• Title/Summary/Keyword: Concentrated Wastes

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Gravity, Magnetic and VLF explorations in the ubong industrial waste landfill, Pohang (포항 유봉산업 폐기물 매립지에서의 중력, 자력, VLF 탐사)

  • 권병두
    • Economic and Environmental Geology
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    • v.32 no.2
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    • pp.177-187
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    • 1999
  • Gravity, magnetic and VLF surveys were conducted to investigat the structural stability and hazards associated with the Ubong landfill in Pohang City, which has been built to dump industrial wastes. In 1994, the collapse of a bank happened in the 6th landfill site due to sudden heavy rain, and a large quantity of waste materials flowed out to the nearby landfill sites, factories and roads. We used $10{\times}10m$ resolution DEM data for gravity reductions. The maximum variation of the terrain effect in the survey area is about 0.5 mgal and the terrain effect is large in the vicinity of bank boundary. The Bouguer gravity anomaly map shows the effect due to the variatino of thickness and type of waste materials. The small negative gravity anomaly increases from the 9th site to the 6th site. The small negative gravity anomaly of the 9th site reflects the relatively shallow dumping depth of average 14.5 m in this site and increased density of waste materials by the repeated stabilization process of soil overlaying. The 6th site is located at the center of the former valley and rainfall and groundwater are expected to flow from south-east to north-west. Therefore, considering the previous accident of mixing waste and bank materials at the north-west boundary of the landfill, there may be some environmental problems of leakage of contaminated water and bank stability. The complex inversion technique using Simulated annealing and Marquardt-Levenberg methods was applied to calculate three-dimensional density distribution from gravity data. In the case of 6th site, it is apparent that the landfill had been dumped in four sectors. However, most part of the 9th site and showed that high magnetic industrial wastes were concentrated in the 6th site. The result of magnetic survey showing low magnetic anomalies along the boundaries of two sites is similar to that of gravity data. The VLF data also reveals four divided sectors in the 6th site, and overall anomaly trend indicates the directio of former valley.

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Increase of treatment amount of thermophilic oxic process considering calorie/water (C/W) ratio (칼로리/수분 (C/W)비를 고려한 고온호기 처리법에서의 처리량 증가)

  • Jeon, Kyoung-Ho;Choi, Dong-Yoon;Song, Jun-Ik;Park, Kyu-Hyun;Kwag, Jung-Hoon;Kim, Jae-Hwan;Kang, Hee-Sul
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.2
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    • pp.203-210
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    • 2010
  • The signification of calorie/water (C/W) ratio was investigated in the treatment of highly concentrated organic wastes by thermophilic oxic process (TOP). Swine waste was used in this study. When C/W ratio was 1.6, most of swine waste was decomposed and all water was evaporated in the 24-h injection cycle. To improve treatment efficiency of TOP treating swine waste, the effect of shortening the swine waste injection cycle was examined. The shortening of injection cycle was conducted to stimulate the activity of thermophilic bacteria. A high temperature in the reactor was maintained by shortening of the injection cycle. When the swine waste injection cycle was shortened, the C/W ratio was fixed at 1.6. As a result, by shortening the swine waste injection cycle from 24-h to 12 and 6-h, the maximum loading rate of swine waste per day could be improved 1.9 and 3.5 times, respectively.

Rheology Characteristics of Cement Paste with Blast Furnace Slag Depending on CBS-Dust Contents (CBS-Dust 치환율에 따른 고로슬래그 미분말을 함유한 시멘트 페이스트의 레올로지특성)

  • Park, Byoung-Joo;Sin, Se-Jun;Lee, Dong-Joo;Kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.144-145
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    • 2020
  • Recently, the cement industry has been using various wastes as raw materials and fuel for cement as an eco-friendly business. However, most of these waste resources contain large amounts of chloride and alkali, which are concentrated in manufacturing facilities and adversely affect cement production products. Accordingly, in the cement production process, the chlorine ion contained in cement is managed by introducing the Chlorine Bypass System (CBS) into the manufacturing facility and releasing the dust. However, the processing volume of CBS-Dust has been limited due to the shortage of domestic processing companies, and the cost has also been raised, requiring measures to be taken in dealing with CBS-Dust. In this study, rheological properties of CBS-Dust incorporated paste are tested. With the increase of CBS-Dust, flow was decreased due to enhanced viscosity.

