• Applied Chemistry for Engineering
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• v.8 no.4
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• pp.694-699
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• 1997

Normal-phase HPLC was used to separate the useful phospholipids, PE, PI and PC in soybean lecithin. The mobile phase used in this experiments were haxane, isopropanol and methanol, the gradient mode was applied as the three components could not be separated by the isocratic mode. To find the optimum separation condition, the concentration profiles of effluents were calculated from the plate theory and the capacity factor in step-gradient mode. From the calculated results, PE was separated with hexane/isopropanol/methanol = 90/5/5vol.% in isocratic mode and PI and PC were resolved in the conditions of 10min gradient time and the second mobile phase of hexane/isopropanol/methanol=50/20/30vol.% in step-gradient mode. The agreement between the calculated concentration profile and experimental data was good, so the methodology developed in this work can be used to obtain the optimum separation condition in gradient mode.

• Solar Energy
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• v.6 no.2
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• pp.15-21
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• 1986

In this study, an experimental double diffusive thermohaline system heated from below was constructed and the phenomena of each layer developed in the system were observed. The experiment was performed with the initial salt concentration gradient of $-436.2kg/m^4$ and the net heat flux of approximately $176w/m^2$. An electroconductivity-temperature probe was made and used for the measurements of salt concentration. As the result of this study, it was found that the salt concentration decreased in the bottom mixed layer and increased in the top mixed layer during the experiment while the salt concentration gradient in the diffusive layer unchanged. It was also found that the interfacial boundary layers were due largely to variations in salt concentration rather than temperature.

• The Korean Journal of Physiology
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• v.28 no.2
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• pp.159-167
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• 1994

The contraction of rabbit basilar artery was examined as a function of changes in the $Na^+$ electrochemical gradient in order to determine the contribution of $Na^+/Ca^{2+}$ exchange to the modulation of contractility. Ouabain $(10^{-5}\;M)$ or $K^+-free$ Tyrode solution caused an increase in tonic tension even in the presence of a $Ca^{2+}$ channel blocker $(10^{-6}\;M\;verapamil)$ and an ${\alpha}-receptor$ blocker $(10^{-5}\;M\;phentolamine)$. After treatment with ouabain $(10^{-5}\;M)$, contractions were augmented by reduction of external $Na^+$ concentration. The longer the treatment with ouabain $(10^{-5}\;M)$ was, the larger the amplitude of $Na^+-free$ contracture was. $Na^+-free$ contracture wag induced by either substitution of equimolar Tris for $Na^+$ or substitution of equimolar $Li^+\;for\;Na^+$. The competition between $Na^+\;and\;Ca^{2+}$ for the $Na^+/Ca^{2+}$ exchange carrier would exist, because it was observed that contractility was dependent on the $Na^+$ electrochemical gradient or the extracellular $Ca^{2+}$ concentration (2 mM, 4 mM). Ryanodine $(10^{-7}\;M)$, the blocker of intracellular $Ca^{2+}$ release from the sarcoplasmic reticulum, did not suppress the development of $Na^+-free$ contracture. The contractile response to norepinephrine $(10^{-6}\;M)$ was augmented by reducing the extracellular $Na^+$ concentration. The relaxation rate from caffeine-induced contraction was dependent on the extracellular $Na^+$ concentration (0 mM, 140 mM). From the above results, it could be suggested that $Na^+/Ca^{2+}$ exchange can move $Ca^{2+}$ either into or out of rabbit basilar arterial smooth muscle. $Ca^{2+}$ entry or extrusion is dependent upon the $Na^+$ electrochemical gradient. $Na^+/Ca^{2+}$ exchange plays a significant role in the regulation of contractility in rabbit basilar arterial smooth muscle.

• Journal of Ocean Engineering and Technology
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• v.13 no.2 s.32
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• pp.129-137
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• 1999

The time of the onset of double-diffusive convection in time-dependent, nonlinear concentration fields is investigated theoretically. The initially quiescent horizontal fluid layer with a uniform temperature gradient experiences a sudden concentration change from below, but its stable thermal stratification affects concentration effects in such way to invoke convective motion. The related stability analysis, including Soret effect, is conducted on the basis of the propagation theory. Under the linear stability theory the concentration penetration depth is used as a length scaling factor, and the similarity transform for the linearized perturbation equations. The newlly obtained stability equations are solved numerically. The resulting critical time to mark the onset of regular cells are obtained as a function of the thermal Rayleigh number, the solute Rayleigh number, and the Soret effect coefficient. For a certain value of the Soret effect coefficient, the stable thermal gradient promote double-diffusive convective motion.

• 한국가시화정보학회:학술대회논문집
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• 2002.11a
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• pp.49-50
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• 2002

In micro-channels, the electro-viscous effect is caused by the electrical double layer on pressure-driven liquid flow. Velocity fields of flow inside micro-channels were measured using micro-PIV system for investigating the electro-viscous effect. De-ionized water and aqueous NaCl solutions with four different concentrations were used as working fluid in a PDMS micro-channel of $100{\mu}m$ width and $66{\mu}m$ height. The pressure gradient, dP/dx, was determined from the pre-determined input flow rate Q of syringe pump. The mean velocity $u_m$ used for calculating Reynolds number was obtained from the PIV velocity field data. These are used to plot the pressure gradient as a function of Reynolds numbers. The pressure gradient far lower concentration solution $(10^{-5}\;M)$ was higher than that for the higher concentration solution. The increase of flow resistance was about $30\%\;and\;37.5\%$ at Re=0.02 and 0.06, respectively.

