• 전기화학회지
• /
• 제7권4호
• /
• pp.201-205
• /
• 2004

본 연구에서는 Pt-Ru 촉매를 $H_2PtCI_6$ 및 $RuCl_3$ 용액을 화학적 환원에 의해 전도성 고분자인 폴리피롤을 중합시킨 Nafion 막위에 직접 침적시켰다 EDS 분석 결과 Pt 및 Ru 촉매는 Ppy/Nafion 표면에 주로 분포하는 것을 알 수 있었다. 또한 폴리피롤이 중합된 Nanon 위에 침적시킨 Pt-Ru 촉매의 메탄올에 대한 전기화학적 산화특성을 CV로 평가하였다. 메탄을 산화 개시 전위는 Ru촉매에 사용이 증가함에 따라 음전위 방향으로 전이되었다. 따라서 폴리피롤이 중합된 Nafion표면에 Pt-Ru촉매를 직접 함침할 수 있었고. 메탄올 산화 특성을 나타내는 전극을 제작할 수 있었다.

• 한국세라믹학회지
• /
• 제29권8호
• /
• pp.667-673
• /
• 1992

The alumina-zirconia composite powders of core particle ZrO2 coated with Al2O3 were prepared by the hydrolysis-deposition of the mixed aluminum salt solution of Al2(SO4)3-Al(NO3)3-Urea. The effects of hydrolysis reaction and coating parameters on characteristics of coated powders and composites were also investigated. The degree of coating could be estimated from the ratio of tetra-/mono-ZrO2 present at the room temperature after heat-treating coated powders at 120$0^{\circ}C$ and the result of TEM observations. When the content of ZrO2 in the dispersed coating system, the coating time, and the volume ratio of water/solution were 50 mg/g, 180 min, and 5, respectively the coating efficiency was maximum (the ratio of tetra-/mono-ZrO2 was 87/13). The relative densities of coated Al2O3-ZrO2 composites sintered at 1$650^{\circ}C$ for 4 hrs were about 91~98% and the maximum ratio of tetra-/mono-ZrO2 in Al2O3-20wt% ZrO2 composites was 62/38.

• Journal of Mechanical Science and Technology
• /
• 제18권7호
• /
• pp.1203-1212
• /
• 2004

The purpose of this study is to predict and understand the hydrodynamic forces and their nonlinear behaviors of fluid motion around the submerged plate oscillating near a free surface. To achieve this objective, we have developed a composite grid method for the solution of a radiation problem. The domain is divided into two different grids; one is a moving grid system and the other is a fixed grid system. The moving grid is employed for the body fitted coordinate system and moves with the body. This numerical method is applied to calculation of radiation forces generated by the submerged plate oscillating near a free surface. In order to investigate the characteristics of the radiation forces, the forced heaving tests have been performed with several amplitudes and different submergences near a free surface. These experimental results are compared with the numerical ones obtained by the present method and a linear potential theory. As a result, we can confirm the accuracy of the present method. Finally, the effect of nonlinear and viscous damping has been evaluated on the hydrodynamic forces acting on the submerged plate.

• Advances in materials Research
• /
• 제6권3호
• /
• pp.257-278
• /
• 2017

A simple closed-form solution to calculate the interfacial shear and normal stresses of retrofitted concrete beam strengthened with thin composite plate under mechanical loads including the creep and shrinkage effect has been presented in this paper. In such plated beams, tensile forces develop in the bonded plate, and these have to be transferred to the original beam via interfacial shear and normal stresses. Consequently, debonding failure may occur at the plate ends due to a combination of high shear and normal interfacial stresses. These stresses between a beam and a soffit plate, within the linear elastic range, have been addressed by numerous analytical investigations. Surprisingly, none of these investigations has examined interfacial stresses while taking the creep and shrinkage effect into account. In the present theoretical analysis for the interfacial stresses between reinforced concrete beam and a thin composite plate bonded to its soffit, the influence of creep and shrinkage effect relative to the time of the casting, and the time of the loading of the beams is taken into account. Numerical results from the present analysis are presented both to demonstrate the advantages of the present solution over existing ones and to illustrate the main characteristics of interfacial stress distributions.

• Journal of Industrial and Engineering Chemistry
• /
• 제68권
• /
• pp.173-179
• /
• 2018

Electrochemical characterization was conducted on poly(vinyl alcohol) (PVA)-ceramic composite (PVA-CC) separators for supercapacitor applications. The PVA-CC separators were fabricated by mixing various ceramic particles including aluminum oxide ($Al_2O_3$), silicon dioxide ($SiO_2$), and titanium dioxide ($TiO_2$) into a PVA aqueous solution. These ceramic particles help to create amorphous regions in the crystalline structure of the polymer matrix to increase the ionic conductivity of PVA. Supercapacitors were assembled using PVA-CC separators with symmetric activated carbon electrodes and electrochemical characterization showed enhanced specific capacitance, rate capability, cycle life, and ionic conductivity. Supercapacitors using the $PVA-TiO_2$ composite separator showed particularly good electrochemical performance with a 14.4% specific capacitance increase over supercapacitors using the bare PVA separator after 1000 cycles. With regards to safety, PVA becomes plasticized when immersed in 6 M KOH aqueous solution, thus there was no appreciable loss in tear resistance when the ceramic particles were added to PVA. Thus, the enhanced electrochemical properties can be attained without reduction in safety making the addition of ceramic nanoparticles to PVA separators a cost-effective strategy for increasing the ionic conductivity of separator materials for supercapacitor applications.

