• Title/Summary/Keyword: Concentration of Solution

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On-line Measurement of $H_2$O/LiBr Concentration using Electric Conductivity (전기 전도도를 이용한 $H_2$O/LiBr 용액의 실시간 농도의 측정)

  • 박찬우;김정환;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.12
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    • pp.1078-1083
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    • 2002
  • The objectives of this paper are to measure the concentration of $H_2$O/LiBr solution by measuring the electrical conductivity and to study the effect of the solution temperature and the concentration on the electrical conductivity of the solution. The solution temperature ranges $20^{\circ},\;40^{\circ},\;and\; 60^{\circ}$ for a fixed concentration during the experiment. The valid ranges of the concentration are two regions, low concentration region (1~20% of LiBr) and high concentration region (55~66% of LiBr). The results show that the conductivity of the solution increases linearly with increasing the solution temperature while it increases without creasing the concentration lower than about 35% of LiBr and decreases with increasing the concentration higher than 35%. This paper proposes experimental correlations for the concentration as functions of the solution temperature and the concentration with error band of $\pm7$% for the low concentration region and $\pm1$% for the high concentration region, respectively. The experimental correlation can be practically used in the on-line measurement without any sampling of solution from the closed system.

Effect of Nitrogen Application Levels on Nitrate Concentration in Soil Solution under Plastic Film House

  • Lee, Chang Hoon;Kang, Seong Soo;Kim, Myung Sook;Kim, Yoo Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.1
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    • pp.30-35
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    • 2015
  • This study was conducted to investigate investigated the effect of nitrogen fertilizer on nitrate concentration in soil solution and to determine the relationship between yield and nitrate concentration in soil solution for cucumber cultivation under plastic film house. Nitrogen as urea was applied at rates of 0, 120, 240, 360, and $480kg\;N\;ha^{-1}$ as an additional fertilizer by trickle irrigation during cucumber cultivation. Monitoring of nitrate concentration in soil solution was investigated using porous cups at 25 cm depth under soil surface. Nitrate concentration in soil solution increased with increasing the rate of additional nitrogen. Correlation coefficient between EC value and nitrate concentration was positive in soil and soil solution (p<0.05). An additional nitrogen of about $300kg\;ha^{-1}$ was shown the highest yield of cucumber, and improved yield by 5% compared to N recommendation of $240kg\;N\;ha^{-1}$. The highest yield was determined at nitrate concentration of $82mg\;L^{-1}$ in soil solution by regression equation ($Y=74.2+0.73X+0.000504X^2$, $R^2=0.629^*$). These results means indicate that nitrate concentration in soil solution would be useful method to rapid determination for additional nitrogen during cucumber cultivation under plastic film house.

Manufacture of Ultra Fine CuO Powder from Waste Copper Chloride Solution by Spray Pyrolysis Process

  • Yu, Jae-Keun;Ahn, Zou-Sam;Sohn, Jin-Gun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.165-170
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    • 2001
  • The main purpose of this study is to generate a fine copper oxide powder of high purity, with a compact structure and a uniform particle size by a spray pyrolysis process. The raw material is a waste copper chloride solution formed in the manufacturing process of Print Circuit Board (PCB). This study also examines the influences of various factors on the properties of the generated powder. These factors include the reaction temperature, the inflow speed of the raw material solution, the inflow speed of the air, the size of the nozzle tip, and the concentration of the raw material solution. It is discovered that, as the reaction temperature increases from 80$0^{\circ}C$ to 100$0^{\circ}C$ , the particle size of the generated powder increases accordingly, and that the structure of the powder becomes much more compact. When the reaction temperature is 100$0^{\circ}C$, the particle size of the generated powder increases as the concentration of copper in the raw material solution increases to 40g/l, decreases as the concentration increases up to 120g/l, and increases again as the concentration reaches 200g/1. In the case of a lower concentration of the raw material solution, the generated powder appears largely in the form of CuO. As the concentration increases, however, the powder appears largely in the form of CuCl. When the concentration of copper in the raw material solution is 120g/1, the particle size of the generated powder increases as the inflow speed of the raw material solution increases. When the concentration of copper in the raw material solution is 120g/1, there is no evident change in the particle size of the generated powder as the size of the nozzle tip and the air pressure increases. When the concentration is 40g/1, however, the particle size keeps increasing until the air pressure increases to 0.5kg/$\textrm{cm}^2$, but decreases remarkably as the air pressure exceeds 0.5kg/$\textrm{cm}^2$.

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Application of eddy current technique for the non-contact sensing of low concentration of electrolytic solution

  • Ismail, Abu Bakar Md.;Shida, Katsunor
    • 제어로봇시스템학회:학술대회논문집
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    • 1997.10a
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    • pp.1310-1313
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    • 1997
  • Application of eddy current sensing principle for the non-contact estimation of very low concentration of electrolytic solution is presented in this paper. for this application, a new, simple, low-cost, low-power structure for the eddy current sensor is proposed. By measuring the eddy current produced in the conducting electrolytic solution, the concentration is estimated. Therefore, the unknown concentration can be estimated comparing with the database which is prepared as the relation between the change in inductance and various concentrations of electrolytic solution. The concentration, as low as l ppm of the solutioin can be detected by this sensor. It was tested on various low concentration solutions of NaCl. It shows distinct response for various concentrations.

