• Title/Summary/Keyword: Composite catalysis

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Effect of nonlinear FG-CNT distribution on mechanical properties of functionally graded nano-composite beam

  • Zerrouki, Rachid;Karas, Abdelkader;Zidour, Mohamed;Bousahla, Abdelmoumen Anis;Tounsi, Abdelouahed;Bourada, Fouad;Tounsi, Abdeldjebbar;Benrahou, Kouider Halim;Mahmoud, S.R.
    • Structural Engineering and Mechanics
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    • v.78 no.2
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    • pp.117-124
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    • 2021
  • This work focused on the novel numerical tool for the bending responses of carbon nanotube reinforced composites (CNTRC) beams. The higher order shear deformation beam theory (HSDT) is used to determine strain-displacement relationships. A new exponential function was introduced into the carbon nanotube (CNT) volume fraction equation to show the effect of the CNT distribution on the CNTRC beams through displacements and stresses. To determine the mechanical properties of CNTRCs, the rule of the mixture was employed by assuming that the single-walled carbon nanotubes (SWCNTs)are aligned and distributed in the matrix. The governing equations were derived by Hamilton's principle, and the mathematical models presented in this work are numerically provided to verify the accuracy of the present theory. The effects of aspect ratio (l/d), CNT volume fraction (Vcnt), and the order of exponent (n) on the displacement and stresses are presented and discussed in detail. Based on the analytical results. It turns out that the increase of the exponent degree (n) makes the X-beam stiffer and the exponential CNTs distribution plays an indispensable role to improve the mechanical properties of the CNTRC beams.

Characterization of Crosslinked Poly(vinyl alcohol) Membranes for the Preparation of Composite Membranes and Its Application to Pervaporation Separation (복합막 제조를 위한 가교된 폴리비닐알코올 막의 특성 평가와 이를 이용한 투과증발 분리)

  • 김연국;이정민;임지원;이영무
    • Membrane Journal
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    • v.9 no.3
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    • pp.157-162
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    • 1999
  • In the crosslining reaction of poly(vinyl alcohoJ)(PVA) with sulfur-succinic acid which had been established in our previous work, reaction temperature, 15$0^{\circ}C$, was so high to collapse the pore struc¬tures in support membrane for the preparation of composite membrane. Therefore, the efforts have been focused on lowering of the reaction temperature to 100$^{\circ}$C by using a catalysis, HC!. The newly established crosslinking reaction was characterized through the analysis of the chemical and thermal properties. From these results, the optimum conditions for the membrane preparation couId be drawn as followings : (i) reac¬tion temperature, 100 $^{\circ}C$,(ii) reaction time, 90 min, (iii) the concentration of the catalysis (HCD, 1.5%. Com¬posite membranes were fabricated by coating a casting solution containing PYA, sulfur-succinic acid and HCl on a support membrane followed by crosslinking it at 10$0^{\circ}C$. The resulting membranes were applied to the pervaporation separation of methyl-tert-butyl ether(MTBE)/methanol (MeOH) mixtures at 30, 40, and 5O$^{\circ}C$. The flux of 5.09 g/$m^2$hr at 5O$^{\circ}C$ and the highest separation factor of 1622 were obtained, respectively.

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A Study on the Properties and Fabrication of Bulk Forming GeSe Based Chalcogenide Glass for Infrared Optical Lens (적외선 광학렌즈 제작을 위한 GeSe의 벌크 제작 및 특성 연구)

  • Bae, Dong-Sik;Yeo, Jong-Bin;Park, Jung-Hoo;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.641-645
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    • 2013
  • Chalcogenide glass has superior property of optical transmittance in the infrared region. Glass made using Ge-Se how many important optical applications. We have determined the composite formular of $Ge_{0.25}Se_{0.75}$ to be the GeSe chalcogenide glass composition appropriate for IR lenses. Also, the optical, thermal and physical characteristics of chalcogenide glass depended on the composition ratio. GeSe bulk sample is produced using the traditional melt-quenching method. The optical, structural, thermal and physical properties of the compound were measured by using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential scanning calorimeter (DSC), and Scanning electron microscope (SEM) respectively.

