• Journal of the Korean Geosynthetics Society
• /
• v.20 no.4
• /
• pp.1-7
• /
• 2021

In response to the carbon emission reduction trends and the depletion of natural sand caused by the use of cement in construction works, graphene oxide and porous feldspar were applied as countermeasures in this study. By using (3-aminopropyl)trimethoxysilane-functionalized graphene oxide with enhanced bond characteristics, a concrete specimen was prepared with 5% less cement content than that in a standard mortar mix, and the compressive strengths of the specimens were examined. The compressive strengths of the specimen with (3-aminopropyl)trimethoxysilane-functionalized graphene oxide and porous feldspar and the specimen with standard mixing were 26MPa and 28MPa, respectively, showing only a small difference. In addition, both specimens met the compressive strength of cement mortar required for geotechnical structures. It is believed that a reasonable level of compressive strength was maintained in spite of the lower cement content because the high content of pozzolans, namely SiO₂ and Al₂O₃, in the porous feldspar enhanced the reactions with Ca(OH)₂ during hydration, the nano-sized graphene surface acted as a reactive surface for the hydration products to react actively, and the strong covalent bonding of the carboxyl functional group increased the bonding strength of the hydration products.

• Journal of the Korea Institute of Building Construction
• /
• v.23 no.6
• /
• pp.703-714
• /
• 2023

This research conducts a series of tests to investigate the setting retarding properties and strength development in cement pastes incorporating various types and dosages of sugar-based super retarding agents. Six such agents, including Sucrose, Sugar powder, Saccharin, Aspartame, Stevioside, and Mogroside, commercially available, were selected for evaluation. The study also examines the micro-structural properties of these cement pastes. The test mixtures were prepared using a 27.5% water-to-cement ratio and ordinary Portland cement. Micro-structural analyses were conducted using Scanning Electron Microscopy(SEM), X-Ray Diffraction(XRD), and Energy Dispersive Spectroscopy(EDS). The findings reveal that the incorporation of sucrose, sugar powder, and stevioside significantly retards the setting time. Particularly, adding 0.1% sucrose extended the setting time by approximately two-fold compared to the control(Plain) mixture. Most mixtures, barring those with sugar powder and stevioside, exhibited compressive strength comparable to the Plain mixture. Notably, with 0.2% sucrose, strength measurements were not feasible at 1 day, but at 3 days, the strength gains aligned with the Plain mixture. XRD, SEM, and EDS analyses confirmed the hydration delay(set retarding) of C3S due to sucrose, with further quantitative corroboration provided by EDS. SEM was used to verify the presence or absence of hydration products. The study concludes that sucrose, as a sugar-based retarder, offers effective set retarding capabilities and compressive strength development in concrete.

• Journal of the Korea Institute of Building Construction
• /
• v.16 no.1
• /
• pp.59-65
• /
• 2016

This study examined the compressive strength development and pH values of alpha-calcium sulfate hemihydrate(${\alpha}-CH$)-based binders developed for vegetation concrete with neutral pH between 6~7. Considering cost down and strength enhancement of the prepared binders, the ${\alpha}-CH$ was partially replaced by ground granulated blast furnace slag(GGBS), fly ash(FA), or ordinary Portland cement(OPC) by 25% and 50%. The compressive strength of mortars using 100% ${\alpha}-CH$ was 50% lower than that of 100% OPC mortars. With the increase of the replacement level of GGBS or FA, the compressive strength of ${\alpha}-CH$-based mortars tended to decrease, whereas the pH values were maintained to be 6.5~7.5. The main hydration products of ${\alpha}-CH$-based binders with GGBS or FA were a gypsum($CaSO_4$), whereas portlandite($Ca(OH)_2$) was not observed in such binders. Meanwhile, the pH values of ${\alpha}-CH$-based binders with OPC exceeded 11.5 due to the formation of $Ca(OH)_2$ phase as a hydration product. From the thermogravimetric analysis, the amount of $Ca(OH)_2$ in ${\alpha}-CH$-based binders with OPC was evaluated to be approximately 10% of the cement content.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.24 no.3
• /
• pp.96-103
• /
• 2020

As a basic study for the application of natural zeolite as a concrete admixture, the compressive strength, activity factor, Ca(OH)₂ quantitative analysis and XRD experiments were investigated. It is thought that SiO₂, which is abundant in natural zeolite, affects the strength development by reacting with the hydration product of cement in all specimens in which natural zeolite was added according to powder level and substitution rate. As the substitution rate increases, the compressive strength decreases, which is considered to be due to the decrease in the amount of C₃S and C₂S minerals in the clinker, which affects the strength expression compared to the cement content of the reference mortar. The XRD crystal structure did not show a significant difference from the reference mortar, and it was confirmed that the Z2-10 (Blaine: 15,600㎠ / g) specimen with 10% substitution of natural zeolite was the best among the experimental levels. Substitution amount for use as concrete admixture is 10% substitution is most ideally seen.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.2
• /
• pp.119-127
• /
• 2011

Objective of this study is to identify properties on strength increase of hardened concrete and fluidization of non-hardened concrete using waste ceramics generated by construction waste, which is a type of industrial waste, and by ceramics, which is a clay plastic, during its production process, and determine length change ratio caused by drying shrinkage during substitution of recycle aggregate and waste ceramics, and whether they can be used as concrete compounds. Slump of non-hardened concrete exhibited the best fluidization and formability at recycled aggregate's replacement ratio of 60% driven by higher substitution ratio of recycled aggregate and waste ceramics while air content met the KS requirement when substitution ratio of waste ceramics was $4,000cm^2/g$. Compressive strength of hardened concrete exceeded the requirements at early age and standard age and temperature dropped by roughly $6{\sim}10^{\circ}C$ less than the standard at maximum temperature in adiabatic temperature increase, which will hopefully result in stronger durability.

