• 제목/요약/키워드: Constant Surface Area

검색결과 366건 처리시간 0.038초

잎담배의 흡습 및 탈습에 관한 연구 (Moisture Sorption and Desorption Isotherms of Various Leaf Tobaccos)

  • 진학용;최승찬;이태호;유광근
    • 한국연초학회지
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    • 제3권1호
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    • pp.30-40
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    • 1981
  • The moisture sorption and desorption isotherms of various tobaccos were obtained over a relative humidity range from 0 to 90% at $20^{\circ}C$ and $30^{\circ}C$. The hysteresis effect, constant and rate of moisture sorption and desorption, monomolecular-layer moisture content, and specific surface area were analyzed from the obtained data. The moisture sorption and desorption isotherms showed a different characteristics for different tobacco varieties. At a lower humidity range below 50% RH, Burley tobacco had higher moisture sorption and desorption figures than Hicks and Basma, while, at a higher humidity range above 50% RH, Hicks had higher values than the others. The hysteresis effect of tobacco were greater in an intermediate humidity range (40-70% RN), and Basma showed a greater effect than the others. The sorption and desorption constant (K) increased with temperature, but decreased with RH, and Burley tobacco had larger K values, while Hicks had smaller K values than others. The sorption and desorption rate of Burley tobacco were greater than the other tobaccos. The monomolecular-layer moisture was 27.8 and 51.4mg/g, and the specific surface was 101 and $186m^2/g$, for Basma and Burley, respectively.

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해양심층수와 지하염수의 자원특성 비교분석 (Comparative Analysis of Resources Characteristics for Deep Ocean water and Brine Groundwater)

  • 문덕수;정동호;김현주
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2003년도 추계학술대회 논문집
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    • pp.333-335
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    • 2003
  • Deep Ocean Water is formed within restricted area including polar sea (high latitude) by cooling of surface seawater and globally circulated in the state of insolation with surface seawater. Although not as obvious as estuaries mixing, Brine groundwater is mixture of recirculated seawater and groundwater. Seawater having high osmotic pressure infiltrate into unconfined aquifer where is connected to the sea. The ions dissolved in seawater are present in constant proportions to each other and to the total salt content of seawater. However deviation in ion proportions have been observed in some brine groundwater. Some causes of these exception to the Rule of constant proportions are due to many chemical reactions between periphery soil and groundwater. While Deep Ocean Water (DOW) have a large quantity of functional trace metals and biological affinity relative to brine groundwater, DOW have relatively small amount of harmful bacteria and artificial pollutants.

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Experimental Investigation of the Effect of Composition on the Performance and Characteristics of PEM Fuel Cell Catalyst Layers

  • Baik, Jung-Shik;Seong, Dong-Mug;Kim, Tae-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.157-160
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    • 2007
  • The catalyst layer of a proton exchange membrane (PEM) fuel cell is a mixture of polymer, carbon, and platinum. The characteristics of the catalyst layer play critical role in determining the performance of the PEM fuel cell. This research investigates the role of catalyst layer composition using a Central Composite Design (CCD) experiment with two factors which are Nafion content and carbon loading while the platinum catalyst surface area is held constant. For each catalyst layer composition, polarization curves are measured to evaluate cell performance at common operating conditions, Electrochemical Impedance Spectroscopy (EIS), and Cyclic Voltammetry (CV) are then applied to investigate the cause of the observed variations in performance. The results show that both Nafion and carbon content significantly affect MEA performance. The ohmic resistance and active catalyst area of the cell do not correlate with catalyst layer composition, and observed variations in the cell resistance and active catalyst area produced changes in performance that were not significant relative to compositions of catalyst layers.

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Development of Automatic Filet Welding Torch System with High Speed Rotating Arc Sensor

  • Lee, W.K.;Lee, G.Y.;Kim, J.H.;Kim, S.B.
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2001년도 ICCAS
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    • pp.94.1-94
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    • 2001
  • Arc sensor gives important groove information during welding. Automatic seam tracking control system with arc sensor has significant characteristics such that bead formation is given as decentralization of penetration and formation of concave bead profile and that a turning point of transverse weaving with constant arc length control is decided whether or not torch height reaches to a specified setting level. Furthermore, the rotating action of the arc prevents hanging of weld bead and forms flat bead surface under high speed welding condition. The variation of groove and deposition area can be detected from the trace of weaving. The area and width of weaving trace has close correlation with the area of groove and deposition. In this paper, main object of this system is to realize an adaptive microprocessor based controller ...

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균일한 열유속을 갖는 가열된 평판에 부착된 발포알루미늄에 대한 원형 충돌제트의 열유동 특성 (Heat Flow of Round Jet Impinging Aluminum Foam Mounted on the Heated Plate with Constant Heat Flux)

  • 한영희;이계복;이충구
    • 에너지공학
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    • 제18권2호
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    • pp.108-113
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    • 2009
  • 균일한 열유속을 갖는 가열된 평판에 부착된 발포 알루미늄에 대한 충돌제트의 열유동 특성에 대한 실험적 연구가 수행되었다. 열전달 특성에 대한 기공도, 다공성 물질의 두께, Reynolds 수의 영향이 고찰되었다. 실험결과 가열평판에 부착된 발포 알루미늄에 의해 열전달의 증가를 얻을 수 있었고 다공성 물질의 삽입에 의한 열전달 증가는 열전달 표면적의 증가와 압력 손실에 의한 운동량 감소에 의해 영향을 받는 것을 확인하였다.

