• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.14-21
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• 2008

Synthetic gas is defined as reformed gas from hydrocarbon-based fuel and the major chemical species of the synthetic gas are $H_2$, CO and $N_2$. Among them, hydrogen from synthetic gas is very useful species in chemical process such as combustion. It is a main reason that many studies have been performed to develop an effective reforming device. Furthermore, other technologies have been studied for synthetic gas application, such as the ESGI(Exhaust Synthetic Gas Injection) technology. ESGI injects and burns synthetic gas in the exhaust pipe so that heat from hydrogen combustion helps fast warmup of the close-coupled catalyst and reduction of harmful emissions. However, it is very hard to understand combustion characteristic of hydrogen under low oxygen environment and complicated variation in chemical species in exhaust gas. This study focuses on the characteristics of hydrogen combustion under ESGI operating conditions using a CVC(Constant Volume Chamber). Measurements of pressure variation and flame speed have been performed for various oxygen and hydrogen concentrations. Results have been analyzed to understand ignition and combustion characteristics of hydrogen under lower oxygen conditions. The CVC experiments showed that under lower oxygen concentration, amount of active chemicals in the combustion chamber was a crucial factor to influence hydrogen combustion as well as hydrogen/oxygen ratio. It is also found that increase in volume fraction of oxygen is effective for the fast and stable burning of hydrogen by virtue of increase in flame speed.

• Nuclear Engineering and Technology
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• v.33 no.1
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• pp.83-92
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• 2001

The properties of off-gas generated from vitrification process of ion-exchange resin were characterized. Theoretical composition and flow rate of the off-gas were calculated based on chemical composition of resin and it＇s burning condition inside CCM. The calculated off-gas flow rate was 67.9Nm$^3$/h at the burning rate of 40kg/h. And the composition of off-gas was avaluated as $CO_2$(41.4%), steam(40.0%), $O_2$(13.3%), NO(3.6%), and SO$_2$(1.6%) in order. Then, actual flow rate and composition of off-gas were measured during pilot-scale demonstration tests and the results were compared with theoretical values. The actual flow rate of off-gas was about 1.6 times higher than theoretical one. The difference between theoretical and actual flow rates was caused by the in-leakage of air to the system, and the in-leakage rate was evaluated as 36.3Nm$^3$/h. Because of continuous change in the combustion parameters inside CCM, during demonstration tests, the concentration of toxic gases showed wide fluctuation. However, the concentration of CO, a barometer of incompleteness of combustion inside CCM, was stabilized soon. The result showed quasi-equilibrium state was achieved two hours after feeding of resin.

• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.1
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• pp.80-89
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• 1998

The residual gas in an spark-ignition engine is one of important factors on emissions and performance such as combustion stability. With high residual gas fractions, flame speed and maximum combustion temperature are decreased and these are deeply related with combustion stability especially at idle and NOx emission at relatively high engine load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating load. Therefore, there is a need to characterize the residual gas fraction as a function of the engine operating parameters. In the present study, the quantitative measurement technique of residual gas fraction was studied by using Fast Response Flame Ionization Detector(FRFID). The measuring technique and model for estimation of residual gas fraction were reported in this paper. By the assuming that the raw signal from FRFID saturates with the same slope for firing and misfiring cycle, in-cylinder hydrocarbon(HC) concentration can be estimated. Residual gas fraction can be obtained from the in-cylinder HC concentration measured at firing and motoring condition. The developed measurement and calibration procedure were applied to the limited engine operating and design condition such as intake manifold pressure and valve overlap. The results show relevant trends by comparing those from previous studies.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.2
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• pp.1-8
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• 2004

A cylindrical constant volume combustion chamber was used to investigate the exhaust emission characteristics of homogeneous charge, stratified pattern and inhomogeneous charge under various conditions using gas chromatography. In the case of homogeneous charge condition, the $CO_2$ concentration is proportional to excess air ratio and overall charge pressure, the $CO_2$ concentration is proportional to excess air ratio and the UHC concentration is inversely proportional to ignition time and overall charge pressure. In the case of stratified pattern, the RI(rich injection) condition shows better exhaust emission characteristics, especially $CO_2$, than that of HI (homogeneous injection) or LI (lean injection) conditions. In inhomogeneous charge conditions, when initial charge pressure is increased, $CO_2$ and UHC concentration is reduced but $O_2$ concentration is increased. And when the excess air ratio of initial charge mixture is 3.0, UHC and $CO_2$concentration show lowest values.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.1
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• pp.15-26
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• 1997

The present study is mainly motivated to numerically simulate the autoignition and combustion process of a diesel spray in RCM and effects of design parameters on combustion and engine performance in the DI diesel engine using EGR. In case of the burning spray in RCM, special emphasis is given to the autoignition process coupled with the fluid mechanics and chemical reaction. Computations are carried out for a wide range of operating condition in terms of temperature, concentration of oxygen and carbon dioxide of the intake gas in the DI diesel engine. Numerical results indicate that the mixing process along the edges of spray jet has a crucial role for autoignition and combustion process. Temperature and concentration of O2 and CO2 of intake gas significantly influence the combustion characteristics and engine performance in the diesel/EGR environment.