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Design of Pretreatment Process of Lead Frame Etching Wastes Using Reduction-Oxidation Method (환원-산화법을 이용한 리드프레임 에칭폐액의 정제과정 설계)

  • Lee, Seung Bum;Jeon, Gil Song;Jung, Rae Yoon;Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.21-25
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    • 2016
  • When copper alloy is used in etching process for the production of lead frame, the high concentration of heavy metals, such as iron, nickel and zinc may be included in the etching waste. Those etching waste is classified as a specified one. Therefore a customized design was designed for the purification process of the lead frame etching waste liquid containing high concentrations of heavy metals for the production of an electroplating copper(II) oxide. Since the lead frame etching waste solution contains highly concentrated heavy metal species, an ion exchange method is difficult to remove all heavy metals. In this study, a copper(I) chloride was manufactured by using water solubility difference related to the reduction-oxidation method followed by the reunion of copper(II) chloride using sodium sulfate as an oxidant. The hydrazine was chosen as a reducing agent. The optimum added amount was 1.4 mol per 1.0 mol of copper. In the case of removal of heavy metals by using the combination of reduction-oxidation and ion exchange resin methods, 4.3 ppm of $Fe^{3+}$, 2.4 ppm of $Ni^{2+}$ and 0.78 ppm of $Zn^{2+}$ can be reused as raw materials for electroplating copper(II) oxide when repeated three times.

Separation Technologies for the Removal of Nitrate-Nitrogen from Aqueous Solution (수용액으로부터 질산성질소 제거를 위한 기술)

  • Seo, Yang Gon;Jung, Se Yeong
    • Clean Technology
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    • v.23 no.1
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    • pp.1-14
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    • 2017
  • At high nitrate concentrations, water must be treated to meet regulated concentrations because it results in threat to human health and eutrophication of natural water. However, it is almost impossible to remove nitrate by conventional water treatment methods such as coagulation, filtration and precipitation, due to its high water solubility. Therefore, other technologies including adsorption, ion exchange, reverse osmosis, denitrification, and electrodialysis are required to effectively remove nitrate. Each of these technologies has their own strengths and drawbacks and their feasibility is weighted against factors such as cost, water quality improvement, residuals handling, and pre-treatment requirements. An adsorption technique is the most popular and common process because of its cost effectiveness, ease of operation, and simplicity of design. Surface modifications of adsorbents have been enhanced their adsorption of nitrate. The nitrate-selective membrane process of electrodialysis reversal and reverse osmosis have proven over time and at many locations to be highly effective in removing nitrate contaminating problems in aqueous solutions. Both electrodiaysis and reverse osmosis methods generate highly concentrated wastes and need careful consideration with respect to disposal.

Application Plan of Sludge Reduction and Improvement of Ananerobic Digestion Rate Using VFAs from Food Waste (증산제를 통한 혐기소화율 개선 및 슬러지 감량 활용방안)

  • Lee, Kawng Hun;Kim, Gil Su;Sun, Beong Keon;Choi, Chan Sup;Cho, Gin Woo;Shin, Jae Hoon;Jeong, Tae Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.3
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    • pp.47-54
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    • 2018
  • This study examined the improvement of anaerobic digestion rate and sludge reduction as a result of the addition of anaerobic digestion with thickened sludge and solution of VFAs obtained from food waste. The methane production rate of the digestion system was 2.21 times higher when anaerobic digestion reactor injected into anaerobes with VFAs from food wastes of 5 percent. Also, The reduction of the amount of concentrated sludge injected will proceed rapidly because of the TCOD concentration in the digestion reactor was more than twice higher. Indirectly it was shown that the increased production system contributed significantly to the methane production efficiency.

Fundamental Studies on the Calcium Precipitation for the Reuse of Wastewater Containing Phosphate (칼슘 침전처리에 의한 인산폐수 재사용에 관한 연구)

  • Kim Yaung-Im;Kim Dong-Su
    • Resources Recycling
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    • v.12 no.4
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    • pp.38-43
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    • 2003
  • Phosphate is an essential material for the growth of organisms. However. since relatively small amount is required. a large amount of phosphate is abandoned in wastes and wastewater. which contaminate the ecological environment including aquatic system. Purpose of this study is to treat especially high concentrated phosphate wastewater by use of calcium precipitation method. The pH range considered was from 6 to 12 and the maximum removal of phosphate was attained at pH 12. The con-centration of phosphate was observed to decrease rapidly until a half amount of calcium ion to its equivalent for the formation of calcium phosphate precipitate was added. which resulted in the decrease of the remaining concentration of phosphate down to 0.0027 mM. The effect of fluoride ion was examined and the concentration ratio between the phosphate and fluoride ion did not have any significant influence on the removal efficiency of phosphate. The effect of pH was also investigated. With the increasing of the pH in solution, the removal rate of phosphate was increased. Also it was investigated that the effect of fluoride on the phosphate removal was not significant.

