• 제목/요약/키워드: Composites materials

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Effect of Carbon Nanofiber Structure on Crystallization Kinetics of Polypropylene/Carbon Nanofiber Composites

  • Lee, Sung-Ho;Hahn, Jae-Ryang;Ku, Bon-Cheol;Kim, Jun-Kyung
    • Bulletin of the Korean Chemical Society
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    • 제32권7호
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    • pp.2369-2376
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    • 2011
  • Effect of heat treatment of carbon nanofibers (CNF) on electrical properties and crystallization behavior of polypropylene was reported. Two types of CNFs (untreated and heat treated at 2300 $^{\circ}C$) were incorporated into polypropylene (PP) using intensive mixing. A significant drop in volume resistivity was observed with composites containing untreated 5 wt % and heat treated 3 wt % CNF. In non-isothermal crystallization studies, both untreated and heat treated CNFs acted as nucleating agents. Composites with heat treated CNFs showed a higher crystallization temperature than composites with untreated CNFs did. TEM results of CNF revealed that an irregular structure of CNFs can be converted into the continuous graphitic structure after heat treatment. Furthermore, STM showed that the higher carbonization temperature leads to the higher graphite degree which presents the larger carbon network size, suggesting that a more graphitic structure of CNFs led to a higher crystallization temperature of PP.

용탕단조를 이용한 SiC 휘스카 강화 마그네슘복합재료의 제조 (Squeeze Casting of SiC Whisker Reinforced Magnesium Composites)

  • 장시영;신동혁;홍성길;최정철
    • 한국주조공학회지
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    • 제20권3호
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    • pp.167-172
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    • 2000
  • Squeeze casting was performed to fabricate the SiC whisker reinforced magnesium matrix composites, and the suitability of the squeeze casting for the production of the sound composites was determined by micro/macro-structures observations and tensile test. The two-directional infiltration of the melt and the removal of air during infiltration using the devised mold were necessary to produce the composites. The pressure of 100 MPa was effective for the production of composites with the SiC whisker volume fraction of 30%, but the pressure should be lower than 50 MPa in case of below 20% in the volume fraction. The SiC whiskers in the squeeze cast composites were randomly and densely aligned, and the SiC whiskers/magnesium interfaces were continuously well-bonded. The elastic modulus, 0.2% proof stress and tensile strength in the composite were about 2.5times, l0times and 4times as large as those of magnesium, respectively, indicating that the squeeze casting sufficiently provides the high strength magnesium composites reinforced with SiC whiskers.

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Effect of Fe Contents in Fe-AC/Tio2 Composites on Photodegradation Behaviors of Methylene Blue

  • Oh, Won-Chun;Chen, Ming-Liang;Zhang, Feng-Jun;Jang, Hyun-Tae
    • 한국세라믹학회지
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    • 제45권6호
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    • pp.324-330
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    • 2008
  • Activated carbon/$TiO_2$ (AC/$TiO_2$) composites modified with different concentrations of Fe were prepared. The $N_2$ adsorption data showed that the composites had decreased surface area compared with the pristine activated carbon. This indicated the blocking of the micropores on the surface of AC, which was further supported by observation via SEM. XRD results showed patterns for the composites and an anatase typed titanium dioxide structure with a small part of rutile in a higher Fe concentration (> 1.0 mol/L). EDX results showed the presence of C and, O, with Ti peaks on the composites of Fe-AC/$TiO_2$ with relatively lower Ti concentration, which may be due to the higher Fe concentration incorporated into the composites. Subsequently, the photocatalytic effects on methylene blue (MB) were investigated. The improved decomposition of MB showed the combined effects of adsorptions and photodegradation. Especially, the composites modified by Fe revealed enhanced photodegradation behaviors of MB.

Carbon Black-Polyethylene복합재료의 Percolation Threshold 전후 저항율에 미치는 온도의 영향 (Effect of the Temperature on Resistivity of Carbon Black-Polyethylene Composites Below and Above Percolation Threshold)

  • 신순기
    • 한국재료학회지
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    • 제19권12호
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    • pp.644-648
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    • 2009
  • Temperature dependency of resistivity of the carbon black-polyethylene composites below and above percolation threshold is studied based on the electrical conduction mechanism. Temperature coefficient of resistance of the composites below percolation threshold changed from minus to plus, increasing volume fraction of carbon black; this trend decreased with increasing volume fraction of carbon black. The temperature dependence of resistivity of the composites below percolation threshold can be explained with a tunneling conduction model by incorporating the effect of thermal expansion of the composites into a tunneling gap. Temperature coefficient of resistance of the composites above percolation threshold was positive and its absolute value increased with increasing volume fraction of carbon black. By assuming that the electrical conduction through percolating paths is a thermally activated process and by incorporating the effect of thermal expansion into the volume fraction of carbon black, the temperature dependency of the resistivity above percolation threshold has been well explained without violating the universal law of conductivity. The apparent activation energy is estimated to be 0.14 eV.

