlinear parameter estimation(NPE), which is a statistical and an inverse method, is used to estimate the thermal diffusivity of the porous insulation material. In order to apply the NPE method for measuring the thermal diffusivity, and algorithm for programing suitable to IBM personal computer is established, and is studied the statistical treatment of experimental data and theory of estimation. The experimental data obtained by discrete measurement using a constant heat flux technique are used to find the boundary conditions, initial conditions, and the thermal diffusivity, and then the final values are compared with the values obtained by some different methods. The results are presented as follows:(1) NPE method is used to establish the estimation of the thermal diffusivity and compared results with experimental output shows, that this method can be applicable to define the thermal diffusivity without considering hear flux types. (2) Because of all of the temperatures obtained by the discrete measurement on each steps of time are used to estimate the thermal diffusivity. Although some error in the temperature measurements of temperature are included in estimating process, its influences on the final value are minimzed in NPE method. (3) NPE method can reduce the experimental time including the time of data collecting in a few minutes and can take smaller specimen compared with steady state method. If the tube-type furnace is used, also the adjusting time of surrounding temperature can be reduced.

• Korean Chemical Engineering Research
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• v.52 no.2
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• pp.199-204
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• 2014

In binary solidification compositional convection in a porous mushy layer influences the quality of the final products. We consider the mushy layer solidifying from below with a constant solidification velocity. The disturbance equations for the mushy layer are derived using linear stability theory. The basic-state temperature fields and the distribution of the porosity in the mushy layer are investigated numerically. When the superheat is large, the thickness of the mushy layer is relatively small compared to the thickness of the thermal boundary layer. With decreasing the superheat the critical Rayleigh number based on the thickness of the mushy layer increases and the mushy layer becomes stable to the compositional convection. The critical Rayleigh number obtained from the continuity conditions of temperature and heat flux at the mush-liquid interface is smaller than that from the isothermal condition at the upper boundary of the mushy layer.

• Journal of the Korean Society of Visualization
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• v.6 no.2
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• pp.33-38
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• 2008

The effect of the radial temperature gradient and the presence of slits in the wall of outer of two cylinders involved in creating a Taylor-Couette flow was investigated by measuring the velocity field inside the gap. The slits were azimuthally located along the inner wall of the outer cylinder and the number of slits used in this study was 18. The radius ratio and aspect ratio of the models were 0.825 and 48, respectively. The heating film wrapped around the inner cylinder was used for generating the constant heat flux and we ensured the constant temperature condition at the outer space of the outer cylinder. The velocity fields were measured by using the PIV(particle image velocimetry) method. The refractive index matching method was applied to remove image distortion. The results were compared with plain wall configuration of Taylor-Couette flow. From the results, the presence of slits in the wall of outer cylinder and temperature gradient increased the flow instability.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.6
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• pp.734-749
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• 1998

A numerical study t predict the characteristics on transient operation of the heat pipe cooling system with multiple heaters for electronic system has been performed. The heat pipe cooling system of 45 cm length and 16 mm diameter was composed of evaporator section with four heaters which simulate electronic components, insulated transport section, and condenser section with a conductor which was cooled under the constant heat flux boundary condition. Two test cases were investigated in present study; Case 1 indicated that the 1st and 2nd heaters among four heaters were heated off, while the 3rd and the 4th heaters were heated on. Case 2 was the inverse situation switched from heating locations of Case 1. Case 3 indicated that the 1st and 4th heaters among four heaters were heated off, while the 2nd and 3rd heaters were heated on. The results showed that the transient time to reach the steady state is shorter for Case 1 than for Case 2. Especially, the maximum temperature among the heaters which simulate electronic components during switching operation is relatively small compared to the maximum allowable operating temperature in electronic system. It is concluded that the heat pipe cooling system in present study operate with the good thermal reliability even for sudden switching situation of the heaters.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.1
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• pp.50-58
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• 2000