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A STUDY ON THE CORROSION OF AMALGAMS IN CHLORIDE SOLUTION (Chloride용액에서의 아말감부식에 대한 연구)

  • Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.23 no.1
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    • pp.502-514
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    • 1998
  • The purpose of this study is to observe the corrosion characteristcs of four dental amalgams(CAULK FINE CUT, CAULK SPHERICAL, DISPERSALLOY, TYTIN) and to determine a function of chloride concentration through the anodic polarization curve obtained by using a potentiostat. After each amalgam alloy and Hg being triturated, the triturated mass was inserted into the cylinderical metal mold, and condensed by hydrolic pressure. Each specimen was removed from the metal mold. 24 hours after condensation, specimens were polished with the emery paper and stored at room temperature for 6 months. The anodic polarization curves were employed to compare the corrosion behaviours of the amalgam m KCl and KCl-NaCl solution, which had chlonde concentration of 0.4 g/l, 0.8 g/l, 1.2 gil, and 1.6 gil at $37^{\circ}C$ with 3-electrode potentiostat. After the immersion of specimen in electrolyte for 1 hour, the potential scan was begun. The potential scan range was - 1500mV ~+800mV(vs. S.C.E.) in the working electrode and the scan rate was 50mV/sec. The results were as follows, 1. The corrosion potential. the potential of anodic current peak, and transpassive potential in the solution of high chloride concentration shifted to more cathodic direction than those in the solution of low concentration, and the current density in the solution of high chloride concentration was higher than that in the solution of low concentration. 2. The corrosion potential, the potential of anodic current peak, and transpassive potential for CAULK FINE CUT amalgam were the most cathodic among the others, and the current density were the highest among the others. 3. In the solution of low chloride concentration, the corrosion potential, the potential of anodic current peak, and transpassive potential for DISPERSALLOY were the most anodic among the others, however in the solution of high chloride concentration, those for TYTIN were the most anodic among the others. 4. The anodic polarization curve for CAULK SPHERICAL was similar to that for high copper amalgams.

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Forward Osmosis Based Seawater Desalination using Liquid Fertilizer as Draw Solution (액상 비료를 유도 용액으로 사용하는 정삼투 기반의 해수 담수화)

  • Park, Seong-Jik;An, Hee-Kyung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.2
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    • pp.21-27
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    • 2013
  • The present study explored the way to desalinate seawater for agricultural irrigation using forward osmosis (FO) process using liquid fertilizer as draw solution. FO experiments were performed in a cross flow mode using flat sheet FO membrane. The effect of membrane orientation, flow rate, and draw solution concentration on the performance of forward osmosis was investigated by measuring water flux of forward osmosis membrane. The water flux when the draw solution was placed against the membrane active layer was lower than the water flux when the feed solution was placed against the membrane active layer. This results indicated that the decrease of effective osmotic pressure by dilutive internal concentration polarization was less than that by concentrative internal concentration polarization. Increasing flow rate from 66.7 to 133.1 $cm^3$/min resulted in increase of the water flux when the membrane active layer orient to draw solution and feed solution, respectively. The reduction of resistance to water flow increased water flux at higher flow rate. The water flux of FO membrane increased with increasing draw solution concentration from 10000 to 30000 mg/L. The water flux for $KH_2PO_4$ draw solution was similar to that for commercial fertilizer. Optimization of FO process would contribute to economically desalinate brackish water for agricultural use.

Effect of Several Zinc Solutions on Concentration of Oral Volatile Sulfur Compounds(VSCs) (수종의 Zinc 수용액이 구강내 휘발성 황화합물의 농도에 미치는 영향)

  • Park, Moon-Soo;Han, Song
    • Journal of Oral Medicine and Pain
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    • v.25 no.1
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    • pp.1-7
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    • 2000
  • The purpose of this study is to investigate effects of several zinc solutions including Artemisia asiatica-containing zinc solution on concentration of oral volatile sulfur compounds(VSCs). We determined the VSCs concentration of breath of human subjects before and after use of zinc solutions(O.25% $ZnF_2$ Artemisia asiatica-containing 0.25% $ZnCl_2$ and Artemisia asiatica-containing 0.25% $ZnCl_2$ solutions) The results were as follows : 1. 0.25% $ZnCl_2$ solution was more effective than 0.25% $ZnF_2$ solution in reducing the concentration of oral VSCs and the maintenance duration of effectiveness. 2. Artemisia asiatica-containing 0.25% $ZnCl_2$ solution was more effective than Artemisia asiatica-containing 0.25% $ZnF_2$ solution in reducing the concentration of oral VSCs and the maintenance duration of effectiveness. 3. Artemisia asiatica-containing 0.25% $ZnF_2$ solution and 0.25% $ZnF_2$ solution showed no significant difference in reducing the concentration of oral VSCs and the maintenance duration of effectiveness but, Artemisia asiatica-containing 0.25% $ZnF_2$ solution was slightly more effective. 4. Artemisia asiatica-containing 0.25% $ZnCl_2$ solution and 0.25% $ZnCl_2$ solution showed no significant difference in reducing the concentration of oral VSCs and the maintenance duration of effectiveness but, Artemisia asiatica-containing 0.25% $ZnF_2$ solution was slightly more effective.

