• Title/Summary/Keyword: Composites materials

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Electrical Transport Properties and Magnetoresistance of (1-x)La0.7Sr0.3MnO3/xZnFe2O4 Composites

  • Seo, Yong-Jun;Kim, Geun-Woo;Sung, Chang-Hoon;Lee, Chan-Gyu;Koo, Bon-Heun
    • Korean Journal of Materials Research
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    • v.20 no.3
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    • pp.137-141
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    • 2010
  • The $(1-x)La_{0.7}Sr_{0.3}MnO_3(LSMO)/xZnFe_2O_4$(ZFO) (x = 0, 0.01, 0.03, 0.06 and 0.09) composites were prepared by a conventional solid-state reaction method. We investigated the structural properties, magnetic properties and electrical transport properties of (1-x)LSMO/xZFO composites using X-ray diffraction (XRD), scanning electron microscopy (SEM), field-cooled dc magnetization and magnetoresistance (MR) measurements. The XRD and SEM results indicate that LSMO and ZFO coexist in the composites and the ZFO mostly segregates at the grain boundaries of LSMO, which agreed well with the results of the magnetic measurements. The resistivity of the samples increased by the increase of the ZFO doping level. A clear metal-to-insulator (M-I) transition was observed at 360K in pure LSMO. The introduction of ZFO further downshifted the transition temperature (350K-160K) while the transition disappeared in the sample (x = 0.09) and it presented insulating/semiconducting behavior in the measured temperature range (100K to 400K). The MR was measured in the presence of the 10kOe field. Compared with pure LSMO, the enhancement of low-field magnetoresistance (LFMR) was observed in the composites. It was clearly observed that the magnetoresistance effect of x = 0.03 was enhanced at room temperature range. These phenomena can be explained using the double-exchange (DE) mechanism, the grain boundary effect and the intrinsic transport properties together.

Heating Properties of Cement Composites using Waste Carbon Materials (폐탄소 소재를 활용한 시멘트복합체 발열성능 평가)

  • Koo, Hyun-Chul;Cho, Hyeong-Kyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.213-214
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    • 2023
  • The burden of housing heating costs has increased as energy prices such as global oil prices (28.1%), LNG (38%) and minerals (100%) have soared due to the Ukraine crisis. Accordingly, an electrically conductive cement composites had developed using waste carbon materials such as waste cathode materials, waste CNTs, and waste carbon fibers, and the heat generation performance was evaluated.

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Electromagnetic Interference Reflectivity of Nanostructured Manganese Ferrite Reinforced Polypyrrole Composites

  • Chakraborty, Himel;Chabri, Sumit;Bhowmik, Nandagopal
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.6
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    • pp.295-298
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    • 2013
  • Nano-size manganese ferrite reinforced conductive polypyrrole composites reveal a core-shell structure by in situ polymerization, in the presence of dodecyl benzene sulfonic acid as the surfactant and dopant, and iron chloride as the oxidant. The structure and magnetic properties of manganese ferrite nano-fillers were measured, by using X-ray diffraction and vibrating sample magnetometer. The morphology, microstructure, and conductivity of the composite were characterized by transmission electron microscopy, Fourier transform infrared spectroscopy, and four-wire technique. The microwave-absorbing properties of composites reinforcement dispersed in resin coating with the coating thickness of 1.2 nm were investigated, by using vector network analyzers, in the frequency range of 8~12 GHz. A reflection loss of -8 dB was observed at 10.5 GHz.

Preparation of Porous Mullite Composites through Recycling of Coal Fly Ash (석탄회의 재활용을 통한 다공질 뮬라이트 복합체의 제조)

  • Kim, Won-Young;Ji, Hyung-Bin;Yang, Tae-Young;Yoon, Seog-Young;Park, Hong-Chae
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.151-156
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    • 2010
  • Porous mullite/alumina composites have been fabricated by a freeze casting technique using TBA-based coal fly ash/alumina slurry. After sintering, unidirectional macropore channels aligned regularly along the TBA ice growth direction were developed; simultaneously, small sized micropores fromed in the outer walls of the pore channels. The physical and mechanical properties (e.g. porosity and compressive strength) of the sintered porous composites were roughly dependant of processing conditions, due to the complexity of the factors affecting them. However, with increasing solid loading and sintering temperature, the compressive strength generally increased and the porosity decreased. After sintering $1500^{\circ}C$ for 2 h, the porous specimen (porosity: 52.1%) showed a maximum compressive strength of 70.0 MPa.

Effect of Oxy-Fluorinated Carbon Fiber Surfaces on Mechanical Interfacial Properties of Carbon Fibers-reinforced Composites (산소-불소처리된가 탄소섬유 강화 복합재료의 기계적 계면특성에 미치는 영향)

  • Oh Jin-Seok;Lee Jae Rock;Park Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.100-103
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    • 2004
  • In this work, the effects of oxy-fluorination on surface characteristics of carbon fibers were investigated in mechanical interfacial properties of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by X-ray photoelectron spectroscopy (XPS), FT-IR. and contact angle measurements. And their mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical stress intensity factor $(K_{IC})$. As experimental results, the $F_{1S}/C_{1S}$ ratio of carbon fiber surfaces was increased by oxy-fluorination, due to the development of the oxygen containing functional groups. The mechanical interfacial properties of the composites, including ILSS and $K_{IC}$, had been improved in the oxy-fluorination on fibers. These results could be explained that the oxy-fluorination was resulted in the increase of the adhesion between fibers and matrix in a composite system.