Experiments were carried out to obtain the effects of nozzle configuration and jet to jet spacing on the heat transfer characteristics of single line of circular water jets impinging on a constant heat flux plane surface. The nozzle configurations are Cone type, Reverse cone type and Vertical circular type, and the nozzle arrays are single jet(nozzle dia. 8 mm), 1 row of 3 jets and 1 row of 5 jets. Jet velocities ranging from 3m/s to 8m/s were investigated for the nozzle to target plate spacing of 80 mm. For the Cone and Reverse cone type nozzle arrays, the average Nusselt number of 1 row of 5 jets was larger than that of 1 row of 3 jets at Re$_{D}$<45000, but that of 1 row of 3 jets was larger than that of 1 row of 5 jets at $Reo\le45000$. For the Vertical circular type nozzle, however, the average Nusselt number of 1 row of 3 jets was larger than that of 1 row of 5 jets at all jet velocities. In the condition of fixed mass flow rates, the maximum heat transfer augmentation was obtained for 1 row of 5 jets and was over 2 times larger than that of the single jet for all nozzle configurations. The nozzle configurations that produce the maximum average Nusselt number are as follows: For 1 row of 3 jets, the Vertical circular type at $Reo\le45000$ and the Reverse cone type at $Reo\le45000$. But, they are the Reverse cone type at Re$_{D}$<55000 and the Vertical circular type at$Reo\le55000$ for 1 row of 5 jets.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.327-334
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• 2004

Spectroscopic and electrostatic probe measurements were made to examine plasma characteristics with or without a metal plate for a 10-㎾-class direct-current arcjet Heat fluxes into the plate from the plasma were also evaluated with a Nickel slug and thermocouple arrangement. Ammonia and mixtures of nitrogen and hydrogen were used. The NH$_3$ and $N_2$+3H$_2$ plasmas in the nozzle and in the downstream plume without a plate were in thermodynamical nonequilibrium states. As a result, the H-atom electronic excitation temperature and the $N_2$ molecule-rotational excitation temperature intensively decreased downstream in the nozzle although the NH molecule-rotational excitation temperature did not show an axial decrease. Each temperature was kept in a small range in the plume without a plate except for the NH rotational temperature for NH$_3$ gas. On the other hand, as approaching the plate, the thermodynamical nonequilibrium plasma came to be a temperature-equilibrium one because the plasma flow tended to stagnate in front of the plate. The electron temperature had a small radial variation near the plate. Both the electron number density and the heat flux decreased radially outward, and an increase in H$_2$ mole fraction raised them at a constant radial position. In cases with NH$_3$ and $N_2$+3H$_2$ a large number of NH radical with a radially wide distribution was considered to cause a large amount of energy loss, i.e., frozen flow loss, for arcjet thrusters.

• Solar Energy
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• v.15 no.2
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• pp.47-64
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• 1995

An experimental investigation is carried out to see the local heat transfer characteristics of a rotating heated flat plate surface with constant heat flux when a normal water jet is impinging on this surface. The effects of jet Reynolds number, rotating Reynolds number are investigated while the distance between the nozzle and the flat plate is set fixed. As a result, correlations to relate the local Nusselt number to the local rotational Reynolds number, jet Prandtl number and the dimensionless radial position are presented.

• Journal of the Korean Ceramic Society
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• v.49 no.4
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• pp.385-396
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• 2012

Thermal shock test methods and thermal shock parameters for ceramics were reviewed from the following viewpoints: (1) The test methods should be based on the precise estimation of both temperature and thermal stress distributions in a specimen taking into account the temperature-dependent thermo-mechanical properties; (2) The thermal shock parameters must be defined as a physical property of the materials and described as a function of temperature at the fracture point of the specimen; (3) The relation between the strength and fracture toughness of brittle ceramics under a thermal shock load must be the same as the relation under a mechanical load. In addition, appropriate thermal shock parameters should be defined by the thermal shock strength and thermal shock fracture toughness based on stress and energy criteria, respectively. A constant heat flux method is introduced as a testing technique suitable for estimating these thermal shock parameters directly from the electric power charged.

• Communications of the Korean Mathematical Society
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• v.33 no.2
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• pp.571-580
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• 2018

The object of the present paper is to prove the non-existence of pseudo projective Ricci symmetric spacetimes $(PW\;RS)_4$ with different types of energy momentum tensor. We also discuss whether a fluid $(PW\;RS)_4$ spacetime with the basic vector field as the velocity vector field of the fluid can admit heat flux. Next we consider perfect fluid and dust fluid $(PW\;RS)_4$ spacetimes respectively. Finally we construct an example of a $(PW\;RS)_4$ spacetime.