• 제목/요약/키워드: Concentration of Solution

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황산철 도금액 중 Si 입자의 공석 특성 (Co-deposition of Si Particles During Electrodeposition of Fe in Sulfate Solution)

  • 문성모;이상열;이규환;장도연
    • 한국표면공학회지
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    • 제37권6호
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    • pp.319-325
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    • 2004
  • Fe thin films containing Si particles were prepared on metallic substrates by electrodeposition method in sulfate solutions and the content of codeposited Si particles in the films was investigated as a function of applied current density, the content of Si particels in the solution, solution pH, solution temperature and concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film was not dependent on the applied current density, solution pH and solution temperature, while it was dependent on the content of Si particles in the solution and the concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film increased with increasing content of Si particles in the solution but reached a maximum value of about 6 wt% when the content of Si particles in the solution exceeds 100 g/l. On the other hand, the content of Si codeposited in the film increased up to about 17 wt% with decreasing concentration of $FeSO_4$$7H_2$O in the solution. These results would be applied to the fabrication of very thin Fe-6.5 wt% Si sheets for electrical applications.

기포 펌프를 적용한 흡수식 열펌프용 고온 재생기의 작동 특성 실험 (Experiments on a Regenerator with Thermosyphon for Absorption Heat Pumps)

  • 박찬우;정종수;남평우
    • 설비공학논문집
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    • 제8권4호
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    • pp.463-472
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    • 1996
  • Experiments were carried out to study the operation characteristics of a regenerator with a thermo-syphon pump and a surface-flame burner for a lithium bromide (LiBr)-water absorption heat pump. A cylindrical-shape metal-fiber burner and commercial grade propane were used. The emission of carbon monoxide and nitric oxide was measured by a combustion gas analyzer. Ther regeneration rate of water vapor as a refrigerant was measured. It could be as a reference value showing the performance of the regenerator. The circulation rate of the LiBr-water solution was also measured from both the tanks for the weak-and the strong-solution. Using a refractometer, the LiBr concetration in the solution was calculated from the measured refractory index of the solution. Temperature of the solution and the condensed water was recorded at several points in the experimental apparatus with thermocouples, using a personal computer. This data collecting system for measuring temperature was calibrated with a set of standard thermometers. The generating rate of water vapor as refrigerant increased linearly with heat supplied. It was about 4.0g/s with the heat supplied at a rate of 16,500kcal/h. The circulation rate of LiBr solution also increases with the heat supplied. The difference in LiBr concentrations between the weak and the strong solution was in the range of 1 to 5% when the concentration of the strong solution was about 60%. It was dependent upon both the heat supplied and the circulation rate of the solution. The initial concentration and the level of the LiBr solution in the regenerator were measured and recorded before experiments. The effect of them on the generating rate of water vapor and the circulation rate of the solution was also studied. The generating rate of water vapor was not strongly dependent upon both the level of the LiBr solution and the initial LiBr concentration. However, the concentration difference of the solution increases with the initial level of the LiBr solution.

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금속 은으로 제조한 Ag+ 용액의 항균효과와 안정성 (Antibacterial Activity and the Stability of an Ag+ Solution made using metallic Silver)

  • 강환열;정명주;정영기
    • KSBB Journal
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    • 제15권5호
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    • pp.521-524
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    • 2000
  • An Ag+ solution was made by supplying pure metal silver in filtrated distilled at constant voltage. the solution at an Ag+ concentration of 10 ppm showed specific activity against Gram positive and negative bacteria, and more than 90% activity against Candida albicans ATCC 102321 at the same concentration. The ionic solution produced was stable with regard to antibacterial activity and an Ag+ Concentration in the temperature range of 4$^{\circ}C$∼37$^{\circ}C$ for more than 4 weeks. In addition, the no pH change was observed under there conditions and the solution was confirmed stable by adjusting pH from 5.5 to 6.5.