• Journal of the Korea Institute of Building Construction
• /
• v.9 no.5
• /
• pp.127-133
• /
• 2009

It is important to increase the strength of binders in order to enhance the strength of concrete. However, when the mineral admixture used for high strength concrete is incorporated individually, its dispersibility decreases due to the phenomenon of compaction, which reduces its fluidity and results in insufficient strength being created. To solve this problem, we can pre-mix each binder in advance to disperse a mineral admixture among binders, which will strengthen the fluidity and strength of concrete. Therefore, this study analyzed the properties of high strength concrete depending on the mix method used, to determine the effect of pre-mix cements ranging from W/B 15 to 35%. It was found that the fluidity of pre-mix increased to a level higher than that of individual mix due to its dispersion and ball bearing effect. The air content was slightly decreased from the result of individual mix due to the micro filler effect, which causes fine particles of silica-fume to fill the voids among cement particles, while the setting time of pre-mix was shorter than that of individual mix, because enhanced dispersion of pre-mix affects hydration heat time. The compressive strength of pre-mix increased due to the phenomenon of compaction of gap structure, and the variation of coefficient decreased by 1.69% on average in strength variation.

• International Journal of Highway Engineering
• /
• v.11 no.2
• /
• pp.185-194
• /
• 2009

The autogenous shrinkage of high-performance concrete, including very-early strength latex-modified concrete(VES-LMC), is generally bigger than that of normal strength concrete because of the low water/cement ratio, high binder contents, and usage of superplasticizer. Mix. proportion of VES-LMC has low water/cement ratio(0.38), high cement content(390kg/m$^3$), and aid of latex(15% of cement weight). Thus, these factors of VES-LMC, rapid water self-dissipation and evaporation within 3 hours of concrete placement would increase the autogenous shrinkage. The purpose of this study was to evaluate the early-age shrinkage, thermal deformation and autogenous shrinkages of VES-LMC with retarder contents(retarder solids-cement ratio, by weight) using to secure working time in field. The experimental results showed that retarder contents do not affect of the maximum hydration temperature. Early-age expansion of VES-LMC was mostly caused by thermal expansion and partly by autogenous expansion. The autogenous shrinkage is decreased by increasing the retarder contents within this study. On the other hand, the usage of retarder should be decided carefully considering the field conditions because an excessive usage of retarder can cause handful early-age expansion.

• International Journal of Highway Engineering
• /
• v.13 no.2
• /
• pp.103-114
• /
• 2011

Usage of bicycle has been supported the universal reduction of energy consumption and $CO_2$. For the same purpose, new constructions for long length bike roads are planned in Korea. Recently, laboratory tests of physical properties and resistance against environmental loading about optimum mix design of roller compacted concrete, that have advantages of high structural performance by cement hydration and aggregate interlocking, simple construction procedure and low construction cost, are performed for the effective construction of new bike roads. However, properties of roller compacted concrete had different results between laboratory and field tests since it had different compaction method. Also, construction method of roller compacted concrete are not defined for the application of bike roads since it had different demand performance such as thin pavement thickness, low strength and etc with road pavements. Thus, in this experimental research was launched to evaluate the core properties, visual inspection, compaction ratio, water content, thickness reduction rate of roller compaction, skid resistance and roughness by experimental construction about variable mix proportion and compaction method based on laboratory test results. And construction method of roller compacted concrete pavement were suggested for the application of bike roads.

• Resources Recycling
• /
• v.19 no.5
• /
• pp.50-57
• /
• 2010

Ternary blended concrete(TBC), which contains both fly ash and granulated blast furnace slag, has an initial cost effective and is environment friendly. Furthermore, it has a lot of technical advantages such as the improvement of long term compressive strength, high workability, and the reduction of hydration heat. However, as the use and study on the performance of ternary blended concrete is limited, it is low short term compressive strength. This study was performed to evaluate the characteristics which are a long and short term compressive strengths, permeability and chemical attacks resistance of hardened high early concrete containing slag powder and fly-ash using high early strength cement(HE-TBC). Replacement rate of FA is fixed on 10% and replacement rate of slag powder are 0%, 10%, 20% and 30%. The test results showed that compressive and flexural strength of HE-TBC increased as the slag contents increased from 0% to 30% at the short term of curing. The permeability resistance of HE-TBC(fly ash 10%, blast 30%) was extremely good at the short and long terms. However, high early strength ternary blended concrete had weak on carbonation of chemical attack.

• Journal of the Korea Concrete Institute
• /
• v.15 no.2
• /
• pp.305-313
• /
• 2003

The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the coefficient of air convection, which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind and types of form. From experimental results, the coefficient of air convection was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent coefficient of air convection including effects of velocity of wind and types of form was theoretically proposed. The coefficient of air convection in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with types of form. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the coefficient of air convection by this model was well agreed with those by experimental results.