• Title/Summary/Keyword: Composite coatings

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Characteristics of plasma sprayed composite YSZ/Ni-Cr resistant heating coatings (YSZ/Ni-Cr 저항 발열 복합용사피막의 특성)

  • 김병수;박경채;김태형;양병모
    • Proceedings of the KWS Conference
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    • 2003.05a
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    • pp.111-113
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    • 2003
  • The existing heating unit is indirect-heating method that make use or the nichrome wire or halogen lamp. The indirect-heating method has the demerits of long warming time, high power consumption and many organization parts. In this study, the heating unit of direct-heating method manufactured as being the thermal spray coating of conductive heating material on the surface of heating unit in order to improve the demerits of indirect-heating method. And YSZ added Ni-20Cr that had moderate electrical resistivity was chosen of the conductive heating material.

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Effect of Concentration and Surface Property of Silica Sol on the Determination of Particle Size and Electrophoretic Mobility by Light Scattering Method (광산란법에서 실리카 졸의 농도 및 표면특성이 입자 크기 및 전기영동 이동도 측정결과에 미치는 영향)

  • Cho, Gyeong Sook;Lee, Dong-Hyun;Kim, Dae Sung;Lim, Hyung Mi;Kim, Chong Youp;Lee, Seung-Ho
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.622-627
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    • 2013
  • Colloidal silica is used in various industrial products such as chemical mechanical polishing slurry for planarization of silicon and sapphire wafer, organic-inorganic hybrid coatings, binder of investment casting, etc. An accurate determination of particle size and dispersion stability of silica sol is demanded because it has a strong influence on surface of wafer, film of coatings or bulks having mechanical, chemical and optical properties. The study herein is discussed on the effect of measurement results of average particle size, sol viscosity and electrophoretic mobility of particle according to the volume fraction of eight types of silica sol with different size and surface properties of silica particles which are presented by the manufacturer. The measured particle size and the mobility of these sol were changed by volume fraction or particle size due to highly active surface of silica particle and change of concentration of counter ion by dilution of silica sol. While in case the measured sizes of small particles less than 60 nm are increased with increasing volume fraction, the measured sizes of larger particles than 60 nm are slightly decreased. The mobility of small particle such as 12 nm are decreased with increase of viscosity. However, the mobility of 100 nm particles under 0.048 volume fraction are increased with increasing volume fraction and then decreased over higher volume fraction.

A Study of the Effects of Na Ion on Codeposition of Particles in the Formation of Electroless Ni Composite Coatings (무전해 Ni 복합도금에서 분말의 공석에 미치는 Na 이온의 영향)

  • 이원해;이승평
    • Journal of the Korean institute of surface engineering
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    • v.22 no.2
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    • pp.101-108
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    • 1989
  • Effects of Na+ ion on zeta potential of SiC and Al2O3 particles suspended in nikel sufate and nickel chloride solutions were investigated. various complexing agents for Ni2+ ion were added to electroless Ni composite bath and the effects of the complexing agents on zeta potential and codeposition of the particles from the baths were studied. It was confirmed that Na+ ion was absorbed on the particles bringing about the positive surface charge and thus they promoted the entrapment of the particles into the nickel deposit. On the basis of these results it was possible to deposit SiCc particle in nickel chloride electrolyte containing complex agent such as trisodium citrate+sodium succinate.

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A Study on the Analysis of 3 Dimensional Substrate Behaviour of Complex Environmental Deterioration and the Analysis of Results (복합열화분석용 3차원 거동대응성 시험을 통한 결과분석)

  • Song, Je-Young;Seo, Hyun-Jae;Kim, Bum-Soo;Choi, Eun-Kyu;Lee, Jung-Hun;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.219-220
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    • 2017
  • Current domestic waterproofing market in Korea mainly uses single-ply waterproofing materials comprised of coatings or waterproof sheets and two or more-ply composite waterproofing methods. In order to evaluate these types of composite waterproofing systems, a new test equipment and method that incorporates various deterioration conditions (joint displacement, chemical exposure, water pressure etc) was developed. In a comparison testing, the results showed that flexible type materials have higher response performance towards joint displacement than the hardened material. Furthermore, the importance of securing the stability of the waterproofing method in the vulnerable over-lap joint areas of waterproofing sheets is emphasized.

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IR Absorption Property in NaNo-thick Nickel Cobalt Composite Silicides (나노급 두께의 Ni50Co50 복합 실리사이드의 적외선 흡수 특성 연구)

  • Song, Oh Sung;Kim, Jong Ryul;Choi, Young Youn
    • Korean Journal of Metals and Materials
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    • v.46 no.2
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    • pp.88-96
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    • 2008
  • Thermal evaporated 10 nm-$Ni_{50}Co_{50}$/(70 nm-poly)Si films were deposited to examine the energy saving properties of silicides formed by rapid thermal annealing at temperature ranging from 500 to $1,100^{\circ}C$ for 40 seconds. Thermal evaporated 10 nm-Ni/(70 nm-poly)Si films were also deposited as a reference using the same method for depositing the 10 nm-$Ni_{50}Co_{50}$/(70 nm-poly)Si films. A four-point probe was used to examine the sheet resistance. Transmission electron microscopy (TEM) and X-ray diffraction XRD were used to determine cross sectional microstructure and phase changes, respectively. UV-VIS-NIR and FT-IR (Fourier transform infrared spectroscopy) were used to examine the near-infrared (NIR) and middle-infrared (MIR) absorbance. TEM analysis confirmed that the uniform nickel-cobalt composite silicide layers approximately 21 to 55 nm in thickness had formed on the single and polycrystalline silicon substrates as well as on the 25 to 100 nm thick nickel silicide layers. In particular, nickel-cobalt composite silicides showed a low sheet resistance, even after rapid annealing at $1,100^{\circ}C$. Nickel-cobalt composite silicide and nickel silicide films on the single silicon substrates showed similar absorbance in the near-IR region, while those on the polycrystalline silicon substrates showed excellent absorbance until the 1,750 nm region. Silicides on polycrystalline substrates showed high absorbance in the middle IR region. Nickel-cobalt composite silicides on the poly-Si substrates annealed at $1,000^{\circ}C$ superior IR absorption on both NIR and MIR region. These results suggest that the newly proposed $Ni_{50}Co_{50}$ composite silicides may be suitable for applications of IR absorption coatings.

