• Title/Summary/Keyword: Constant Correlation Model

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Prediction of Setting Time of Concrete Using Fly Ash and Super Retarding Agent (초지연제 및 플라이애쉬를 사용한 콘크리트의 응결시간 예측)

  • Han, Min-Cheol
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.759-767
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    • 2006
  • This paper presents a method to estimate the setting time of concrete using super retarding agent(SRA) and fly ash(FA) under various curing temperature conditions by applying maturity based on equivalent age. To estimate setting time, the equivalent age using apparent activation energy($E_a$) was applied. Increasing SRA content and decreasing curing temperature leads to retard initial and final set markedly. $E_a$ at the initial set and final set obtained by Arrhenius function showed differences in response to mixture type. It is estimated to be from $24{\sim}35KJ/mol$ in all mixtures, which is smaller than that of conventional mixture ranging from $30{\sim}50KJ/mol$. Based on the application of $E_a$ to Freisleben-Hansen and Pederson's equivalent age function, equivalent age is nearly constant, regardless of curing temperature and SRA contents. This implies that the concept of maturity is applicable in estimating the setting time of concrete containing SRA. A high correlation between estimated setting time and measured setting time is observed. Multi-regression model to determine appropriate dosage of SRA reflecting FA contents and equivalent age was provided. Thus, the setting time estimation method studied herein can be applicable to the concrete containing SRA and FA in construction fields.

Isotherms, Kinetics and Thermodynamic Parameters Studies of New Fuchsin Dye Adsorption on Granular Activated Carbon (입상 활성탄에 대한 New Fuchsin 염료흡착의 등온선, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.632-638
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    • 2014
  • Batch adsorption studies including equilibrium, kinetics and thermodynamic parameters for the adsorption of new fuchsin dye using granular activated carbon were investigated with varying the operating variables such as initial concentration, contact time and temperature. Equilibrium adsorption data were fitted into Langmuir, Freundlich, Dubinin-Radushkevich and Temkin isotherms. Adsorption equilibrium was mostly well described by Langmuir Isotherm. From the estimated separation factor of Langmuir ($R_L$ = 0.023), and Freundlich (1/n = 0.198), this process could be employed as an effective treatment for the adsorption of new fuchsin dye. Also based on the adsorption energy (E = 0.002 kJ/mol) from Dubinin-Radushkevich isotherm and the adsorption heat constant (B = 1.920 J/mol) from Temkin isotherm, this adsorption is physical adsorption. From kinetic experiments, the adsorption reaction processes were confirmed following the pseudo second order model with good correlation. The intraparticle diffusion was a rate controlling step. Thermodynamic parameters including changes of free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption. The change of enthalpy (92.49 kJ/mol) and activation energy (11.79 kJ/mol) indicated the endothermic nature of adsorption processes. The change of entropy (313.7 J/mol K) showed an increasing disorder in the adsorption process. The change of free energy found that the spontaneity of process increased with increasing the adsorption temperature.

Equilibrium, Kinetic and Thermodynamic Parameter Studies on Adsorption of Allura Red from Aqueous Solution by Granular Activated Carbon (입상활성탄에 의한 수용액으로부터 오로라 레드의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.430-436
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    • 2014
  • Allura Red (AR) is a water-soluble harmful tar-based food colorant (FD & C Red 40). Batch adsorption studies were performed for the removal of AR using bituminous coal based granular activated carbon as adsorbent by varying the operation parameters such as adsorbent dosage, initial concentration, contact time and temperature. Experimental equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin isotherms. The equilibrium process was described well by Freundlich isotherm. From determined separation factor ($R_L$), adsorption of AR by granular activated carbon could be employed as effective treatment method. Temkin parameter, B was determined to 1.62~3.288 J/mol indicating a physical adsorption process. By estimation of adsorption rate experimental data, the value of intraparticle diffusion rate constant ($k_m$) increased with the increasing adsorption temperature. The adsorption process were found to confirm to the pseudo second order model with good correlation. Thermodynamic parameters like change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The negative Gibbs free energy change (${\Delta}G$ = -2.16~-6.55 kJ/mol) and the positive enthalpy change (${\Delta}H$ = + 23.29 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

Anisotropy of shear strength according to roughness in joint surface (절리면 거칠기에 의한 전단강도 이방성)

