• Steel and Composite Structures
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• 제27권6호
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• pp.727-745
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• 2018

The design criteria and the corresponding performance levels characterize the response of extended stiffened end-plate beam-to-column joints. In order to guarantee a ductile behavior, hierarchy criteria should be adopted to enforce the plastic deformations in the ductile components of the joint. However, the effectiveness of thesecriteria can be impaired if the actual resistance of the end-plate material largely differs from the design value due to the potential activation of brittle failure modes of the bolt rows (e.g., occurrence of failure mode 3 in the place of mode 1 per bolt row). Also the number and the position of bolt rows directly affect the joint response. The presence of a bolt row in the center of the connection does not improve the strength of the joint under both gravity, wind and seismic loading, but it can modify the damage pattern of ductile connections, reducing the gap opening between the end-plate and the column face. On the other hand, the presence of a central bolt row can influence the capacity of the joint to resist the catenary actions developing under a column loss scenario, thus improving the joint robustness. Aiming at investigating the influence of these features on both the cyclic behavior and the response under column loss, a wide range of finite element analyses (FEAs) were performed and the main results are described and discussed in this paper.

• Advances in nano research
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• 제8권2호
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• pp.135-148
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• 2020

The incorporation of carbon nanotubes in a polymer matrix makes it possible to obtain nanocomposite materials with exceptional properties. It's in this scientific background that this work was based. There are several theories that deal with the behavior of plates, in this research based on the Mindlin-Reissner theory that takes into account the transversal shear effect, for analysis of the critical buckling load of a reinforced polymer plate with parabolic distribution of carbon nanotubes. The equations of the model are derived and the critical loads of linear and parabolic distribution of carbon nanotubes are obtained. With different disposition of nanotubes of carbon in the polymer matrix, the effects of different parameters such as the volume fractions, the plate geometric ratios and the number of modes on the critical load buckling are analysed and discussed. The results show that the critical buckling load of parabolic distribution is larger than the linear distribution. This variation is attributed to the concentration of reinforcement (CNTs) at the top and bottom faces for the X-CNT type which make the plate more rigid against buckling.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.475-481
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• 2013

By using ionic liquid 1-hexylpyridinium hexafluorophosphate ($HPPF_6$) based carbon ionic liquid electrode (CILE) as the substrate electrode, a $CoMoO_4$ nanorods and myoglobin (Mb) composite was casted on the surface of CILE with chitosan (CTS) as the film forming material to obtain the modified electrode (CTS/$CoMoO_4$-Mb/CILE). Spectroscopic results indicated that Mb retained its native structures without any conformational changes after mixed with $CoMoO_4$ nanorods and CTS. Electrochemical behaviors of Mb on the electrode were carefully investigated by cyclic voltammetry with a pair of well-defined redox peaks from the heme Fe(III)/Fe(II) redox center of Mb appeared, which indicated that direct electron transfer between Mb and CILE was realized. Electrochemical parameters such as the electron transfer number (n), charge transfer coefficient (${\alpha}$) and electron transfer rate constant ($k_s$) were estimated by cyclic voltammetry with the results as 1.09, 0.53 and 1.16 $s^{-1}$, respectively. The Mb modified electrode showed good electrocatalytic ability toward the reduction of trichloroacetic acid in the concentration range from 0.1 to 32.0 mmol $L^{-1}$ with the detection limit as 0.036 mmol $L^{-1}$ ($3{\sigma}$), and the reduction of $H_2O_2$ in the concentration range from 0.12 to 397.0 ${\mu}mol\;L^{-1}$ with the detection limit as 0.0426 ${\mu}mol\;L^{-1}$ ($3{\sigma}$).