• 대한소아치과학회지
• /
• 제51권3호
• /
• pp.197-207
• /
• 2024

This study aims to evaluate the color stability and surface roughness of the single-shade composite resin after finishing and polishing for primary molars. A single-shade composite resin (OM, OMNICHROMA) and two multi-shade composite resins (FT, Filtek^TM Z350XT; ES, ESTELITE^® SIGMA QUICK) were included. The specimens were divided into three subgroups using different polishing methods: control, Sof-Lex XT, and Sof-Lex Diamond. For color stability tests, cavities were prepared on extracted primary second molars and restored with experimental composite resins. Each specimen was immersed in the coffee solution for 48 hours. The color difference of each specimen was calculated. For surface roughness tests, cylindrical specimens were crafted with experimental composite resins. Surface roughness was analyzed using an atomic force microscope and a scanning electron microscope. In the color stability tests, FT demonstrated a significantly lower ΔE_ab than ES among the control groups, but no significant differences were observed between the ΔE_ab values of OM and FT or OM and ES. Additionally, no significant differences were found between the Sof-Lex XT and Sof-Lex Diamond subgroups in the three composite groups. Moreover, no significant differences in the surface roughness were found between the three composite groups, regardless of the polishing methods. The single-shade composite resin demonstrated comparable color stability and surface roughness to that of the multi-shade composite resins regardless of the polishing methods used in restoring primary molars. The single-shade composite resin is expected to be applicable in clinical pediatric dentistry reducing chair time due to the easy shade matching procedures.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
• /
• pp.151-154
• /
• 2002

The durability of two kinds of CFRP plates, carbon/UP and carbon/V, was studied under severe environmental conditions. Immersion into the chemical solutions and accelerated weathering were executed on the CFRP plates and the weight change under each condition was measured. After those treatments, the plates were tested by tensile testing machine to measure the mechanical properties and observed by SEM to find the damage behaviour of the surface. Comparing the virgin plates and the chemically exposed plates, both plates show severe deterioration of the mechanical properties. But, the plates subjected to alkali solution show much larger reduction than those of acidic solution and carbon/V has better chemical resistance than carbon/UP. The material properties of CFRP plate exposed to the weathering were deteriorated linearly proportional to the exposure time.

• 한국세라믹학회지
• /
• 제30권10호
• /
• pp.811-818
• /
• 1993

Al2O3/ZrO2-Spinel composites were prepared by infiltrating magnesium sulfate solution into the porous preform made from Al2O3-20wt% ZrO2 composite powders derived through an emulsion route. The microstructure and composition of the modified composites could be controlled by manipulating the presingtering temperature of the preform, infiltration time, and so on. It was found that spinel phases were concentrated near the surface than in the interior of the Al2O3/ZrO2-Spinel composites infiltrated for 6hrs, while spinel phases were uniformly distributed in the comosites infiltrated for 2 days. The relative density and fracture toughness of the composite infiltrated for 6 hrs were 98.6% and 7.2MN/m3/2, respectively.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2001년도 추계학술발표대회 논문집
• /
• pp.163-169
• /
• 2001

The solution of two-dimensional deflection of circular wavy reinforcing fiber elastics was obtained for one end clamped boundary under concentrated load condition. The fiber was regarded as a linear elastic material. Wavy shape was described as a combination of half-circular arc smoothly connected each other with constant curvature of all the same magnitude and alternative sign. Also load direction was taken into account. As a result, the solution was expressed in terms of a series of elliptic integrals. These elliptic integrals had two different transformed parameters involved with load value and initial radius of curvature. While we found the exact solutions and expressed them in terms of elliptic integrals, the recursive ignition formulae about the displacement and arc length at each segment of circular section were obtained. Algorithm of determining unknown parameters was established and the profile curve of deflected beam was shown in comparison with initial shape.

• 한국소음진동공학회논문집
• /
• 제19권5호
• /
• pp.537-544
• /
• 2009

In order to increase the critical speed of rotating disks of which functional material could not be changed such as in optical and magnetic data storage disks, a new disk with a rim reinforced by composite material is proposed and its concept is verified by numerical analysis. Stress distributions are found for the rotating disk composed of two annular disks of which materials are isotropic inside and orthotropic outside. Dynamic equation is formulated in order to calculate the natural frequency and critical speed. For the solution of lateral vibration, a rotational symmertry condition is applied along circumferential direction and a finite element interpolation with Hermite polynomial is performed along the radial direction to obtain a proper solution. According to the results, reinforcing a disk at rim makes critical speeds drastically increased, and induces a buckling phenomenon in mode (0,0) which occurs over the lowest critical speed.