  • 이창훈;정교철
    • The Journal of Engineering Geology
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    • v.12 no.4
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    • pp.421-437
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    • 2002
  • In order to quantify the anisotropic properties of rock included joints and shear behavior in joint surface, the mold is Produced for rock joint surface using gypsum Plaster and Peformed for replicated joint models made of cement mortar. Rock sample is measured using mechanical profilometer before testing and their result is expressed quantitatively. The statistical parameters and the fractal dimension by fractal theory for roughness is investigated its coordinate value for numerical process. The shear strength to the shear displacement in low level normal stress ismaintained or increased in most joint models. Their results present that this relationship is depended several roughness properties in joint model for natural rock joint. The relationship between the shear strength and the Properties for profiles estimated by some statistical parameter in roughness has the low correlation and is not constant. The result between the data for direct shear test and using Barton's equation, Barton's equation has not the effectiveness for the effect of anisotropy and has not suitable to recognizing the properties for joint surface. It means that JRC has not the properties of anisotropic rock surface. The fractal dimension is well correlated with the data of direct shear test than those of JRC. New experimental formulae using fractal dimension is comported with the anisotropic properties for direct shear test.

Wind Tunnel Test Study on the Characteristics of Wind-Induced Responses of Tall Buildings with Openings (중공부(中空部)를 가진 고층건축물(高層建築物)의 풍응답(風應答) 특성(特性)에 관한 풍동실험(風洞實驗) 연구(硏究))

  • Kim, Dong Woo;Kil, Yong Sik;Ha, Young Cheol
    • Journal of Korean Society of Steel Construction
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    • v.17 no.4 s.77
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    • pp.499-509
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    • 2005
  • The excessive wind-induced motion of tall buildings most frequently result from vortex-shedding-induced across-wind oscillations. This form of excitation is most pronounced for relatively flexible, lightweight, and lightly damped high-rise buildings with constant cross-sections. This paper discusses the aerodynamic means ofmitigating the across-wind vortex shedding induced in such situations. Openings are added in both the drag and lift directions in the buildings to provide pressure equalization. Theytend to reduce the effectiveness of across-wind forces by reducing their magnitudes and disrupting their spatial correlation. The effects of buildings with several geometries of openings on aerodynamic excitations and displacement responses have been studied for high-rise buildings with square cross-sections and an aspect ratio of 8:1 in a wind tunnel. High-frequency force balance testshave been carried out at the Kumoh National University of Technology using rigid models with 24 kinds of opening shapes. The measured model's aerodynamic excitations and displacement were compared withthose of a square cylinder with no openings to estimate the effectiveness of openings for wind-induced oscillations. From these results, theopening shape, size, and location of buildings to reduce wind-induced vortex shedding and responses were pointed out.

Estimation of PM concentrations at night time using CCTV images in the area around the road (도로 주변 지역의 CCTV영상을 이용한 야간시간대 미세먼지 농도 추정)

  • Won, Taeyeon;Eo, Yang Dam;Jo, Su Min;Song, Junyoung;Youn, Junhee
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.39 no.6
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    • pp.393-399
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    • 2021
  • In this study, experiments were conducted to estimate the PM concentrations by learning the nighttime CCTV images of various PM concentrations environments. In the case of daytime images, there have been many related studies, and the various texture and brightness information of images is well expressed, so the information affecting learning is clear. However, nighttime images contain less information than daytime images, and studies using only nighttime images are rare. Therefore, we conducted an experiment combining nighttime images with non-uniform characteristics due to light sources such as vehicles and streetlights and building roofs, building walls, and streetlights with relatively constant light sources as an ROI (Region of Interest). After that, the correlation was analyzed compared to the daytime experiment to see if deep learning-based PM concentrations estimation was possible with nighttime images. As a result of the experiment, the result of roof ROI learning was the highest, and the combined learning model with the entire image showed more improved results. Overall, R2 exceeded 0.9, indicating that PM estimation is possible from nighttime CCTV images, and it was calculated that additional combined learning of weather data did not significantly affect the experimental results.