복합소재의 건설분야 응용현황과 콘크리트 합성압축부재의 개발 (Application of Composites to Construction Industry and Development of Concrete Filled Composite Compression Member)

  • 이성우;박신전
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 1999년도 추계학술발표대회 논문집
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    • pp.183-188
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    • 1999
  • Due to many advantages of advanced composite materials, research on the application of composites to the construction industry is initiated. In this paper, fabrication methods efficient for infrastructures and application examples of each method are discussed. It also presents the structural characteristics of concrete filled glass fiber reinforced composite tubular member. Experimental results shows that strength and ductility of composite compression member is considerably increased due to concrete confinement action of composite surface.

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일본내 연구동향(6편중 제 2편) (Some Aspects of Mechanical Test Methods for Advanced Composites)

  • Fukuda, Hiroshi;Wada, Atsushi
    • Composites Research
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    • 제15권1호
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    • pp.61-69
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    • 2002
  • This paper review research activities of some mechanical test methods thor advanced composites which have been conducted in Fukuda laboratory. Tokyo University of Science. The subjects are (1) innovation and development of compression bending test. (2) mechanical-property evaluation of soft-core sandwich beam, and (3) loop test to measure the strength of monofilaments.

Magnetostrictive Properties of Polymer-Bonded Fe-Co Based Alloy Composites

  • S. M. Na;S. J. Suh;K. H. Shin;Lee, Y. S.;S. H. Lim
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2002년도 동계연구발표회 논문개요집
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    • pp.138-139
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    • 2002
  • Polymer-bonded magnetostrictive composites have some distinct advantages over conventional type materials in being cost effective and suitable for high frequency applications due to high electrical resistivity. Composites of rare earth based alloys were reported to show good magnetostrictive characteristics both in static and dynamic conditions [1]. It was originally thought that the application of the polymer-bonding technique to transition metal alloys is straightforward. (omitted)

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VaRI 공정 유동해석 간소화 방법에 대한 연구 (A Study on Simplifying Flow Analysis of VaRI Process)

  • 김영민;이정완;김정수;안세훈;오영석;이진우;김위대;엄문광
    • Composites Research
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    • 제34권4호
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    • pp.233-240
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    • 2021
  • VaRI(Vacuum assisted Resin Infusion) 공정은 공정비용이 저렴하며, 크기가 큰 복합재 제작에 적합한 OoA(Out of Autoclave) 공정이다. VaRI 공정에서는 원할한 수지 주입을 위해 섬유 상단에 유로망을 적층한다. 수지는 이 유로망을 따라 섬유의 면 방향으로 빠르게 공급되고, 공급된 수지는 다시 섬유의 두께방향으로 함침된다. 면방향의 유동과 두께방향의 유동이 동시에 일어나기 때문에 수지의 유동을 예측하기 힘들며, 수지 주입과정을 예측하기 위해 3D 수치해석 프로그램이 사용되고 있다. 하지만, 3D로 해석하기 위해서 섬유와 유로망의 두께방향에 많은 Element가 필요하고, 이로 인해 제품의 크기가 클수록 해석시간이 오래 걸린다. 따라서 본 연구에서는 3D 유동해석을 2D 해석으로 간소화하여 유동해석에 소요되는 시간을 줄이는 방법을 제시하였다. 3D 유동해석과 간소화된 2D 유동해석을 동일조건에서 비교하여 효용성을 검증하였고, 충진시간 오차율은 약 7%, 유동해석시간 감소율은 약 95%로 나타났다. 또한 3D 해석에서 섬유 상, 중, 하단 간의 유동 전진 거리의 차이가 일정하다는 것을 활용하여 간소화된 2D 유동해석에서도 상, 중, 하단의 유동 전진 거리를 예측할 수 있었다.