• Title/Summary/Keyword: Confined

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Nanospace Confinement of Conducting Polymers using Mesoporous Silica and Organosilica

  • Itahara, Hiroshi;Inagaki, Shinji;Asahi, Ryoji
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.277-277
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    • 2006
  • Conducting polymers (e.g. poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylen vinylene] (MEH-PPV)) confined in one-dimensional nanoscale channels of mesoporous materials, are expected to lead the novel applications for electroconductive and optoelectronic devices. We investigated the adsorption behavior of MEH-PPV on organically surface-modified mesoporous silica (FSM-16) and mesoporous organosilica. The amount of the confined MEH-PPV was found to strongly depend on the surface modifications of the mesoporous materials. The optical absorption edge of the confined MHE-PPV was clearly blue-shifted when compared to that of a free MHE-PPV.

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Analysis on Inhomogeneous Textures Developed in Aluminum AA 1050 Sheets during Continuous Confined Strip Shearing (알루미늄 AA 1050 판재구속전단가공 시 불균질 집합조직 형성의 해석)

  • 이재필;석한길;허무영
    • Transactions of Materials Processing
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    • v.13 no.4
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    • pp.382-387
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    • 2004
  • The continuous confined strip shearing (CCSS) based on the equal channel angular pressing (ECAP) was modeled by means of a rigid-plastic two-dimensional finite element method (FEM). Parallel to the simulations, samples of AA 1050 sheets were experimentally deformed by CCSS. The CCSS deformation led to the formation of through thickness texture gradients comprising a strong shear texture in the sheet center and weak shear textures in the sheet surfaces. FEM analysis revealed variations in the strain component $\varepsilon_13$ along the sample thickness direction, which gave rise to the evolution of different textures. A high friction between the sample and die surface was responsible for lowering intensities of the shear texture components in thickness layers close to the surfaces.

A Study on Mechanical Characteristics of Reinforced Concrete Columns Confined with Carbon Fiber Sheet (CFS로 횡보강된 철근콘크리트 기둥의 역학적 특성에 관한 연구)

  • 권영웅;정성철
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.743-749
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    • 1999
  • Recently new rehabilitation techniques have been proposed with advanced composite materials like carbon fiber, aramid, glass fiber sheet and so forth. The purpose of this paper is to investigate the mechanical characteristics of reinforced concrete columns confined with carbon fiber sheet and evaluate the degree of their strengthening effect. For the test, the specimen size of column is 15cm$\times$15cm$\times$90cm reinforced with 4 number of main bars of 10 mm diameter, tied bars of 6 mm diameter and slenderness ratio 20. Columns were wrapped with carbon fiber sheet along the column length. It is necessary to make some assumption regarding the confinement of carbon fiber sheet to apply to reinforced concrete columns under concentric loads. The strength gain effect of columns confined with carbon fiber sheet could be predicted using the proposed equation.

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Modeling and Parametric Studies on Moment-Curvature Relations for Reinforced Concrete Columns (철근콘크리트 기둥의 휨-곡률 모델링 및 변수고찰)

  • 이차돈;최기봉;차준실
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.285-290
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    • 2000
  • A mathematical model which can simulate biaxial moment-curvature relations for reinforced concrete column is developed. The developed model is capable of tracing the post-peak behavior of a column after peak load. The model can take into account different sectional shapes of a column and various constitutive models of confined concrete. The developed model is used to evaluate constitutive models of confined concrete under concentric loading, suggested by different researchers. Error function which measures the overall constitutive behavior of a confined concrete is intrcduced. The constitutive model minimizing this error function is selected and is incorporated into the developed model in order to investigate the effect of main parameters on the general column behavior.

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Experiment of Compressive Strength Enhancement of Circular Concrete Column Confined by Carbon Tubes

  • Hong Won-Kee;Kim Hee-Cheul;Yoon Suk-Han
    • KCI Concrete Journal
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    • v.14 no.4
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    • pp.139-144
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    • 2002
  • Concrete filled FRP tube has lately attracted attention as the member that can substitute the conventional reinforced concrete. Glass fiber and carbon fiber are some of available materials for FRP tube. Carbon tube is filament wound with specified winding angle to meet the appropriate capacity demands. Confinement effect of carbon tube is varied according to winding angle. In this study, a total 4 of large scale circular specimens of 30cm diameter and 60cm height is tested. To estimate the effect of winding angle and thickness of carbon tube on the increased confined compressive strength, the test tube are wound with $\pm45^{\circ}\;and\;\pm30^{\circ}$ with two types of thickness, 2mm and 3mm, respectively. It is shown that effectively increased confined strength and ductility are observed from the specimens with $\pm45^{\circ}$ winding angle than $\pm30^{\circ}$ winding angle. Increasing thickness is not as effective as adjusting winding angle for the confinement of concrete core.