• Steel and Composite Structures
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• 제12권4호
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• pp.291-302
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• 2012

Frequently, steel silos are supported by discrete supports or columns to permit easy access beneath the barrel. In such cases, large loads are transferred to the limited number of supports, causing locally high axial compressive stress concentrations in the shell wall above the supports. If not dealt with properly, these increased stresses will lead to premature failure of the silo due to local instability in the regions above the supports. Local stiffening near the supports is a way to improve the buckling resistance, as material is added in the region of elevated stresses, levelling these out to values found in uniformly supported silos. The aim of a study on the properties of local stiffening will then be to increase the failure load, governed by an interaction of plastic collapse and elastic instability, to that of a discrete supported silo. However, during the course of such a study it was found that, although the failure remains local, the cylinder height is also a parameter that influences the failure mechanism, a fact that is not properly taken into account in current design practice and codes. This paper describes the mechanism behind the effect of the cylinder height on the failure load, which is related to pre-buckling deformations of the shell structure. All results and conclusions are based on geometrically and materially non-linear finite element analyses.

• Archives of Pharmacal Research
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• 제24권3호
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• pp.229-233
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• 2001

This Paper deals with the development of a technology for making a hydrophilic gel of Polyethylene oxide reception in which radiating ability is employed to cause cross-linking of Polymers in a water solution. The gel of polyethylene oxide was shown to be nontoxic contain 5-50% of polymer and be useful in composite medicinal forms along with biologically active substances including Bac. subtilis proteases. Proteases immobilized in the gel possess high thermal stability and proteolytic activity and are readily applied in medicine. The effect of immobilized proteolytic and glucolytic enzymes of Bac. subtillis (Immozimase) on the warm ischemia-reperfusion (I/R) which can cause hepatic and jejunum injury was also studied. These enzymes were immobilized on water-soluble polymer polyethylene glycol by means of an electron beam. The number of degraanulated mast cells as well as serum ALT after I/R in the group with Immozimase was decreased to almost half as compared with the control group. Pretreatment with Immozimase resulted in significant reduction of hepatic and gut neutrophil accumulation as compared with control animals. It was concluded that Immozimase has a protective effect for hepatic and gut ischemia/reperfusion, and this effect seems to be associated with prevention of leukocyte accumulation .

• 콘크리트학회논문집
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• 제26권6호
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• pp.741-749
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• 2014

프리스트레스트 중공(PHC) 슬래브는 장경간에 적합하도록 경량화된 효율적인 프리캐스트 부재이며, 국내 외에서 많이 사용되고 있다. 특히, 국내에서는 현장타설콘크리트와 같이 사용되는 합성슬래브 형태로 주로 적용되고 있다. 그러나, 압출성형방식으로 제작되는 PHC 슬래브 부재는 매우 낮은 슬럼프의 콘크리트로 제작되어 타설 직후에도 표면경도가 높기 때문에 계면의 거친면 처리 및 전단연결재 배치가 어려운 단점이 있다. 이 연구에서는 PHC slab 부재와 토핑콘크리트 사이의 합성성능을 고찰하기 위하여 다양한 계면상태를 변수로 직접전단실험을 수행하였으며, 기존 실험결과를 수집하여 국내 외 수평전단강도 설계기준을 평가하였다.

• 한국건설관리학회논문집
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• 제1권1호
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• pp.80-86
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• 2000

최근 공동주택의 유지관리를 위한 인건비, 에너지비가 급속하게 증가하고 있다. 이에 따라 설계단계에서 이 비용을 절감할 수 있는 기법의 필요성이 제기되고 있다. 공동주택에 있어서는 대부분의 경우 세대당 동일한 내외벽, 창호 등이 반복적으로 사용되므로 단위평면의 LCC 최적화가 전체 건물의 LCC 최적화에 있어서 가장 중요하다. 이를 위하여 본 연구에서는 LCC 비용항목 중 공동주택의 물리적 시스템에 탄력성있게 변화하는 LCC 비용항목을 파악하였고, 초기건축비, 보수교체비, 에너지비를 종합적으로 최적화시킬 수 있도록 LCC 부위단가 개념을 도입하여 공동주택 적정치수 산정방법을 제시하였다. 여기에서 보수교체비산정은 보수교체비용 최소화에 의한 최적 보수교체주기법에 근거하였으며, 에너지 소비량 추정은 DOE-2에 의한 동적 에너지 부하량을 추정하여 LCC 부위단가 개념에 접목하였다. 보수교체비 최적화 기법과 동적에너지 분석에 의한 LCC 부위단가 개념은 기존의 개념과는 다른 독창적인 개념이다.