• Journal of the Korean Applied Science and Technology
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• v.27 no.4
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• pp.545-551
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• 2010

Hydrophobically monoendcapped poly(sodium acrylate)s formed hydrophobic microdomains in water. This was concluded on poly(sodium acrylate)s with a linear $C_{12}$-alkyl chain attached specifically at the end of the polymer. There was no well defined CMC (critical micelle concentration), but rather a gradual transition from a micelle free solution to a micelle solution. Steady state fluorescence spectroscopy indicates that the micro domains are rather hydrophobic. At pH 5 in the abscence of salt and at pH 9 in the prescence of 1 M sodium citrate the CAC (critical aggregation concentration) was in the range of 0.1 to 2.4 mM. However at pH 5 there was a linear increase in the transition concentration with a head-group size due to an increase in steric and electrostatic repulsions between polymer main chains. At pH 9 in the abscence of salt the transition concentration was in the range of 1 to 80 mM. For the larger polymers there was a effect which consisted of a concentration gradient of sodium counterion toward the hydrophobic domain. The effect was larger for the larger polymers because of the higher total sodium concentration and the less steep counterion concentration gradient.

• Journal of Environmental Science International
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• v.14 no.6
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• pp.555-563
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• 2005

This study presents the characteristics of nocturnal inversion layer and their effect on the concentration variations of surface air pollutants using tethersonde and automatic weather station (AWS, 2 layer tower) system in Ulsan during 2003, The method for the distinction of inversion intensity was decided based on the sum of nocturnal temperature gradient. As the results, there was a close correlation (correlation coefficient of 0,76) between the maximum inversion height obtained from tethersonde and the sum of nocturnal temperature gradient. The air pollutant concentration was also directly proportional to the inversion intensity. When the inversion intensity was strong in the nighttime, ozone $(O_3)$ concentration was lower, while nitrogen dioxide $(NO_2)$ concentration was higher. The carbon monoxide (CO) concentration was gradually higher according to the nocturnal inversion intensity, whereas sulfur dioxide $(SO_2)$ concentration was relatively constant. In addition, we found that there was no correlation between the inversion intensity and TSP concentration.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.166-173
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• 2007

A numerical study was conducted to have the effect of $CO_2$ addition to fuel on the chemical reaction mechanism with the change of the initial concentration of $CO_2$ and the axial velocity gradient. From this study, it was found that there were two serious effects of $CO_2$ addition on a non-premixed flame ; a diluent effect by the reactive species reduction and chemical effect of the breakdown of $CO_2$ by the third-body collision and thermal dissociation. Especially, the chemical effect was serious at the lower velocity gradient of the axial flow. It was certain that the mole fraction profile of $CO_2$ was deflected and CO was increased with the initial concentration of $CO_2$. It was also ascertained that the breakdown of $CO_2$ would cause the increasing of CO mole fraction at the reaction region. It was also found that the addition of $CO_2$ did not alter the basic skeleton of $H_2-O_2$ reaction mechanism, but contributed to the formation and destruction of hydrocarbon products such as HCO. The conversion of CO was also suppressed and $CO_2$ played a role of a dilution in the reaction zone at the higher axial velocity gradient.

• Journal of the Korean Ceramic Society
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• v.34 no.10
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• pp.1015-1020
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• 1997

In the Nd;YAG crystal growth by Czochralski method, the relationship between the core formation and the solid-liquid interface was observed by controlling the temperature gradient in the furnace. When the crystal was grown along<111> direction, defects and core area were reduced as the temperature gradient increased. The optimum temperature gradient was found to be higher than 4$0^{\circ}C$/cm. The Nd3+ concentration analysis by ICP-Mass showed that the segregation coefficient was about 20% higher in the core region than core-free region, where the segregation coefficients of core region and core-free region were 0.22 and 0.18, respectively.

• Membrane Journal
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• v.12 no.2
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• pp.90-96
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• 2002

A novel methodology on the calculations of osmotic pressure and gradient diffusion coefficient has been provided ill the present study, by applying a succinct numerical analysis on the experimental results. Although both the osmotic pressure and the gradient diffusion coefficient represent a fundamental characteristic in related membrane filtrations such as microfiltration and ultrafiltration, neither theoretical analysis nor experiments can readily determine them. The osmotic pressure of colloidal suspension has been successfully determined from a relationship between the data of the time-dependent permeate flux, their numerical accumulations, and their numerical derivatives. It is obvious that the osmotic pressure is gradually increased, as the particle concentration increases. The thermodynamic coefficient was calculated from the numerical differentiation of the correlation equation of osmotic pressure, and the hydrodynamic coefficient was evaluated from the previously developed relation for an ordered system. Finally, the estimated gradient diffusion coefficient, which entirely depends on the particle concentration, was compared to the previous results obtained from the statistical mechanical simulations.