• Journal of the Korean Society of Combustion
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• v.7 no.2
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• pp.34-41
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• 2002

To investigate the combustion characteristics of a swirling diffusion gas burner with oxygen enrichment, mean temperature, CO, $CO_2$, and HC concentrations were measured at various oxygen enrichment conditions. According to the results, the flame temperature increased and the region of high temperature was expanded with increasing oxygen concentration. The $CO_2$ concentrations increased, while the CO concentrations decreased in proportion to the increase of oxygen concentration. On the other hand, the HC concentrations were decreased and this tendency was very strong at the downstream of the combustor.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.6
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• pp.774-779
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• 2012

MILD (Moderate and Intense Low Oxygen Dilution) combustion is a technology that uses the recirculation of combustion gas to increase thermal efficiency not only by keeping down the concentration of Nitric Oxides and temperature but also by uniformizing the internal temperature of the combustion furnace. This study is a trial to obtain MILD combustion characteristics by adjusting the equivalence ratio with the air flow rate in the conical combustor while keeping the fuel flow rate and measuring the exhaust gas of the combustion furnace.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2868-2873
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• 2008

Carbon Monoxide(CO) poisoning accident is higher than any other gas accident in the rate of deaths/incidents. In the last five years, 36 people died and 104 were wounded because of carbon monoxide poisoning accident. Most of these CO poisoning accidents were caused by defective exhaust tube in the old gas boiler and multi-use facility. In this study, the spread of incomplete combustion gas(CO) released from leakage hole of exhaust tube was analyzed by computational flow modeling and concentration measuring test. CO gas leaked form exhaust tube in a building was highest concentrated near the ceiling and formed the circular currents along the walls. Through these experiments and simulation, the reasonable installation location of carbon monoxide alarm was made certain and suggested.

• Journal of the Korean Society of Combustion
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• v.10 no.1
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• pp.1-6
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• 2005

This paper presents the combustion characteristics of hydrocarbon fuel from a conventional pressure-swirl nozzle of a small-scale burner. The nozzle has orifice diameters of 0.256 mm and liquid flow rates ranging from 50 to 64 mL/min were selected for the experiments. The furnace temperature distribution along the axial distance, the gas emission such as CO, $CO_2$, NOx, $SO_2$, flue gas temperature, and combustion efficiency were studied. The local furnace and flue gas temperatures decreased with an increase in air velocity. At injection pressures of 1.1 and 1.3 MPa the maximum furnace temperatures occurred closer to the burner exit, at an axial distance of 242 mm from the diffuser tip. The CO and $CO_2$concentrations decreased with an increase in air velocity, but they increased with an increase in injection pressure. The effect of air velocity on NOx was not clearly seen at low injection pressures, but at injection pressure of 1.3 MPa it decreased with an increase in air velocity. The effect of air velocity on $SO_2$ concentration level is not well understood. The combustion efficiency decreased with an increase in air velocity but it increased with an increase in injection pressure. It is recommended that injection pressure less than 0.9 MPa with air velocity not above 8.0 m/s would be suitable for this burner.

• Applied Chemistry for Engineering
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• v.23 no.3
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• pp.333-338
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• 2012

To verify the utilization of fluff refuse derived fuel (RDF) as energy source, the combustion charateristic has been studied by an experimental combustion furnace under various temperatures. The characteristics of flue gas, dust and residue from fluff RDF combustion has been analyzed and compared with those of pelletized RDF. From this work, it was found that the incomplete combustion of fluff RDF was greater than that of pelletized RDF because the combustion reaction rate of fluff RDF was faster than that of pelletized RDF, and oxgen concentration in fluff RDF combustion decreased rapidly. It was also found that carbon monoxide concentration of flue gas from fluff RDF combustion increased with combustion temperature because the oxygen consumption and the incomplete combustion increased. Therefore, it is felt that the combustion operation conditions of fluff RDF should be carefully determined.