• 한국세라믹학회지
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• 제48권5호
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• pp.447-453
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• 2011

The monodisperse spherical $SiO_2$ particles were overcoated with $Y_2O_3:Eu^{3+}$ phosphor layers via a Pechini sol-gel process and the resulting $SiO_2@Y_2O_3:Eu^{3+}$ core-shell phosphors were subsequently annealed at $800^{\circ}C$ at an ambient atmosphere. The crystallographic structure, morphology, and luminescent property of core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and photoluminescence (PL). The spherical, nonagglomerated $SiO_2$ particles prepared by a Stober method exhibited a relatively narrow size distribution in the range of 260-300 nm. The thickness of phosphor shell layer in the core-shell particles can be facilely controlled by varying the coating number of $Y_2O_3:Eu^{3+}$ phosphors. The core-shell structured $SiO_2@Y_2O_3:Eu^{3+}$ phosphors showed a strong red emission, which was dominated by the $^5D_0-^7F_2$ transition (610 nm) of $Eu^{3+}$ ion under the ultraviolet excitation (263 nm). The PL emission properties of $SiO_2@Y_2O_3:Eu^{3+}$ phosphors were also compared with pure $Y_2O_3:Eu^{3+}$ nanophosphors.

• 한국세라믹학회지
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• 제56권3호
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• pp.211-232
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• 2019

Porous ceramics are promising materials for a number of functional and structural applications that include thermal insulation, filters, bio-scaffolds for tissue engineering, and preforms for composite fabrication. These applications take advantage of the special characteristics of porous ceramics, such as low thermal mass, low thermal conductivity, high surface area, controlled permeability, and low density. In this review, we emphasize the direct foaming method, a simple and versatile approach that allows the fabrication of porous ceramics with tailored microstructure, along with distinctive properties. The wet foam stability is achieved under the controlled addition of amphiphiles to the colloidal suspension, which induce in situ hydrophobization, allowing the wet foam to resist coarsening and Ostwald ripening upon drying and sintering. Different components, like contact angle, adsorption free energy, air content, bubble size, and Laplace pressure, play vital roles in the stabilization of the particle stabilized wet foam to the porous ceramics. The mechanical behavior of the load-displacements curves of sintered samples was investigated using Herzian indentations testes. From the collected results, we found that microporous structures with pore sizes from 30 ㎛ to 570 ㎛ and the porosity within the range from 70% to 85%.

• Steel and Composite Structures
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• 제8권5호
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• pp.403-421
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• 2008

The design provisions for semi-rigid steel frames have been incorporated in codes of practice for steel structures. In order to do the same, it is necessary to know the experimental moment-relative rotation (M-${\theta}_r$) behaviour of beam-to-column connections. In spite of numerous publications and collection of several connection databases, there is no unified approach for the semi-rigid design of steel frames. Amongst the many connection models available, the Frye-Morris polynomial model, with its limitations reported in the literature, is simple to adopt at least for the linear design space. However this model requires more number of connection tests and regression analyses to make it a realistic prediction model. In this paper, 3D nonlinear finite element (FE) analysis of beam-column connection specimens, carried out using ABAQUS software, for evaluating the M-${\theta}_r$ behaviour of semi-rigid top and seat-angle (TSA) bolted connections are described. The finite element model is validated against experimental behaviour of the same connection with regard to their moment-rotation behaviour, stress distribution and mode of failure of the connections. The calibrated FE model is used to evaluate the performance of the Frye-Morris polynomial model. The results of the numerical parametric studies carried out using the validated FE model have been used in proposing modifications to the Frye-Morris model for TSA connection in terms of the powers of the size parameters.