• Geomechanics and Engineering
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• v.25 no.1
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• pp.31-40
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• 2021

Injection grouting is one of the most common ground improvement practice to increase the strength and reduce the hydraulic conductivity of soils. Owing to the environmental concerns of conventional grout materials, such as cement-based or silicate-based materials, bio-inspired biogeotechnical approaches are considered to be new sustainable and environmentally friendly ground improvement methods. Biopolymers, which are excretory products from living organisms, have been shown to significantly reduce the hydraulic conductivity via pore-clogging and increase the strength of soils. To study the practical application of biopolymers for seepage and ground water control, in this study, we explored the injection capabilities of biopolymer-based grout materials in both linear aperture and particulate media (i.e., sand and glassbeads) considering different injection pressures, biopolymer concentrations, and flow channel geometries. The hydraulic conductivity control of a biopolymer-based grout material was evaluated after injection into sandy soil under confined boundary conditions. The results showed that the performance of xanthan gum injection was mainly affected by the injection pressure and pore geometry (e.g., porosity) inside the soil. Additionally, with an increase in the xanthan gum concentration, the injection efficiency diminished while the hydraulic conductivity reduction efficiency enhanced significantly. The results of this study provide the potential capabilities of injection grouting to be performed with biopolymer-based materials for field application.

• Corrosion Science and Technology
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• v.3 no.6
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• pp.245-250
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• 2004

A series of classical G109 type concrete specimens was exposed to cyclic wet and dry ponding with 15 w/o NaCl solution for approximately five years. Mix design variables included 1) three cement alkalinities (EqA of 0.97, 0.52, and 0.36) and 2) three water-cement ratios (0.50, 0.41, and 0.37). To determine the corrosion initiation time, corrosion potential and macro-cell current between top and bottom bars were monitored. Subsequent to corrosion initiation, specimens were autopsied and visually inspected. Concrete powder samples were collected from top rebar trace and chloride concentration was measured. Also, time-to-corrosion, $T_i$, for specimens of the individual mix designs was represented using Weibull analysis. Time-to-corrosion was a distributed parameter; and because of this, corrosion initiation of four identical specimens for each mix varied, often over a relatively wide range. Specimens fabricated using the lowest water cement ratio and the highest alkalinity cement exhibited the longest time-to-corrosion initiation and the highest chloride threshold levels. Time-to-corrosion did not increase monotonically with cement alkalinity, however, presumably as a consequence of relatively high $Cl^-$ binding in the lower pore water pH range. The chloride threshold level, $Cl_{th}$, increased with increasing $T_i$ and, consequently, was greatest for the highest cement alkalinity specimens.

• Journal of Biomedical Engineering Research
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• v.35 no.6
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• pp.192-196
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• 2014

Collagen scaffolds were synthesized by cross linking into a solution mixture of 1-ethyl-3-[3-dimethylaminopropyl] carbodiimide hydrochlorid(EDC) in ethanol, followed by pressing, cleaning and lyophilization process after the type I atelo-collagen solutions in D.I water(pH3). The experimental conditions are collagen concentration of 1.0 wt%, 3.0 wt%, 5.0 wt% and differential concentration of cross-linker. Then, parametric studies were performed by varying the parameters to investigate the morphology, the porosity, the swelling ratio and the thickness and genotoxicity of the scaffolds. The scaffolds thickness pattern was regular to concentration of the degree of cross-linker and collagen. It was observed that the swelling ratio, the degree of crosslink, and the pore size(thickness of scaffold) can be controlled by adjusting the collagen, crosslinker. Among the parameters investigated, the smallest thickness can be achieved by collagen, crosslinker concentrate condition. The collagen scaffold is induced no genotoxicity. The lowest swelling ratio, as an indication of the highest degree of crosslink, can be obtained by adding crosslink agent.