Adsorption Characteristics of U ranium (VI) Ion on Cryptand Synthetic Resin Adsorbent

  • Kim, Hae-Jin
    • 통합자연과학논문집
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    • 제10권4호
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    • pp.225-231
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    • 2017
  • Cryptand resins were synthesized by mixing 1-aza-18-crown-6 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 5%, and 10% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > calcium ($Ca^{2+}$) > neodymium ($Nd^{3+}$) ion, adsorbability of the uranium ion was the crosslink in order of 1%, 2%, 5%, and 10% and it was increased with the lower dielectric constant.

Oxidation Kinetics of Carbon Fibers

  • Roh, Jae-Seung
    • Carbon letters
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    • 제6권1호
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    • pp.1-5
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    • 2005
  • Isotropic pitch based carbon fibers were exposed to isothermal oxidation in carbon dioxide gas to study the activation kinetics under the temperature of 800~$1100^{\circ}C$. The kinetic equation $f=1-{\exp}(-at^b)$ was introduced and the constant b was obtained in the range of 0.92~1.25. It was shown that the activated carbon fiber shows the highly specific surface area (SSA) when the constant b comes close to 1. The activation kinetics were evaluated by the reaction-controlling regime (RCR) according to changes of the apparent activation energy with changes of the conversion. It was observed that the activation energies increase from 47.6 to 51.2 kcal/mole with the conversion increasing from 0.2 to 0.8. It was found that the pores of the activated carbon fiber under the chemical reaction were developed well through the fiber.

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A New Type of Nonthermal Plasma Reactor

  • Geum, Sang-Taek;Moon, Jae-Duk;Jun, Sun-Gon
    • The Korean Journal of Ceramics
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    • 제5권3호
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    • pp.245-249
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    • 1999
  • A new type of nonthermal plasma reactor utilizing ferroelectric pellets is proposed to generate nonthermal plasma efficiently, which is used for simultaneous control of various pollutant gases. Electric charges stored on ferroelctric pellets by corona discharge between a corona tip and a mesh electrode provide partial electrical discharges among ferroelectric pellets. These partial electrical discharges can enhance partial discharges around the surface of ferroelectric pellets. This method utilizes wide reacting area of ferroelectric pellets and partial discharge. Positive and negative dc voltage are applied to the corona tip to generate partial discharges, and corona currents are estimated to investigate charge storage on ferroelectric pellets as function of time and charge relaxation time constants of ferroelectric pellects. As a result, charge relaxationtime, dielectric constants of ferroelectric pellets, polarity of applied voltage and applied time influence partial discharges among ferroelectric pellect.

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Adsorption and Separation of U (VI), Co (II), and Dy (III) Metal Ions on Crown Synthetic Resin

  • Kim, Joon-Tae
    • 통합자연과학논문집
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    • 제10권1호
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    • pp.43-50
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    • 2017
  • Synthetic resins were combined 1-aza-12-crown-4 macrocyclic ligand with styrene divinylbenzene copolymer having 1%, 2%, 8%, and 16% crosslink by a substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, SEM, surface area, and IR-spectrum. As the results of the effects of pH, crosslink of synthetic resin, and dielectric constant of a solvent on metal ion adsorption for resin adsorbent, the metal ions showed high adsorption at pH 3 or over. Adsorption selectivity for the resin in ethanol solvent was the order of uranium ($UO_2{^{2+}}$) > cobalt ($Co^{2+}$) > dysprosium ($Dy^{3+}$) ion, adsorbability of the metal ion was the crosslink in order of 1%, 2%, 8%, and 16% and it was increased with the lower dielectric constant. In addition, theses metal ions could be separated in the column with 1% crosslink resin by using nitric acid (pH 2.0) as an eluent.

Studies on Hydrophobic Drug-Soluble Carrier Coprecipitates(1)

  • Shin, Sang-Chul
    • Archives of Pharmacal Research
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    • 제2권1호
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    • pp.35-47
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    • 1979
  • In order to increase the dissolution rate of furosemide(4-choro-N-furfury1-5-sulfamoy1 anthranilic acid_, various ratio coprecipitates with water-soluble polymers, such as polyvinylpyrrolidone and polythylene glycol, of different molecular weight, were prepared and quantitatively studied by comparing their dissolution characteristics of furosemide at powder state and at nondisintegrating disk state containing constant surface area at various temperatures and rotating velocities. The dissolution characteristics of furosemide from pure furosemide disks and 1:2(w/w) furosemide-PVP coprecipitate disks were in accordance with Noyes-Nernst equation and the rate constant of dissolution was proportional to the square root of rotating velocity of the disks. The intrinsic rate of dissoluton at 150 rpm, 37.deg.C was $2.21{\times}10^{-7}$ for the PVP 10, 000 COPRECIPITATE, $1.64{\times}10^{-7}$ for the PVP 40, 000 coprecipitate, and$ 1.44 {\times} 10^{-7}$for the PVP 360, 000 corprecipitate, while the rate was $1.27{\times}10^{-8}M/cm^{2} min$ for pure furosemide, repectively. The activation energy of dissolution was about 17, 000 for furosemide and about 7, 300 cal/mole for the 1:2 furosemide PVP 40, 000 coprecipitate, respectively.

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