• Journal of Powder Materials
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• v.16 no.5
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• pp.310-315
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• 2009

Ultra-fine TiC/Co composite powder was synthesized by the carbothermal reduction process without wet chemical processing. The starting powder was prepared by milling of titanium dioxide and cobalt oxalate powders followed by subsequent calcination to have a target composition of TiC-15 wt.%Co. The prepared oxide powder was mixed again with carbon black, and this mixture was then heat-treated under flowing argon atmosphere. The changes in the phase, mass and particle size of the mixture during heat treatment were investigated using XRD, TG-DTA and SEM. The synthesized oxide powder after heat treatment at 700$^{\circ}C$ has a mixed phase of TiO$_2$ and CoTiO$_3$ phases. This composite oxide powder was carbothermally reduced to TiC/Co composite powder by the solid carbon. The synthesized TiC/Co composite powder at 1300$^{\circ}C$ for 9 hours has particle size of under about 0.4 $\mu$m.

• Journal of Powder Materials
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• v.25 no.1
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• pp.36-42
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• 2018

In order to expand the application of oxide dispersion-strengthened (ODS) steel, a composite material is manufactured by adding mechanically alloyed ODS steel powder to conventional steel and investigated in terms of microstructure and wear properties. For comparison, a commercial automobile part material is also tested. Initial microstructural observations confirm that the composite material with added ODS steel contains i) a pearlitic Fe matrix area and ii) an area with Cr-based carbides and ODS steel particles in the form of a $Fe-Fe_3C$ structure. In the commercial material, various hard Co-, Fe-Mo-, and Cr-based particles are present in a pearlitic Fe matrix. Wear testing using the VSR engine simulation wear test confirms that the seatface widths of the composite material with added ODS steel and the commercial material are increased by 24% and 47%, respectively, with wear depths of 0.05 mm and 0.1 mm, respectively. The ODS steel-added composite material shows better wear resistance. Post-wear-testing surface and cross-sectional observations show that particles in the commercial material easily fall off, while the ODS steel-added material has an even, smooth wear surface.

• Journal of Electrochemical Science and Technology
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• v.2 no.1
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• pp.32-38
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• 2011

The composite barium strontium cobalt ferrite (BSCF) cathodes were investigated in the intermediate temperature range of solid oxide fuel cells (SOFCs). The characteristics and electrochemical performances of composited BSCF/samarium doped ceria (SDC); BSCF/gadolinium doped ceria (GDC); and BSCF/SDC/GDC were compared to single BSCF cathode. The BSCF used in this study were synthesized using glycine nitrate process and mechanically mixing was used to fabricate a composite cathode. Using a composite form, the thermal expansion coefficient (TEC) could be reduced and BSCF/SDC/GDC exhibited the lowest TEC value at $18.95{\times}10^{-6}K^{-1}$. The electrochemical performance from half cells and single cells exhibited nearly the same trend. All the composite cathodes gave higher electrochemical performance than the single BSCF cathode (0.22 $Wcm^{-2}$); however, when two kinds of electrolyte were used (BSCF/SDC/GDC, 0.36$Wcm^{-2}$), the electrochemical performance was lower than when the BSCF/SDC (0.45 $Wcm^{-2}$) or BSCF/GDC (0.45 $Wcm^{-2}$) was applied as cathode ($650^{\circ}C$, 97%$H_2$/3%$H_2O$ to the anode and ambient air to the cathode).

• Nuclear Engineering and Technology
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• v.55 no.8
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• pp.2919-2926
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• 2023

In this paper, rare earth element (REE)/polyester composites were designed with lanthanum oxide, gadolinium oxide, and lutetium oxide as ray shielding agents, and polyethylene terephthalate (PET) as the base. Monte Carlo simulation was carried out using FLUKA software. We found that the radiation protection performance of the composite is affected by the type and amount of REE; a higher amount of REE equated to a better radiation protection performance of the composite. When the thickness of the composite and total thickness of the REE is constant, the number of superimposed layers inside the composite does not affect its shielding performance. Compared with a single-type REE/PET composite, a mixed-type REE/PET composite has a wider range of γ-ray absorption and better radiation protection performance. When the mass ratio of PET to REE is 2:8 and different types of REE are mixed with equal mass, several 0.2 cm-thick mixed-type REE/PET composites can shield >70% of 60 and 80 KeV γ-rays.