• Membrane Journal
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• v.28 no.1
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• pp.62-66
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• 2018

In this study the cleaning spherical beads with same density as water were fabricated. Bead moving velocity was measured with respect to the aeration rate and bead concentration in water reservoir. The permeation experiments for FR (filtration and relaxation) and SFCO (sinusoidal filtration continuous operation) modes were simultaneously carried out under the condition of 1 to 3% cleaning spherical bead concentration, 20 LMH and 500 mL/min aeration rate in the MLSS 8,000 mg/L activated sludge solution. The used membrane was the $90cm^2$ effective area and $0.4{\mu}m$ nominal pore size flat membrane. The TMP (transmembrane pressure) decreased as the bead concentration increased, and was shown most effective in FR mode with 2% bead concentration.

• Membrane Journal
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• v.17 no.1
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• pp.14-22
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• 2007

This is the research about the concentration of trace Magnolia flavor components in water by pervaporation. We have investigated the change of selectivity depending on support membrane structure and active layer thickness using prepared PVDF/PDMS composite membrane. Through the pure water flux test for PVDF support membrane, we could indirectly confirm that as the coagulation temperature decreases and the polymer concentration increases, the surface porosity and pore diameter decreases. Appling these results to transport mechanism, we could explain the effect of support membrane structure for the composite membrane. The selectivity increases as the thickness of PDMS active layer increases. We could know that there is a limitation to describe the transport on the active layer by Fick's law through these results.

• Membrane Journal
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• v.26 no.1
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• pp.70-75
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• 2016

The reuse of wastewater is being diffused to manage and develop the water resources. Generally, the treated wastewater is discharged to the river after being treated to meet the effluent quality standard or reused for diverse uses through the reprocessing. And recently, as the reuse of the treated wastewater is activated, the technologies to utilize for the high quality water resources such as industrial water by reusing the wastewater with Membrane Distillation (MD) are under development. In this study, the direct contact membrane distillation (DCMD) process has been applied to treat sewage discharge water for water reuse. The laboratory scale experiment was performed by using a hydrophobic PVDF membrane with the pore size of $0.22{\mu}m$. The influence of operating parameters, such as feed temperature, feed flow rate, feed concentration, on the permeate flux and rejection has been investigated. All filtration tests were conducted till the feed volume reached a concentration factor of 3.0. Thus, the operating period ranged between 19 hr and 49 hr depending on filtration performance. The results showed that above 92% of TN, TP, COD and TOC in the feed could be rejected regardless of an operating condition. The water flux was ranged from 13.8 to 20.3 LMH. The lowest flux was obtained at the operating condition with the feed temperature of $50^{\circ}C$ and feed flow velocity of 500 mL/min while the highest one was measured with $60^{\circ}C$ and 900 mL/min. When the concentration factor reached 3.0, water flux declined by approximately ranged from 14.5% to 33.3%. But the fouling in MD is almost fully reversible, with more than 90% recovery of permeate water flux following a DI water rinse without the addition of chemical cleaning reagents.

• Journal of Soil and Groundwater Environment
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• v.11 no.2
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• pp.68-76
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• 2006

Anaerobic reductive dechlorination of tetrachloroethylene (PCE) to ethylene was investigated by performing laboratory experiments using semi-continuous flow two-in-series soil columns. The columns were packed with soils obtained from TCE-contaminated site in Korea. Site ground water containing lactate (as electron donor and/or carbon source) and PCE was pumped into the soil columns. During the first operation with a period of 50 days, injected mass ratio of lactate and PCE was 620:1 and incomplete reductive dechlorination of PCE to cis-DCE was observed in the columns. However, complete dechlorination of PCE to ethylene was observed when the mass ratio increased to 5,050:1 in the second operation, suggesting that the electron donor might be limited during the first operation period. Dechlorination rate of PCE to cis-DCE was $0.62{\sim}1.94\;{\mu}mol$ PCE/L pore volume/d and $2.76\;{\mu}mol$ cis-DCE/ L pore volume/d for that for cis-DCE to ethylene, resulting that net dechlorination rate in the system was 1.43 umol PCE/L pore volume/d. During the degradation of cis-DCE to ethylene, the concentration of hydrogen in column groundwater was $22{\sim}29\;mM$ and $10{\sim}64\;mM$ for the degradation of PCE to cis-DCE. These positive results indicate that the TCE-contaminated groundwater investigated in this study could be remediated through in-situ biological anaerobic reductive dechlorination processes.