A Study on the Development of Framework Using Component Based Methodology (컴포넌트기반 방법론을 사용한 프레임워크 개발에 관한 연구)

  • Kim, Haeng-Gon;Han, Eun-Ju
    • The Transactions of the Korea Information Processing Society
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    • v.7 no.3
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    • pp.842-851
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    • 2000
  • Developers can reuse not only class code but also wide range of knowledge on domain by reusing framework. Existing Object-Oriented Methodology and Catalysis Methodology were presented when redefining component in the course of redesigning framework. However, existing methodologies have weakness that entire process is waterfall mode or design of interface lays too much stress on implementation stage. So, this thesis will present Component-Oriented Methodology for the reuse of framework, and construct the environment for framework and domain development. That is, domain is analyzed by input of domain knowledge on real world to create software based on component, and hotspot is identified through analyzed information, and refactoring by putting additional information on users and developers. After that, I will create domain framework and application framework depending on domain. In this Component-Oriented Methodology, information is searched, understood and extracted or composite through component library storage internally. Then this information is classified into the information on component, and used as additional information in redesigning. With this, developer can obtain reusability, easiness and portability by constructing infrastructure environment that allows to register, update and delete component through Component Management System(CMS) under he development environment which can be easily applied to his own application using framework component, in this thesis, CoRBA(Common Object Request Broker Architecture) environment.

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Material Properties of GeSbSe Chalcogenide Glass and Fabrication Process for 8~12 ㎛ IR Region Aspherical Optical Lens (GeSbSe계 기반 8~12 ㎛ 파장대역 적외선 광학 렌즈 제작 및 비구면 렌즈 가공기술 개발)

  • Bae, Dong-Sik;Yeo, Jong-Bin;Han, Sang-Hyun;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.3
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    • pp.183-189
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    • 2013
  • The chalcogenide glass has superior optical properties in IR region transmittances. We have determined the composition of GeSbSe chalcogenide glass for the application of good IR lenses, resulting in the composite rate of $Ge_{19}Sb_{23}Se_{58}$. The optical, structural, thermal and physical properties were measured by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential scanning calorimeter (DSC), X-ray computed tomography (X-ray CT) respectively. The fabrication of the chalcogenide glass lens for infrared optics applications was proposed using a diamond turning machining technology which is known as the suitable ways for the production cost reduction and the accurate fabrication process control.

Free vibration responses of nonlinear FG-CNT distribution in a polymer matrix

  • Zerrouki, Rachid;Hamidi, Ahmed;Tlidji, Youcef;Karas, Abdelkader;Zidour, Mohamed;Tounsi, Abdelouahed
    • Smart Structures and Systems
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    • v.30 no.2
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    • pp.135-143
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    • 2022
  • The object of this paper is to investigate the free vibration behavior under the effect of carbon nanotube distribution in functionally graded carbon nanotube-reinforced composite (FG-CNTRC) by using higher-order shear deformation theories. In this work, we present a novel distribution method for carbon nanotubes in the polymer matrix by using a new exponential power law distribution of carbon nanotube volume fraction. It is assumed that the SWCNTs are aligned along the beam axial direction and the distribution of the SWCNTs may vary through the thickness of the beam with different patterns of reinforcement. The rule of mixtures is used in order to obtain material properties of the CNTRC beams. Hamilton's principle is used in deriving the equations of motion. The validity of the free Vibration results is examined by comparing them with those of the known data in the literature. The results that obtained indicate that the carbon nanotube volume fraction distribution play a very important role on the free vibrations characteristics of the CNTRC beam.

Ethylene Gas Adsorption of Clay-Woodceramics from 3 layers-clay-woodparticleboard

  • Lee, Hwa Hyoung;Kang, Seog-Goo
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.6
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    • pp.83-88
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    • 2003
  • The woodceramics are porous amorphous carbon and glassy carbon composite materials. Woodceramics attracted a lot of attention in recent years because they are environmentally friendly and because of their unique functional characteristics such as catalysis, moisture absorption, deodorization, purification, carrier for microbial activity, specific stiffness, corrosion and friction resistance, and their electromagnetic shielding capacity. In this paper, we made new products of clay-woodceramics to investigate the industrial analysis and ethylene gas adsorption for basic data of building- and packging- materials keeping fruit fresh for a long time. Clay-woodceramics were carbonized for 3 h of heating in a special furnace under a gas flow of nitrogen(15 ml/min.) from 3 layers-clay-woodparticleboard made from pallet waste wood, phenol- formaldehyde resin(hereafter PF, Non volatile content:52%, resin content 30%), and clay(10%, 20% and 30%). Carbonization temperature was 400℃, 600℃ and 800℃. Experimental results shows that the higher the carbonization temperature, the higher the fixed carbon and the lower the volatile contents. The higher the clay content, the more the ash content. The higher the carbonization temperature, the more the ethylene gas adsorption. Carbonization temperature of 800℃ gave the best reslts as same as that of white charcoal and activated carbon.(800℃-clay-woodceramic: 5.36 ppm, white charcoal: 5.66 ppm, activated carbon: 5.79 ppm) The clay contents did not make difference of ethylene gas adsoption.

