• Korean Journal of Materials Research
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• v.32 no.4
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• pp.230-236
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• 2022

The formation behavior of a passive state film on the surface of STS304 in electrolytic solution was analyzed to determine its metallic ion composition. The properties of passive state films vary depending on the Fe and Cr ions in the electrolytic solution. It was observed that the passive state film surface became flat and glossy as the concentration of Fe and Cr ions in the electrolytic solution increased. The corrosion resistance property of the passive state film was proportional to the amount of Fe and Cr in the electrolytic solution. An initial passive state film with high Fe concentration was formed on the surface of STS304 during early electrolytic polishing. Osmotic pressure of Fe ions occurs between the passive state film and electrolytic solution due to the Fe ion concentration gradient. The Fe in the passive state film is dissolved into the electrolyte, and Cr fills up the Fe ion vacancies. As a result, a good corrosion-resistant floating film was formed. The more Fe ions in the electrolytic solution, the faster the film is formed, and as a result, a flat passive state film containing a large amount of Cr can be formed.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.2C
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• pp.99-108
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• 2006

In this study a series of bench scale test are conducted to increase the undrained shear strength of clayey soils using by Electro-kinetic injection stabilization method. The sodium silicate was injected in anode reservoir and its concentration was changed with 500, 1000, 1500, 2000, 2500mM for configuration of applicability of Electro-kinetic injection stabilization method. Also, the treatment time and electric gradient was changed to acquire the optical influence factors. For increasing the shear strength to maximum values, the calcium chloride and aluminium hydroxide, which concentration was changed with 50, 250, 500, 750, 1000mM, were added at anode reservoir for 5 days after the treatment of sodium silicate in 5 days as the 2nd additives. The test of results in determination of sodium silicate concentration show that the undrained shear strength at each point had a tendency to converge into a constant value when the concentration of sodium silicate came to 1000mM and above. The maximum shear strength increasement was 800% compared with initial value. After a series of test, the electric gradient and treatment time for application of electric fielld were 1V/cm and 6 days. In case of 2nd additives test, the concentration for maximum shear strength is 250mM in all additives and the effects of shear strength improvement was developed approximately 20~30% in comparison to addition of single injection material.

• Journal of Electrochemical Science and Technology
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• v.10 no.1
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• pp.14-21
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• 2019

Supported liquid membrane process usually is used for recovering or enrichment of valuable metals in the industrial wastewater. But, even if the metals in the wastewater was separated with high chemical selectivity, it cannot be enough concentrated since separation performance of supported liquid membrane (SLM) process is limited by concentration gradient between feed solution and stripping solution. If metal concentration in the stripping solution to be enough low, transport of metal through membrane can be accomplishment constantly. Therefore, Electrodialysis (ED) has been placed after SLM process and the stripping solution of SLM was used as the feed solution for the ED process. Transport of ions in the solutions is successfully performed by ED process. Thus, the metal concentration in the stripping solution does not rise as to stop ion transport. Besides, valuable metals easily are concentrated by ED process for re-use. In this study, effects of operation parameters like initial Cd(II) concentration, HCl concentration in the feed solution of SLM and applied voltage are investigated on separation efficiency, flux and permeability of the both processes. As the feed solution concentration increased, all performance values has increased. When initial concentration of 100 mg/L is used, separation performances (SP) are 55% and 70%, for SLM and consecutive process, respectively. The best HCl concentration in the feed solution of SLM has determined as 2 M, in this conditions SP are 64% and 72%, for SLM and consecutive process, respectively. With increased of applied voltage on ED process, SP of the consecutive process has been raised from 72% to 83%. According to the obtained experimental data, consecutive process has better separation performance than SLM. When the separation performances of both processes were compared for the same operating conditions, it was determined higher the separation efficiency, permeability and flux values of the consecutive process, 8%, 9% and %10.6, respectively. Consequently, the use of the consecutive process increases the performance efficiency of both processes. The consecutive process studied has quite a good chemical separation efficiency, and enrichment capability. Moreover, this process requires few water and energy.