An Analysis of the Relationship between Self-Esteem and Leisure Satisfaction and Quality of Life in the Elderly Women's Participation of a Ballet Program (고령여성의 발레운동 참여에 따른 자아존중감과 여가만족 및 삶의 질의 관계 분석)

  • Park, Seon-Hee
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.6
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    • pp.161-170
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    • 2020
  • The purpose of this study is to examine satisfaction at using leisure time and quality of life in the elderly women's participation of a ballet program. A questionnaire survey was conducted with 148 elderly women registering for 10 dance academies in G Metropolitan City in relation to self-esteem, leisure satisfaction, and quality of life. After data processing, the following conclusions were drawn. The results of correlation and regression analysis between self-esteem and leisure satisfaction and quality of life were as follows. Positive self-esteem had positive effects on all sub-factors of leisure satisfaction and quality of life. Negative self-esteem had negative effects on social satisfaction of leisure satisfaction and health and psychological factors of quality of life. The results of research model fit and hypothesis testing between self-esteem and leisure satisfaction and quality of life were as follows. Self-esteem had positive effects on leisure satisfaction and quality of life and high leisure satisfaction had significant effects on quality of life factors. In conclusion, the elderly women's participation in the ballet program improved their self-esteem and significantly positive effects on their leisure satisfaction and quality of life. It is, therefore, suggested that the elderly's ballet exercise through constant physical activity will prevent diseases and promote health in their old age.

Evaluation of Roadmap Image Quality by Parameter Change in Angiography (혈관조영검사에서 매개변수 변화에 따른 Roadmap 영상의 화질평가)

  • Kong, Chang gi;Song, Jong Nam;Han, Jae Bok
    • Journal of the Korean Society of Radiology
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    • v.14 no.1
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    • pp.53-60
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    • 2020
  • The purpose of this study is to identify factors affecting picture quality in Roadmap images, which were studied by varying the dilution rate, collimation field and flow rate of contrast medium. For a quantitative evaluation of the quality of the picture, a 3mm vessel model Water Phantom was self-produced using acrylic, a roadmap image was acquired with a self-produced vascular model Water Phantom, and the SNR(Signal to Noise Ratio) and CNR (Contrast to Noise Ratio) were analyzed. CM:N/S In the study on the change of dilution rate, CM:N/S dilution rate changed to (100%~10%:100%), and the measurement of the roadmap image taken using the vascular model Water Phantom showed that the measurement value of SNR gradually decreased as the N/S dilution rate was increased, and the measurement of CNR was gradually reduced. It was confirmed that the higher the dilution rate of CM:N/S, the lower the SNR and CNR, and also significant image can be obtained at the dilution rate of CM:N/S (100%~70:30%). The study showed the value of SNR and CNR in Roadmap image was increased as the Collimation Field was narrowed to the center of the vascular phantom; the Collimation Field was narrowed to the center of the vessel model by 2cm intervals to 0cm through 12cm. To verify the relationship with Roadmap image and Flow Rate, volume of the autoinjector was kept constant at 15 and the flow rate was gradually increased 1, 2, 3, 4, 5, 6, 7, 8, 9, 10. The value of SNR and CNR of images taken by using water Phantom gradually decreased as the Flow Rate increased, but at Flow Rate 9 and 10, the SNR and CNR value was increase. It was not possible to confirm the relationship with SNR and CNR by ROI mean value and Background mean value. It is considered that further study is needed to evaluate the correlation about Roadmap image and Flow Rate. In conclusion, as the dilution rate of N/S in contrast medium was increased, the value of SNR and CNR was decreased. The narrower the Collimation Field, the higher image quality by increasing value of SNR and CNR. However, it is not confirmed the relationship Roadmap image and Flow Rate. It is considered that appropriate contrast medium concentration to minimize the effects of kidney and proper Collimation Field to improve contrast of image and reduce exposure X-ray during procedure is needed.

The Effect of Compost Application on Degradation of Total Petroleum Hydrocarbon in Petroleum-Contaminated Soil (유류오염 토양 내 석유계 탄화수소 화합물의 분해에 대한 퇴비의 시용 효과)