Free vibration analysis of FGM plates using an optimization methodology combining artificial neural networks and third order shear deformation theory

  • Mohamed Janane Allah;Saad Hassouna;Rachid Aitbelale;Abdelaziz Timesli
    • Steel and Composite Structures
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    • v.49 no.6
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    • pp.633-643
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    • 2023
  • In this study, the natural frequencies of Functional Graded Materials (FGM) plates are predicted using Artificial Neural Network (ANN). A model based on Third-order Shear Deformation Theory (TSDT) and FEM is used to train the ANN model. Different training methods are tested to simulate input and output dependency. As this is a parametric model, several architectures and optimization algorithms were tested. The proposed model allows us to minimize the CPU time to evaluate candidate material properties for FGM plate material selection and demonstrate their influence on dynamic behavior. Consequently, the time required for the FGM design process (candidate materials for material selection) and the geometric optimization of the FGM structure would remain reasonable. The ANN model can help industries to produce FGM plates with good mechanical properties of the selected materials. I addition, this model can be used to directly predict vibration behavior by testing a large number of FGM plates, representing all possible combinations of metals and ceramics in today's industry, without having to solve any eigenvalue problems.

Preparation of Co3O4/NF Anode for Lithium-ion Batteries

  • Tian, Shiyi;Li, Botao;Zhang, Bochao;Wang, Yang;Yang, Xu;Ye, Han;Xia, Zhijie;Zheng, Guoxu
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.384-391
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    • 2020
  • Due to its characteristics of light weight, high energy density, good safety, long service life, no memory effect, and environmental friendliness, lithium-ion batteries (LIBs) are widely used in various portable electronic products. The capacity and performance of LIBs largely depend on the performance of electrode materials. Therefore, the development of better positive and negative materials is the focus of current research. The application of metal organic framework materials (MOFs) derivatives in energy storage has attracted much attention and research. Using MOFs as precursors, porous metal oxides and porous carbon materials with controllable structure can be obtained. In this paper, rod-shaped Co-MOF-74 was grown on Ni Foam (NF) by hydrothermal method, and then Co-MOF-74/NF precursor was heat-treated to obtain rodshaped Co3O4/NF. Ni Foam was skeleton structured, which effectively relieved. The change of internal stress changes and destroys the structural volume of the electrode material and reduces the capacity attenuation. Co3O4/NF composite material has a specific discharge capacity of up to 1858 mA h/g for the first time, and a reversible capacity of up to 902.4 mA h/g at a current density of 200 mA/g, and has excellent rate and impedance performance. The synthesis strategy reported in this article opens the way to design high-performance electrodes for energy storage and electrochemical catalysis.

Development of Hydrogel Containing Catechin for Wound Dressing (카테킨이 함유된 창상피복제용 하이드로젤의 개발)

  • Kim, Jin;Cho, Eun Bi;Lee, Ki-Young
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.462-469
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    • 2013
  • Catechin (CTEC) is well-known as a very powerful antioxidant, containing the effects of anti-inflammation and skin wound healing. In this study, CTEC/${\beta}$-cyclodextrin (${\beta}$-CD) nanoparticles were incorporated into poly(vinyl alcohol) (PVA)/pectin (PT) hydrogel. The composite was designed for the induction of re-epithelializaton in skin wound. CTEC/${\beta}$-CD nanoparticles were prepared by a molecular complex method. The size of the CTEC nanoparticles formed in the hydrogel was in the range of $250{\pm}17.5$ nm. The incorporation efficiency of CTEC in the nanoparticles was 74%. The cumulative amounts of CTEC released from the hydrogel containing CTEC nanoparticles in the buffers of pH7.4 and 5.5 were $86.51{\pm}3.14%$ and $35.95{\pm}2.14%$ of total CTEC loaded in the hydrogel within 72 h, respectively. Also, in the wound healing test, the CTEC nanoparticles-loaded PVA/PT hydrogel showed faster healing of the wound made in rat dorsum than the CTEC gel.