Synthesis of $LiCoO_{2}$ Nanoparticles From Leach Liquor of Lithium Ion Battery Wastes by Flame Spray Pyrolysis

  • Lee Churl Kyoung;Chang Hankwon;Jang Hee Dong;Sohn Jeong-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.37-43
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    • 2005
  • [ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

The Status of Biogas as Renewable Energy (신재생에너지로서 바이오가스 현황)

  • Lim, Young-Kwan;Lee, Joung-Min;Jung, Choong-Sub
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.125-130
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    • 2012
  • In these days, there has been increased focus on global warming and the exhaustion of resources recently caused by the heavy consumption of fossil resources. In order to resolve these problems, biomass is increasingly gaining international attention as a renewable energy source. Biogas derived from various biomass is environmental friendly alternative fuel for power generation, heating and vehicle fuel. Large amounts of sewage sludge, food waste and manure are generated from human activity, but these organic wastes contain high levels of organic matter and thus they are potential substrates for producing methane of biogas. The biogas contains 60% of highly concentrated methane, which is expected to be used effectively as energy. In this paper, we investigate the status of biogas in Korea as an alternative energy.

A Study on Reported Status and Management Plan of Marine Facilities in Korea 2. On the Basis of Region and Type of Facilities (국내 해양시설의 신고 현황과 관리 방안에 관한 연구 2. 지역별 및 시설종류별 현황을 중심으로)

  • Kim, Kwang-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.16 no.3
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    • pp.275-285
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    • 2010
  • Present state of nationwide marine facilities reported to 12 regional maritime affairs and port offices of MLTM in Korea for two years 2008 and 2009 was analyzed based on region and type of facilities, and national management plan was proposed in this study. As of the end of 2009, 8 types of marine facilities were reported to Yeosu regional maritime affairs and port office, while only 3 types of facilities were reported to Pohang, Daesan and Jeju regional offices, respectively. Oil and noxious liquid substances storage facilities belonged in the type of facility which was reported to all of 12 regional offices, and ranged from 11 facilities reported to Pyeongtaek regional office to the respective 38 facilities to Yeosu and Masan regional offices. In pollutants storage facilities, 4 facilities were reported to Masan regional office, 2 facilities to Donghae and Mokpo regional offices, respectively, 1 facility to Yeosu, Gunsan and Pyeongtaek regional offices, respectively, and none of facilities to the other regional offices. Ship construction, repair and scrap facilities belonged in the type of facility which was reported to all of 12 regional offices, and 45% of the facilities were concentrated in Southeastern Sea of Korea centering around Busan and Masan. In cargo handling facilities, 3 facilities were reported to Busan and Masan regional offices, respectively, 1 facility to Daesan regional office, and none of facilities to the other regional offices. In wastes storage facilities, 5 facilities were reported to Ulsan regional office, 4 facilities to Gunsan regional office, 2 facilities to Incheon regional office, 1 facility to Yeosu regional office, and none of facilities to the other regional offices. 65% of nationwide water intake and drainage facilities were concentrated in the areas of Pohang and Mokpo, and 78% of nationwide fishing spots at play were concentrated in the area of Masan. In other marine facilities, 4 facilities were reported to Donghae regional office, 3 facilities to Masan regional office, 2 facilities to Yeosu and Pyeongtaek regional offices, respectively, 1 facility to Incheon and Ulsan regional offices, respectively, and none of facilities to the other regional offices. In integrated marine science base facilities, 3 facilities were reported to Jeju regional office, 1 facility to Yeosu, Ulsan and Gunsan regional offices, respectively, and none of facilities to the other regional offices. The management based on the circumstances of regional offices, the management based on the characteristics of the type of facilities, the amendment of the relevant rules and regulations, facility owner's full knowledge and observance of the relevant rules and regulations with regard to the relevant type of facilities, and positive management actions from national point of view were proposed for national management plans of marine facilities.