• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.189-189
• /
• 2006

The self-assembly of supramolecular dendrimers allows the rapid construction of nanosized structures with regularly ordered features that depend on the shape of the molecules and the relative strength of the intra-and intermolecular interactions. Here we report on a dramatic improvement in the degree of control and selectivity in the orientation of fan-shaped supramolecular molecules over a large area, which has been achieved by confined geometries and applied fields. The order and orientation of supramolecular dendrimers can be controlled by surface anchoring in confined geometries. POM, SEM, TEM, AFM and XRD results show that the molecules form the complicated defect-ordering in the microchannels with different feature sizes. We show that these defect domains are strongly influenced by the boundary and feature size of the surfaces. This technique can be used to create a grain size in the plane of the film that is much larger than that which can be achieved using previously reported soft-material based pattering.

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.277-277
• /
• 2006

Conducting polymers (e.g. poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylen vinylene] (MEH-PPV)) confined in one-dimensional nanoscale channels of mesoporous materials, are expected to lead the novel applications for electroconductive and optoelectronic devices. We investigated the adsorption behavior of MEH-PPV on organically surface-modified mesoporous silica (FSM-16) and mesoporous organosilica. The amount of the confined MEH-PPV was found to strongly depend on the surface modifications of the mesoporous materials. The optical absorption edge of the confined MHE-PPV was clearly blue-shifted when compared to that of a free MHE-PPV.

• Transactions of Materials Processing
• /
• v.13 no.4
• /
• pp.382-387
• /
• 2004

The continuous confined strip shearing (CCSS) based on the equal channel angular pressing (ECAP) was modeled by means of a rigid-plastic two-dimensional finite element method (FEM). Parallel to the simulations, samples of AA 1050 sheets were experimentally deformed by CCSS. The CCSS deformation led to the formation of through thickness texture gradients comprising a strong shear texture in the sheet center and weak shear textures in the sheet surfaces. FEM analysis revealed variations in the strain component $\varepsilon_13$ along the sample thickness direction, which gave rise to the evolution of different textures. A high friction between the sample and die surface was responsible for lowering intensities of the shear texture components in thickness layers close to the surfaces.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.04a
• /
• pp.743-749
• /
• 1999

Recently new rehabilitation techniques have been proposed with advanced composite materials like carbon fiber, aramid, glass fiber sheet and so forth. The purpose of this paper is to investigate the mechanical characteristics of reinforced concrete columns confined with carbon fiber sheet and evaluate the degree of their strengthening effect. For the test, the specimen size of column is 15cm$\times$15cm$\times$90cm reinforced with 4 number of main bars of 10 mm diameter, tied bars of 6 mm diameter and slenderness ratio 20. Columns were wrapped with carbon fiber sheet along the column length. It is necessary to make some assumption regarding the confinement of carbon fiber sheet to apply to reinforced concrete columns under concentric loads. The strength gain effect of columns confined with carbon fiber sheet could be predicted using the proposed equation.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.10a
• /
• pp.285-290
• /
• 2000

A mathematical model which can simulate biaxial moment-curvature relations for reinforced concrete column is developed. The developed model is capable of tracing the post-peak behavior of a column after peak load. The model can take into account different sectional shapes of a column and various constitutive models of confined concrete. The developed model is used to evaluate constitutive models of confined concrete under concentric loading, suggested by different researchers. Error function which measures the overall constitutive behavior of a confined concrete is intrcduced. The constitutive model minimizing this error function is selected and is incorporated into the developed model in order to investigate the effect of main parameters on the general column behavior.

• KCI Concrete Journal
• /
• v.14 no.4
• /
• pp.139-144
• /
• 2002

Concrete filled FRP tube has lately attracted attention as the member that can substitute the conventional reinforced concrete. Glass fiber and carbon fiber are some of available materials for FRP tube. Carbon tube is filament wound with specified winding angle to meet the appropriate capacity demands. Confinement effect of carbon tube is varied according to winding angle. In this study, a total 4 of large scale circular specimens of 30cm diameter and 60cm height is tested. To estimate the effect of winding angle and thickness of carbon tube on the increased confined compressive strength, the test tube are wound with $\pm45^{\circ}\;and\;\pm30^{\circ}$ with two types of thickness, 2mm and 3mm, respectively. It is shown that effectively increased confined strength and ductility are observed from the specimens with $\pm45^{\circ}$ winding angle than $\pm30^{\circ}$ winding angle. Increasing thickness is not as effective as adjusting winding angle for the confinement of concrete core.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.05a
• /
• pp.62-65
• /
• 2006

This study investigated the behavior of R/C column confined with headed crossties subjected to eccentric loading. The 16 specimens are designed to have adequate confinement steel, determined by ACI seismic design. The variables studied in this research test are eccentricity to depth ratios, spacing of lateral steel and the anchor type of end of crossties. From the test results, all columns showed similar behavior up to the peak load but those columns laterally confined with head presented more ductile behavior after the peak load. The comparisons indicate that the flexural behavior of confined-concrete columns can be computed resonable accurately by P-M interaction curve.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.05a
• /
• pp.430-433
• /
• 2006

The reinforced concrete column confined by square steel tubes(RCST) is a reinforced column (RC) confined by thin steel tubes which cover over the full length of the column but terminates 15mm from the column's ends. The steel tube is in uniaxial tension stress state and won't buckle when the column sustains axial load. This will highly increase the bearing capacity and ductility of the columns. The hysteretic behavior of four square RCST columns and one square RC column were experimentally studied under constant axial load and lateral cyclic load. The wide-to-thickness (D/t) ratio of RCST columns employed in this research is 75. The main variables of the experiment were axial load ratio and compressive strength of the concrete. Based on the findings in this research, RCST columns exhibits high lateral strength, ductility, and energy dissipation ability.

• The Korean Journal of Ceramics
• /
• v.7 no.2
• /
• pp.70-73
• /
• 2001

Phase transformation of TiSi$_2$ confined in sub-micron area of which the size is around or smaller than the grain size of C49 TiSi$_2$ phase is studied. It has been known that the C49 to C54 phase change is massive transformation that occurs abruptly starting from C54 nuclei located at triple point grain boundaries of C49 phase. When the C49 phase is confined in sub-micron area, however, the massive phase transformation is observed to be hindered due to the lack of the triple point grain boundaries of C49 phase. Heat treatment at higher temperatures starts to decompose the C49 phase, and the resulting decomposed Ti atoms diffuse to, and react with, the underneath Si material to form C54 phase that exhibits spherical interface with silicon. The newly formed C54 grains can also trigger the massive phase transformation to convert the remaining undecomposed C49 grains to C54 grains by serving as nuclei like conventional C54 nuclei located at triple point grain boundaries.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2010.05a
• /
• pp.87-88
• /
• 2010

The strength and ductile capacity of reinforced concrete column can be improved by confinement using transverse reinforcement. Variety stress-strain models about the reinforced concrete confined by transverse reinforcement has been proposed. In this paper, parameters which effect to the ultimate confinement stress of circular cylinder confined by high strength transverse steel is examined. And the possion's ratio equation is proposed by analysis of strain between concrete and transverse reinforcement.