Industrial application of WC-TiAlN nanocomposite films synthesized by cathodic arc ion plating system on PCB drill

  • Lee, Ho. Y.;Kyung. H. Nam;Joo. S. Yoon;Jeon. G. Han;Young. H. Jun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.06a
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    • pp.3-3
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    • 2001
  • Recently TiN, TiAlN, CrN hardcoatings have adapted many industrial application such as die, mold and cutting tools because of good wear resistant and thermal stability. However, in terms of high speed process, general hard coatings have been limited by oxidation and thermal hardness drop. Especially in the case of PCB drill, high speed cutting and without lubricant process condition have not adapted these coatings until now. Therefore more recently, superhard nanocomposite coating which have superhard and good thermal stability have developed. In previous works, WC-TiAlN new nanocomposite film was investigated by cathodic arc ion plating system. Control of AI concentration, WC-TiAlN multi layer composite coating with controlled microstructure was carried out and provides additional enhancement of mechanical properties as well as oxidation resistance at elevated temperature. It is noted that microhardness ofWC-TiA1N multi layer composite coating increased up to 50 Gpa and got thermal stability about $900^{\circ}C$. In this study WC-TiAlN nanocomposite coating was deposited on PCB drill for enhancement of life time. The parameter was A1 concentration and plasma cleaning time for edge sharpness maintaining. The characteristic of WC-TiAlN film formation and wear behaviors are discussed with data from AlES, XRD, EDS and SEM analysis. Through field test, enhancement of life time for PCB drill was measured.

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The Effects of Dielectric Coatings on Electron Emission from Tungsten

  • Al-Qudah, Ala'a M.;Alnawasreh, Shady S.;Madanat, Mazen A.;Trzaska, Oliwia;Matykiewicz, Danuta;Alrawshdeh, Saad S.;Hagmann, Mark J.;Mousa, Marwan S.
    • Applied Microscopy
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    • v.47 no.1
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    • pp.36-42
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    • 2017
  • Field electron emission measurements were performed on dielectric-coated tungsten emitters, with apex radii in the nanometer and micrometer range, which were prepared by electrochemical etching in NaOH solution. Measurements were performed in a field electron microscopy (FEM) with a base pressure <$10^{-6}$ Pascal ($10^{-8}$ mbar). Four different types of dielectric were used, namely: (1) Clark Electromedical Instruments epoxylite resin, (2) Epidian 6 produced by Ciech Sarzyna S. A., (3) a Radionox solution of colloidal graphite; and (4) Molyslip 2001 E compound ($MoS_2$ and MoS). Current-voltage measurements and FEM images were used to investigate the characteristics of these composite emitters, and to assess how the different types of dielectric coating affect the suitability of the composite emitter as a potential electron source.

Effect of Latex Particle Morphology on the Film Properties of Acrylic Coatings (II);Film Forming Behavior of Model Composite Latex (라텍스 입자구조가 필름형성 및 필름물성에 미치는 영향 (II);모델 복합 라텍스 입자의 필름형성 거동)

  • Ju, In-Ho;Wu, Jong-Pyo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.132-139
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    • 2004
  • Film forming behavior of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. The film forming behavior was evaluated using pseudo on-line measurements of the cumulative weight loss, the UV transmittance, and the tensile fracture energy. Each stages of film formation I, II were not sensitive to the morphology of model latexes, but stage-ill was largely dependent on the morphology of model latexes. The chain mobility of polymer which composed the shell component was found to dominantly determine the behavior of film forming stage-III.

A Study on the Analysis of 3 Dimensional Substrate Behaviour of Complex Environmental Deterioration and the Analysis of Results (방수재료 및 공법의 내구성 평가를 위한 복합열화분석용 3차원 거동대응 시험결과)

  • Song, Je-Young;Seo, Hyun-Jae;Choi, Eun-Kyu;Lee, Jung-Hun;Kim, Byoungil;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.189-190
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    • 2018
  • KS standards mostly relate to single component material evaluation, so in cases of underground structure environments, most cannot predict the existing composite forms of deterioration, resulting in the applied waterproofing materials becoming unable to respond to these damaging factors. Current domestic waterproofing market in Korea mainly uses single-ply waterproofing materials comprised of coatings or waterproof sheets and two or more-ply composite waterproofing methods. In order to evaluate these types of composite waterproofing systems, a new test equipment and method that incorporates various deterioration conditions (joint displacement, chemical exposure, water pressure etc) was developed. In a comparison testing, the results showed that flexible type materials have higher response performance towards joint displacement than the hardened material.

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