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Preparation and Characterization of Polypropylene/Waste Ground Rubber Tire Powder Microcellular Composites by Supercritical Carbon Dioxide

  • Zhang, Zhen Xiu;Lee, Sung-Hyo;Kim, Jin-Kuk;Zhang, Shu Ling;Xin, Zhen Xiang
    • Macromolecular Research
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    • v.16 no.5
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    • pp.404-410
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    • 2008
  • In order to obtain 'value added products' from polypropylene (PP)/waste ground rubber tire powder (WGRT) composites, PP/WGRT microcellular foams were prepared via supercritical carbon dioxide. The effects of blend composition and processing condition on the cell size, cell density and relative density of PP/WGRT micro-cellular composites were studied. The results indicated that the microcellular structure was dependent on blend composition and processing condition. An increased content of waste ground rubber tire powder (WGRT) and maleic anhydride-grafted styrene-ethylene-butylene-styrene (SEBS-g-MA) reduced the cell size, and raised the cell density and relative density, whereas a higher saturation pressure increased the cell size, and reduced the cell density and relative density. With increasing saturation temperature, the cell size increased and the relative density decreased, whereas the cell density initially increased and then decreased.

Consolidation of Bulk Metallic Glass Composites

  • Lee, Jin-Kyu;Kim, Hwi-Jun;Kim, Taek-Soo;Shin, Seung-Yong;Bae, Jung-Chan
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.848-849
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    • 2006
  • Bulk metallic glass (BMG) composites combining a $Cu_{54}Ni_6Zr_{22}Ti_{18}$ matrix with brass powders or $Zr_{62}A_{l8}Ni_{13}Cu_{17}$ metallic glass powders were fabricated by spark plasma sintering. The brass powders and Zr-based metallic glass powders added for the enhancement of plasticity are well distributed homogeneously in the Cu-based metallic glass matrix after consolidation. The BMG composites show macroscopic plasticity after yielding, and the plastic strain increased to around 2% without a decrease in strength for the composite material containing 20 vol% Zr-based amorphous powders. The proper combination of strength and plasticity in the BMG composites was obtained by introducing a second phase in the metallic glass matrix.

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Characteristics of Glass/Carbon Fiber Hybrid Composite Using by VARTM (VARTM 공정을 이용한 유리/탄소섬유 하이브리드 복합체의 특성)

  • Han, In-Sub;Kim, Se-Young;Woo, Sang-Kuk;Hong, Ki-Seok;Soe, Doo-Won
    • Journal of the Korean Ceramic Society
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    • v.43 no.10 s.293
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    • pp.607-612
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    • 2006
  • In VARTM (Vacuum Assisted Resin Transfer Molding) process, the permeability generally controls the filling time of the resin and it also affects the void characteristics of the fiber composite. In this study, carbon and glass fiber inter-layered hybrid composites (carbon fiber centered stack) with an epoxy matrix were fabricated by VARTM process and evaluated the resin flow and macro void characteristics. The permeability of glass fiber was higher than that of carbon fiber used in this study. Using Darcy's equation, the permeability of hybrid composites could be predicted and experimentally confirmed. After curing, the macro void content of hybrid composites was investigated using image analyzer. The calculated filling time was well agreed with experimental result and the void content was significantly changed in hybrid composites.

Comparison of Polyphenylene Sulfide Composites Having Different Processing Temperatures and Glass Fibers

  • Jeong, Do Yeon;Yoo, Seung Yong;Jung, Chan-Gyu;Lee, Jaeyong;Kim, Sang Hoon;Lee, Pyeong-Chan;Lee, Hyun Wook;Ha, Jin Uk
    • Elastomers and Composites
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    • v.54 no.4
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    • pp.308-312
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    • 2019
  • Polyphenylene sulfide (PPS) is a well-known super engineering plastic with a high melting temperature (above 290℃). It is generally insoluble under regular conditions. Therefore, it can be used for replacing metallic materials. Many researchers are looking at the possibility of replacing aluminum in the engine compartment of an automobile. However, studies on PPS are not common as compared to conventional engineering plastics because only a few companies produce super engineering plastics. In this research, the material properties of PPS composites containing two different kinds of glass fibers and produced under different processing temperatures were investigated. The tensile strength of the PPS composites increased as the processing temperature increased. Although glass fibers with similar aspect ratios were compounded under the same processing condition, one of them yielded a higher mechanical strength.

Effect of the Processing Parameters on the Densification and Strength of 2D SiC Fiber-SiC Matrix Composites Fabricated by Slurry Infiltration and Stacking Process

  • Lim, Kwang-Young;Jang, Doo-Hee;Kim, Young-Wook;Park, Ji-Yeon;Park, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.44 no.7
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    • pp.349-353
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    • 2007
  • 2D SiC fiber-SiC (SiC/SiC) composites were fabricated via slurry infiltration and a stacking process. The effects of the additive composition and content in SiC slurries and the effect of the sintering time on the sintered density and strength of SiC/SiC composites were investigated. A slurry containing $Al_2O_3-Y_2O_3-MgO$ (AYM) additives led to a higher strength compared to a slurry containing $Al_2O_3-Y_2O_3-CaO$ (AYC) additives. The sintered density increased as the sintering time increased and showed a maximum (>98%) at 4 h. In contrast, the flexural strength increased as the sintering time increased and showed a maximum (615 MPa) at 6 h. The relative density and flexural strength increased as the additive content increased.