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음/비이온계 혼합계면활성제 용액에서 $\alpha-Fe_2O_3$ 입자의 분산안정성 (The Dispersion Stability of $\alpha-Fe_2O_3$ Particulate Soil in the Anionic/Nonionic Mixed Surfactant Solution)

  • 정선영;강인숙
    • 한국의류학회지
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    • 제28권6호
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    • pp.854-861
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    • 2004
  • To estimate dispersion stability of particles in anionic and nonionic surfactant mixed solution, suspending power was examined as functions of duration time of suspension, ionic and nonionic surfactant mixed ratio, surfactant concentration, kinds of electrolyte, ionic strength and mole numbers of oxyethylene additions to nonionic surfactant using $\alpha$-Fe$_2$O$_3$ particle as the model of particulate soil. The suspending power of anionic and nonionic surfactant mixed solution was relatively higher than that of anionic and nonionic surfactant single solution regardless of solution concentration. The suspending power was gradually decreased with increasing duration time of suspension. In the absence of electrolyte, the effect of surfactant concentration on suspending power was small but in solution with electrolyte, suspending power was lowest at 1 % surfactant concentration. With 1${\times}$10$^{-3}$ ionic strength and polyanionic electrolyte in solution, the suspending power was high but effects of oxyethylene mole number to nonionic surfactant on suspending power was small. Generally the suspending power was gradually increased with decreasing the particle size. Hence the suspending power was inversely related to the particle size.

용접형 판형 열교환기의 열전달 및 압력강하 특성에 관한 실험적 연구 (Experimental study of Heat Transfer and Pressure Drop Characteristics for the Welded Plate Heat Exchanger)

  • 정종윤;김성수;강용태
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 하계학술발표대회 논문집
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    • pp.419-424
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    • 2008
  • Heat transfer and pressure drop characteristics of welded plate heat exchanger are studied to apply it for the solution heat exchanger of 210RT absorption system. This study quantifies the effect of mass flow rate and strong solution concentration on the heat transfer coefficient and pressure drop in the plate heat exchanger. The concentration of weak solution is fixed at 55% and the strong solution varies 55%, 57%, and 59% in mass. The results show that the overall heat transfer coefficient and pressure drop increase linearly with increasing Reynolds number. It is also found that the heat transfer coefficient of hot side increases with increasing the concentration of strong solution while the strong solution concentration has no effect on heat transfer coefficient of cold side.

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헬리컬 흡수기의 열ㆍ물질전달 특성에 관한 실험적 연구 (An Experimental Study on Beat and Mass Transfer Characteristics of Helical Absorber)

  • 권오경;윤재호;윤정인
    • 대한기계학회논문집B
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    • 제28권1호
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    • pp.81-88
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    • 2004
  • In this study, heat and mass transfer characteristics of five components solution (LiBr+Lil+LiNO$_3$+LiCl+$H_2O$) which could be substituted for commonly used LiBr solution are tested using a helical absorber. The arrangement of helical-typed heat exchangers allows to make the system more compact as compared to conventional one. The effects of experimental parameters, such as the solution flow rate, cooling water, solution temperature, solution concentration and surfactant have been investigated in view of the heat and mass transfer. The results of the experiment of heat and mass transfer performance show that five components solution should have 2% higher concentration fur equal absorption capacity of LiBr solution. But considering that five components solution have higher solubility than LiBr solution about 4% high concentration, five components solution could be applied to a small sized water cooled or air cooled absorption chiller/heater. The increase of heat and mass transfer coefficient by surfactant addition is about 25∼30% and 23∼40% respectively.

Effect of the Concentration of Cobalt Chloride Solution for the Preparation of Nano-Sized Cobalt Oxide Powder by Spray Pyrolysis Process

  • Yu, Jae Keun;Cha, Kwang Yong;Seo, Dong Jun;Han, Joung Su;Jang, Jae Bum;Lee, Yong Hwa;Kim, Dong Hee
    • 한국재료학회지
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    • 제24권6호
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    • pp.277-284
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    • 2014
  • Using the spray pyrolysis process, nano-sized cobalt oxide powder with average particle size below 50 nm was prepared from cobalt chloride solution. The influences of the raw material solution on the properties of the powder formed examined. When the concentration of Co was low(20 g/L), the average particle size of the powder formed was roughly 20 nm, and the cohesion between these particles was significantly strong. When the concentration of Co increased to 100 g/L, the droplets nearly failed to exist in circular form and reflected a severely divided form. Furthermore, the average size of the particles formed was roughly 40 nm, and the particles reflected a polygonal form. When the solution was increased to nearly saturation level (Co at 200 g/L), the particle size distribution reflected significant unevenness due to severe droplet division while the surface also reflected significant unevenness. Furthermore, the average size of the particles formed increased significantly to 70 nm. The results of XRD analysis showed that the strength of the peaks reflected very little change when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration was increased to 100 g/L, the strength of the peaks increased compared to when the concentration was 50 g/L. However, when the concentration was increased to 200 g/L, the strength of the peaks failed to reflect significant change compared to when the concentration was 100 g/L. The specific surface area dramatically decreased by 30 % when the concentration of Co was increased from 20 g/L to 50 g/L. Alternatively, when the concentration of Co the solution increased to 100 g/L, the specific surface area decreased by roughly 15 %. Furthermore, when the concentration of Co was increased to nearly saturation level(200 g/L), the specific surface area decreased by roughly 35%.