• International conference on construction engineering and project management
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• 2020.12a
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• pp.463-481
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• 2020

Cutter suction dredgers (CSDs) are widely used in various dredging constructions such as channel excavation, wharf construction, and reef construction. During a CSD construction, the main operation is to control the swing speed of cutter to keep the slurry concentration in a proper range. However, the slurry concentration cannot be monitored in real-time, i.e., there is a "time-lag effect" in the log of slurry concentration, making it difficult for operators to make the optimal decision on controlling. Concerning this issue, a solution scheme that using real-time monitored indicators to predict current slurry concentration is proposed in this research. The characteristics of the CSD monitoring data are first studied, and a set of preprocessing methods are presented. Then we put forward the concept of "index class" to select the important indices. Finally, an ensemble learning algorithm is set up to fit the relationship between the slurry concentration and the indices of the index classes. In the experiment, log data over seven days of a practical dredging construction is collected. For comparison, the Deep Neural Network (DNN), Long Short Time Memory (LSTM), Support Vector Machine (SVM), Random Forest (RF), Gradient Boosting Decision Tree (GBDT), and the Bayesian Ridge algorithm are tried. The results show that our method has the best performance with an R² of 0.886 and a mean square error (MSE) of 5.538. This research provides an effective way for real-time predicting the slurry concentration of CSDs and can help to improve the stationarity and production efficiency of dredging construction.

• Geotechnical Engineering
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• v.11 no.3
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• pp.37-42
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• 1995

The laboratory hydraulic conducti vita tests with rigid wall permeameter were performed to study the effects of waste leachate on the permeability of a marine clay. The marine clay and waste leachate for this study were sampled from Kimpo Wastefills, and the hydraulic gradients applied to the clay specimens aTe relatively high from 37.5 to 225. The test results show that the permeability of a marine clay is increased with increasing the concentration of leachate and with decreasing the hydraulic gradient. And also both the liquid limit and the plasticity index of the marine clay miRed with waste leachate decrease with increasing the concentration of leachate.

• Composites Research
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• v.15 no.4
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• pp.32-36
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• 2002

Recently, the applications of composite materials become broader to civil engineering as well as mechanics and aerospace engineering. Cracks on the civil structures like bridges can cause stress concentration, which induces Peak splitting of fiber Bragg grating sensor and it makes strain measurements difficult. In this study, 4-point bending test of concrete beam with initial crack reinforced by composite patch was conducted in order to verify the effects of the stress concentration on the peak signal of FBG sensor and a novel method for signal maintenance.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 1999.05a
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• pp.385-388
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• 1999

A new local model for impact ionization coefficients is proposed to account for a non-local effect. New model uses an effective electric field which comes from the path integral of a tangent electric field at an arbitrary point. The model consists of local variables, such as doping concentration, carrier concentration and gradient of the field, and can be easily applied to a conventional drift-diffusion device simulator. By comparing the results with Monte Carlo simulation, it is confirmed that new model explains the non-local effect fairly well.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.51-54
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• 2001

This research was carried out to evaluate feasibility of using an Electrokinetic-Fenton(EK-Fenton) technique to treat hydrophobic organic pollutant(phenanthrene) from soils. Experiment examined the effect by introducing a continuous flow of a 3.5% hydrogen peroxide solution at the anode. An electric gradient of 1V/cm was applied to enhance the saturated flow in the soil cell for a period of 11 days. After 11 days or 1 pore volume, overall concentration of residual phenanthrene in the soil cell was 11% and residual phenanathrene concentration in the soil was found to increase with toward the cathode. This results indicated that Fenton-like reaction catalyzed by mineral surface was effective in oxidizing phenanthrene. This results also showed that hydrogen peroxide was effectively transported into the soil by electroosmotic flow as well as by diffusion.

• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.873-881
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• 2004

A serious of EK remediation tests on contaminated soil are performed under unsaturated conditions and analyzed for electrical potential, water content, pH and so on. The results indicated that electrical potential and pH distributions in the sample are dependent on the amount and inward/outward flow of hydrogen ion. Specially, for the closed system the water content is largely decreased with the flow of hydrogen. The maximum electrical conductivity is measured at the catholyte of CEM(Sealing) test and directly related to the remedial efficiency. Although pHs in the region near to the anode are similarly developed, the different concentration of lead is measured with the electrical gradient contrary to the lead concentration dependent on pH within the sample.

• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.890-896
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• 2004

This study is intended as an investigation of the EK remediation characteristics of natural soil with treatment time under unsaturated conditions. EK tests are performed under the voltage gradient of 1V/cm, the degree of saturation of 82.8%, and the installing of cation exchange membrane. It was found from the results that the acid front is initially transported at 0.75cm/day and then continuously degreased until the transport velocity of the acid front is balanced to the velocity of the base front. The residual lead concentration indicated the maximum value at the treatment time of lOdays, then the increasing of treatment time largely decreases the concentration within the sample though electromigration than electroosmosis.