• Journal of the Korean Chemical Society
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• v.62 no.4
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• pp.269-274
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• 2018

Surface renewable nano-$RuO_2$/poly(methyl methacrylate) polymeric composite pH electrodes were prepared. The composite electrode with 53 wt% of nano-$RuO_2$ showed similar good response characteristics to nano-$IrO_2$ composite electrode reported earlier. It showed response slope of -58.7 mV/pH, response time of <1 s, surface renewability of $-57.0{\pm}0.3mV/pH$ (n=5) and long time stability for a month as well as low interferences but high interferences by electrochemically active species like $I^-$ and $Fe(CN){_6}^{3-}$. However, the response slope and time became worse at higher pH than 9 compared to those of nano-$IrO_2$ composite electrodes possibly due to the difference of physical properties resulting from higher content of nano-$RuO_2$ in polymeric composite matrix.

• Transactions on Electrical and Electronic Materials
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• v.7 no.4
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• pp.167-172
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• 2006

Submicron colloidal silica coated with ceria were prepared by mixing of silica and nano ceria particles and modified by hydrothermal reaction. The polishing efficiency of the ceria coated silica slurry was tested over oxide film on silicon wafer. By changing the polishing pressure in the range of $140{\sim}420g/cm^2$ with the ceria coated silica slurries in $100{\sim}300nm$, rates, WIWNU and friction force were measured. The removal rate was in the order of 200, 100, and 300 nm size silica coated with ceria. It was known that the smaller particle size gives the higher removal rate with higher contact area in Cu slurry. In the case of oxide film, the indentation volume as well as contact area gives effect on the removal rate depending on the size of abrasives. The indentation volume increase with the size of abrasive particles, which results to higher removal rate. The highest removal rate in 200 nm silica core coated with ceria is discussed as proper combination of indentation and contact area effect.

• Composites Research
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• v.33 no.1
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• pp.25-29
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• 2020

A liquid crystalline thermosetting-epoxy-based composite was fabricated using diglycidyl ether of 4,4'-biphenol, tin(IV) oxide as a filler, and sulfanilamide as a curing agent. To investigate the thermal behavior, Thermogravimetric Analysis and Laser Flash Apparatus were performed using 3.0-7.0 wt% Tin(IV) oxide. The result showed that the activation energy and thermal conductivity were proportional to the amount of added filler.

• Composites Research
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• v.36 no.3
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• pp.167-172
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• 2023

The manufacturing technology of composite material is applicable with filler characteristics maintaining low cost, flexibility, and easy process to develope the various functional composite materials. To realize functional composites, various researches on the high performance of composite materials using graphene as a filler is being actively conducted. In this study, physical and chemical properties were investigated using graphene to improve high functional properties. Graphene oxide (GO) was prepared using graphane nanoplatelet (GNP), and reduced graphene oxide (R-GO) was formed by reducing GO. The physical properties of GO and R-GO were analyzed, and the reliability of the manufactured method was reviewed by comparing that of GNP results. As a result of analysis by Raman spectroscopy, in the case of R-GO, it was confirmed that the intensity of D-peak and G-peak decreased compared to GO, and an increase of 0.08 was observed through the ratio of ID/IG. For the FTIR results, GO and RGO has a repeating C-C and C=C connection structure unlike GNP. GO and R-GO show clear peaks for C-O bond, C=C bond, C=O bond, and O-H bonding. As a result of X-ray diffraction analysis, GNP showed a wide diffraction peak at 25.86° of (002) plane characteristics, whereas GO and R-GO showed peaks corresponding to (001) and (100) planes. It was also found that the interlayer distance of GO increased by about 2.6 times compared to GNP.

• International Journal of Aeronautical and Space Sciences
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• v.11 no.4
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• pp.360-365
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• 2010

Three phase composite materials are widely used in the shipbuilding industry. When reinforced with fiber and particle, the physical and mechanical properties of polymer composite materials are improved. This paper presents the bending analysis of a three phase composite plate with an epoxy matrix, reinforced glass fiber and titanium oxide particles including creep effect when shear stress is taken into account. The obtained results indicate that creep strains lead to compression in the composite material. Introducing reinforced fibers and particles reduces the plate's deflection, when increasing the stretch coefficient allows the calculation of creep deflection during a long loading period.

• Steel and Composite Structures
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• v.19 no.3
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• pp.777-787
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• 2015

Production and properties of metal matrix composites reinforced with an in-situ high aspect ratio $AlB_2$ flake have been investigated. Boron 2.2wt.% was dissolved in pure Al and Al-Cu alloy at $1300^{\circ}C$ by adding directly boron oxide which resulted in 4 vol.% reinforcing phase. The in-situ $AlB_2$ flake concentration was increased up to 30 vol.% in order to increase the tensile strength of the composites. Hardness, compressive strength and tensile strength of the composite were measured and compared with their matrix. Results showed that 30 vol.% $AlB_2/Al$ composite show a 193% increase in the compressive strength and a 322% increase in compressive yield strength. Results also showed that ductility of composites decreases with adding $AlB_2$ reinforcements.