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Determination of moisture threshold for solution sampling in different soil texture (토양용액 채취를 위한 토성별 한계수분함량 설정)

  • Lee, Chang Hoon;Kim, Myung Sook;Kong, Myung Seok;Kim, Yoo Hak;Oh, Taek-Keun;Kang, Seong Soo
    • Korean Journal of Agricultural Science
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    • v.41 no.4
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    • pp.399-404
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    • 2014
  • Soil moisture is an important factor for the availability and circulation of nutrients in arable soil. The purpose of this study was to set thresholds moisture content on soil nitrate concentration in the solution for real-time diagnosis. Sandy loam, silt loam, and sandy loam was filled with $1.2g\;cm^{-3}$ at Wagner pots, 0, 100, and $200mg\;L^{-1}$ of $KNO_3$ was saturated. Nitrate in standard solution was recovered about 95% by passing the porous cup. Nitrate concentrations in sampling of soil solution were examined by using a porous cup. The soil solution was higher in accordance with sandy loam> silt loam> clay loam, limited water filled pore space for sampling soil solution was 33.7, 56.4, and 62.2%, respectively. Nitrate concentration in the soil solution was negligible at sandy loam and silt loam during sampling periods, which was decreased about 50~82% in clay loam compared to the initial $NO_3$-N concentration in the saturated $KNO_3$ solution. Over limitation of soil solution sampling, soil EC and $NO_3$-N content were increased with the saturated $NO_3$-N concentration, regardless of soil texture (p<0.05). Conclusively, soil solution by using a porous cup was possible, regardless of the soil texture, which was useful for the diagnosis in nitrate concentration of soil solution. However, because nitrate concentration of soil solution in a clay loam changes, it was necessary for careful attention in order to take advantage for the real-time diagnosis of nitrogen management in soil.

Separation of Cd(II) from Aqueous Solutions by A New Consecutive Process Consisting of Supported Liquid Membrane and Electrodialysis

  • Altin, Sureyya;Altin, Ahmet
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.14-21
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    • 2019
  • Supported liquid membrane process usually is used for recovering or enrichment of valuable metals in the industrial wastewater. But, even if the metals in the wastewater was separated with high chemical selectivity, it cannot be enough concentrated since separation performance of supported liquid membrane (SLM) process is limited by concentration gradient between feed solution and stripping solution. If metal concentration in the stripping solution to be enough low, transport of metal through membrane can be accomplishment constantly. Therefore, Electrodialysis (ED) has been placed after SLM process and the stripping solution of SLM was used as the feed solution for the ED process. Transport of ions in the solutions is successfully performed by ED process. Thus, the metal concentration in the stripping solution does not rise as to stop ion transport. Besides, valuable metals easily are concentrated by ED process for re-use. In this study, effects of operation parameters like initial Cd(II) concentration, HCl concentration in the feed solution of SLM and applied voltage are investigated on separation efficiency, flux and permeability of the both processes. As the feed solution concentration increased, all performance values has increased. When initial concentration of 100 mg/L is used, separation performances (SP) are 55% and 70%, for SLM and consecutive process, respectively. The best HCl concentration in the feed solution of SLM has determined as 2 M, in this conditions SP are 64% and 72%, for SLM and consecutive process, respectively. With increased of applied voltage on ED process, SP of the consecutive process has been raised from 72% to 83%. According to the obtained experimental data, consecutive process has better separation performance than SLM. When the separation performances of both processes were compared for the same operating conditions, it was determined higher the separation efficiency, permeability and flux values of the consecutive process, 8%, 9% and %10.6, respectively. Consequently, the use of the consecutive process increases the performance efficiency of both processes. The consecutive process studied has quite a good chemical separation efficiency, and enrichment capability. Moreover, this process requires few water and energy.

Effect of Ca and BSA on Hydrogen Ion Concentration in Bovine Sperm Washed Solution (Ca과 BSA가 소 정자세척액내 수소이온농도에 미치는 영향)

  • 박영식;임경순
    • Korean Journal of Animal Reproduction
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    • v.15 no.3
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    • pp.201-205
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    • 1991
  • This study was carried out to investigate the effects of Ca and BSA on hydrogen ion concentration in sperm washed solution. The results obtained were as follows : 1. The hydrogen concentration in 1st and 2nd sperm washed solutions was signifcinatly(p<0.01) higher when sperm was washed with SHPsolution containing 2mM Ca than when sperm washed with SHP solution or SHP solution containing 10mM Ca. 2. The hydrogen ion concentration in sperm washed solution was significnatly(p<0.05) higher when seprm was washed with SHP solution containing BSA-FAF than when sperm was washed with SHP solution or SHP solution containing BSA-V.

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