• Proceedings of the KOSOMBE Conference
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• v.1997 no.05
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• pp.447-450
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• 1997

A new technique for the preparation of porous vascular prostheses was investigated. Polyurethane solution (10 to 14wt%) was injected into a mold. After freezing at low temperature $(0^{\circ}C\sim-40^{\circ}C)$, solvent was dissolved out with water at $0^{\circ}C$ to form porous tubes. The average pore size $(<10{\mu}m)$and pore occupation (10% to 51%) were easily changed by changing polyurethane concentration, freezing temperature, and freezing methods. This technique can give a proper pore size $(30\sim60{\mu}m)$ for tissue ingrowth, and suitable compliances for matching with arteries and veins. This method might give a desired compliant graft for artificial implantation with the presently valid medical polymers.

• Membrane and Water Treatment
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• v.6 no.3
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• pp.225-235
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• 2015

During low-pressure membrane treatments of cyanobacterial cells, including microfiltration (MF) and ultrafiltration (UF), there have reportedly been releases of intracellular compounds including cyanotoxins and compounds with an earthy-musty odor into the water, probably owing to cyanobacterial cell breakage retained on the membrane. However, to our knowledge, no information was reported regarding the effect of growth phase of cyanobacterial cells on the release of the intracellular compounds. In the present study, we used a geosmin-producing cyanobacterium, Anabaena smithii, to investigate the effect of the growth phase of the cyanobacterium on the release of intracellular geosmin during laboratory-scale MF experiments with the cells in either the logarithmic growth or stationary phase. Separate detection of damaged and intact cells revealed that the extent of cell breakage on the MF membrane was almost the same for logarithmic growth and stationary phase cells. However, whereas the geosmin concentration in the MF permeate increased after 3 h of filtration with cells in the logarithmic growth phase, it did not increase during filtration with cells in the stationary phase: the trend in the geosmin concentration in the MF permeate with time was much different between the logarithmic growth and stationary phases. Adsorption of geosmin to algogenic organic matter (AOM) retained on the MF membrane and/or pore blocking with the AOM were greater when the cells were in the stationary phase versus the logarithmic growth phase, the result being a decrease in the apparent release of intracellular geosmin from the stationary phase cells. In actual drinking water treatment plants employing membrane processes, more attention should be paid to the cyanobacterial cells in logarithmic growth phase than in stationary phase from a viewpoint of preventing the leakage of intracellular earthy-musty odor compounds to finished water.

• Analytical Science and Technology
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• v.24 no.2
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• pp.94-104
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• 2011

Mesoporous silica was synthesized in a water solvent and in an ethanol solvent with the non and cationic cetyltrimethyl ammonium chloride (CTAC) by varying the amount of the amphiphilic acrylic urethane oligomer (AAU) and the pH of the solution. The adsorption of the MX (3-chloro-4 (dichloromethyl)-5-hydroxy-2-(5H)-furanone) in drinking water was studied using the synthesized mesoporous silica as an adsorbent. The most appropriate silica was synthesized in acidic conditions in the water solvent and in alkali conditions in the ethanol solvent. The average pore sizes of the synthesized mesosilica were 3 nm and more. The mesoporous silica synthesized by the addition of the AAU oligomer showed excellent adsorption characteristics. With respect to the co-surfactant, the best adsorption characteristics were obtained when the P64,a non-ionic surfactant with a high molecular weight, was used to synthesize the silica than when other co-surfactants were used. The adsorption rate decreased as the MX concentration in the water increased. Different adsorption equilibrium conditions were reached depending on the adsorbate MX concentration in the adsorbent and the solution. It was seen that perfect adsorption does not occur due to such equilibrium conditions.