구리⋅알킬암모늄화합물계 목재방부제 (ACQ) 유효성분의 목재 흡착 특성 (Adsorption Characteristics of Alkaline Copper Quat Preservative Components in Wood)

  • 이종신;최광식
    • Journal of the Korean Wood Science and Technology
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    • 제42권4호
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    • pp.491-498
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    • 2014
  • ACQ 목재 방부처리 현장에서 약액의 농도관리에 필요한 기초 자료를 얻기 위하여 ACQ 약액을 회수하여 재사용하는 과정에서 일어나는 약액의 농도 변화, 처리 목재의 약제 흡수량 그리고 Cu (CuO로써)와 DDAC의 유효성분 비율변화 등을 조사하였다. 목재 수종은 낙엽송, 미송, 라디에타소나무를 사용하여 조사하였다. ACQ 약액을 회수하여 재사용하는 과정에서 재사용 횟수가 증가함에 따라 약액의 농도는 감소하였으며, 농도 감소경향은 유효성분의 종류별로 다르게 나타나 Cu보다는 DDAC의 농도 감소가 크게 나타났다. Cu의 농도감소는 처리 수종에 크게 영향을 받지 않았으나, DDAC의 경우에는 약액 흡수가 많은 수종에서 농도 감소의 폭이 크게 나타났다. 약액의 재사용 횟수에 관계없이 Cu의 목재 흡수량은 일정한 수준을 유지하였으나 DDAC 흡수량은 재사용 횟수의 증가와 함께 지속적으로 감소하였다. 약액의 재사용 횟수의 증가로 DDAC 농도가 감소하면 Cu의 흡수량이 증가하였으며, 이것은 처리 목재 내 흡착반응 과정에서 경쟁 관계에 있는 DDAC의 양이 감소함에 따라 상대적으로 Cu의 흡착량이 많아지기 때문인 것으로 판단하였다.

Sunset Yellow 액정 색소를 이용한 광학적 이방성 필름 제조 (Preparation of Optically Anisotropic Film by Sunset Yellow Chromonic Liquid Crystal)

  • 김병철;장유진;신승한
    • 공업화학
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    • 제22권1호
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    • pp.81-86
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    • 2011
  • 자기 조립성 염료인 Sunset Yellow-FCF 수용액은 상온에서 농도 25 wt%부터 schlieren 구조의 액정상을 보이기 시작하여, 28 wt% 이상이면 완전한 네마틱 액정상으로 관찰되었다. 전단배향에 의한 코팅으로 광학적 이방성 필름을 제조하기 위해서는 30 wt% 이상의 농도가 필요하였다. 액정 색소의 농도, 코팅속도, 건조 온도, 상대습도 등 코팅 변수가 최종 박막필름의 두께, 투과도에 미치는 영향 분석에 의하면, 최종 필름의 두께에는 용액의 농도가 가장 큰 영향을 주었으며, 평행방향의 투과도에는 건조 온도와 농도의 영향이 가장 컸다. 특히 Sunset Yellow-FCF의 농도 증가로 전단코팅에 의한 배향성이 개선되고 높은 편광도를 갖는 필름제조가 가능하였다. 본 실험에서는 33 wt%의 Sunset Yellow-FCF 수용액을 사용하면, 89.7~98.7%의 편광도를 갖는 광학적 이방성 필름이 제조되었다.

염분이 모래와 벤토나이트 혼합토의 응력 변형에 미치는 영향 (Effect of Sodium Chloride on Stress-Deformation of Sand Bentonite Mixture)

  • 안태봉
    • 한국지반공학회지:지반
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    • 제13권2호
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    • pp.17-28
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    • 1997
  • 이 연구에서는 화학액으로서 해안가에서 쉽게 영향 받는 염분을 사용하였다. 염분 용액으로 포화된 모래 벤토나이트 혼합토를 사용하여 압밀 비배수 삼축압축 시험을 실시하였다. 변형과 강도정수를 삼축압축시험을 통하여 구속응력과 염수의 농도 변화에 따라 구하였다. 실험 결과 영수로 포화된 흙과 벤토나이트의 점착력은 염수의 농도가 증가함에 따라 증가하며 내부마찰각은 변화가 없고 탄성계수는 증가하는 것으로 나타났다.

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