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The Effect of Spacing of Transverse Steel on R/C Column Laterally Reinforced with Head Subjected to Eccentric Loading (Head로 횡구속된 편심하중을 받는 R/C기둥의 띠철근비의 영향)

  • Yoon, Seung-Joe;Lee, Woo-Jin;Kim, Sang-Koo;Yoon, Yong-Dae;Seo, Soo-Yeon;Kim, Seoung-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05a
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    • pp.62-65
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    • 2006
  • This study investigated the behavior of R/C column confined with headed crossties subjected to eccentric loading. The 16 specimens are designed to have adequate confinement steel, determined by ACI seismic design. The variables studied in this research test are eccentricity to depth ratios, spacing of lateral steel and the anchor type of end of crossties. From the test results, all columns showed similar behavior up to the peak load but those columns laterally confined with head presented more ductile behavior after the peak load. The comparisons indicate that the flexural behavior of confined-concrete columns can be computed resonable accurately by P-M interaction curve.

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Hysteretic Behavior of Reinforced Concrete Columns Confined By Square Steel Tubes. (정방향 STRC 기둥의 자기이력현상 거동)

  • Wang, Xiaoyong;Zhang, Sumei;Lee, Han-Seaung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05a
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    • pp.430-433
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    • 2006
  • The reinforced concrete column confined by square steel tubes(RCST) is a reinforced column (RC) confined by thin steel tubes which cover over the full length of the column but terminates 15mm from the column's ends. The steel tube is in uniaxial tension stress state and won't buckle when the column sustains axial load. This will highly increase the bearing capacity and ductility of the columns. The hysteretic behavior of four square RCST columns and one square RC column were experimentally studied under constant axial load and lateral cyclic load. The wide-to-thickness (D/t) ratio of RCST columns employed in this research is 75. The main variables of the experiment were axial load ratio and compressive strength of the concrete. Based on the findings in this research, RCST columns exhibits high lateral strength, ductility, and energy dissipation ability.

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Diffusion-accompanied Phase Transformation of $TiSi_2$ Film Confined in Sub-micron Area

  • Kim, Yeong-Cheol
    • The Korean Journal of Ceramics
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    • v.7 no.2
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    • pp.70-73
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    • 2001
  • Phase transformation of TiSi$_2$ confined in sub-micron area of which the size is around or smaller than the grain size of C49 TiSi$_2$ phase is studied. It has been known that the C49 to C54 phase change is massive transformation that occurs abruptly starting from C54 nuclei located at triple point grain boundaries of C49 phase. When the C49 phase is confined in sub-micron area, however, the massive phase transformation is observed to be hindered due to the lack of the triple point grain boundaries of C49 phase. Heat treatment at higher temperatures starts to decompose the C49 phase, and the resulting decomposed Ti atoms diffuse to, and react with, the underneath Si material to form C54 phase that exhibits spherical interface with silicon. The newly formed C54 grains can also trigger the massive phase transformation to convert the remaining undecomposed C49 grains to C54 grains by serving as nuclei like conventional C54 nuclei located at triple point grain boundaries.

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A stress-strain Model of High-strength concrete confined with Transverse Reinforcement (횡보강철근으로 구속된 고강도 콘크리트의 응력-변형률 구속 모델)

  • Moon, Cho-Hwa;Park, Jong-Wook;Kim, Sang-Woo;Kim, Kil-Hee;Lee, Jung-Yoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.87-88
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    • 2010
  • The strength and ductile capacity of reinforced concrete column can be improved by confinement using transverse reinforcement. Variety stress-strain models about the reinforced concrete confined by transverse reinforcement has been proposed. In this paper, parameters which effect to the ultimate confinement stress of circular cylinder confined by high strength transverse steel is examined. And the possion's ratio equation is proposed by analysis of strain between concrete and transverse reinforcement.

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Women′s Indoor and Outdoor Everyday Life of the Late Choson Period as Expressed in Paintings (조선시대 여성의 가내외에서의 일상생활 -조선후기 회화에 나타난 여성을 중심으로-)

  • 김성희
    • Journal of the Korean Home Economics Association
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    • v.42 no.7
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    • pp.33-53
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    • 2004
  • The purpose of this study was to investigate women's indoor and outdoor everyday life including their housework, labor and leisure of the late Chosen period as expressed in paintings. Women's everyday life was classified into their indoor and outdoor life according to the custom of Naeoe, which had confined women's activities in the outdoors. This study analyzed 93 Paintings depicting the Due life of People. As a result, even though the Chosen period was a conservative society dominated by Confucian custom that confined women in the home, most women spent much of their time in the outdoors carrying water, washing clothes and doing farm work. Some common women participated in marketing household product, peddling and managing a drink shop. Especially, servant women such as Kineo, Muneo and Youneo labored in Public offices or Private Places. Consequently, this study suggests that the misconception should be corrected that traditional women's sex role had been confined exclusively in the home.