  • Kim, Sung Un;Kim, Yong Gyun;Lee, Sang Mong;Park, Hyean Cheal;Kim, Keun Ki;Son, Hong Joo;Noh, Yong Dong;Hong, Chang Oh
    • Korean Journal of Environmental Agriculture
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    • v.34 no.4
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    • pp.268-273
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    • 2015
  • BACKGROUND: Petroleum-contaminated soil from leaking above- and underground storage tanks and spillage during transport of petroleum products is widespread environmental problem in recent years. Application of compost may be the most promising, cost-effective, and eco-friendly technology for soil bioremediation because of its advantages over physical and chemical technology. The objective of this study was to evaluate effect of compost application on degradation of total petroleum hydrocarbon (TPH) in petroleum hydrocarbon-contaminated soil.METHOD AND RESULTS: An arable soil was artificially contaminated by diesel, and compost was applied at the different rate of 0, 10, 30, and 50 Mg/ha. Concentration of TPH in the soil decreased as application rate of compost increased. Degradation efficiency was highest at compost 30 Mg/ha; however, it slightly decreased with compost 50 Mg/ha. Kinetic modeling was performed to estimate the rates of chemical reaction. The correlation coefficient (R2) values for the linear plots using the second-order model were higher than those using the first-oder model. Compost 30 and 50 Mg/ha had the fastest TPH degradation rate in the second-order model. Change of microbial population in soil with compost application was similar to that of TPH. Microbial population in the soil increased as application rate of compost increased. Increasing microbial population in the contaminated soil corresponded to decreased in TPH concentration.CONCLUSION: Conclusively, compost application for soil bioremediation could be an effective response to petroleum hydrocarbon-contaminated soil. The increase in microbial population with compost suggested that compost application at an optimum rate might enhance degradation of TPH in soil.

A Study on the Nursing Performance of the Home Care Nurses in Seoul (서울지역 가정간호사의 업무수행능력 실태조사)

  • Suh, Moon-Ja;Park, Ho-Ran;Kang, Hyun-Sook;Kim, So-Sun;Shin, Kyung-Lim;Kim, Keun-Soon;Kim, Hae-Sook
    • Journal of Korean Academic Society of Home Health Care Nursing
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    • v.6
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    • pp.46-58
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    • 1999
  • The purpose of this research was to find out the state of the nursing performance of the home care nurses in Seoul in order to provide the data for the practical work guide. The data were collected from fifty home care nurses working in 22 institutions located in Seoul. The research tool used for this research was modified and tested by Song Jong-Rye(1999) which was originally modified the standard tool of American Nurses Association (1998) and was partly supplement and adjusted for this research. The reliability of this tool was Cronbach's $\alpha$=.0982. The collected data were statistically processed using SAS for t-test, ANOVA. $Scheff\'{e}$ test. Among the surveyees, 50% have been working as a home care nurse more than three years and 74.0% of them were married. And 52% have B.S degree with certification of home care nurse from the certification program for Home Care Nurses affiliated at nursing schools. Half of the home care nursing organizations were based on the general hospitals, and most(78%) of the responsible senior personnels of those organizations were nurses. The following results are drawn from this research. 1) The level of nursing performance by the task sectors General performance level of home care nurses was relatively high in grade of 3.06 from total 4.00. Among the task sectors. the ethical field scored the highest points, and the next were nursing intervention, professional training, and data gathering, and the research sector scored the lowest point. 2) The level of nursing performance by general features of home care nurses Statistically relevant correlation between performance according to the duration of working experience as a nurse(p=0.8951) and performance according to the duration of working as home care nurse(p=0.2263) did not emerge. Also, performance by marriage status(p=0.2218), education(p=0.5733), and taking the certification program for home card nurse(p =0.1560) has no statistically meaningful correlation. 3) The level of nursing performance by the type of home care nursing organizations There exists a significant difference(p=0.002) between performances by the types of organizations. Most of the responsible senior personnels of the home care nursing organization were nurses. The level of nursing performance of the home care nursing organization under nurse management was relatively higher than that of home care nursing organizations led by medical doctors or non-medical professional, but this was not proved as statistically meaningful(p =0.3617). 4) The level of nursing performance by task sectors according to the characteristic of home care nursing service organization There exists a significant difference between nursing performances by task sectors according to the characteristics of home care nursing organization(p=0.002). In case of model research center of one College of Nursing, the nursing performance in the sectors of organization, theory, and data gathering were lower than that of in hospital based home care nursing service. And in case of local home care centers, performances in sectors of organization, theory, data gathering, nursing intervention. professional training, and research sectors were significantly low. Based on the obtained results, overall performance of home care nurses can be appraised as relatively good. Especially, performances in sectors of the nursing intervention, nursing plan. and data gathering including the in direct nursing were recorded high scores. From this, it can be concluded that high quality of nursing is relatively practicing for home patients at these days. Since the high quality of nursing for patients was directly related to the level of nursing performances of home care nurses, it is required to improve practical performance level of them by making constant evaluation and running continual education program and supplementing curriculum for the sectors with low scores.

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