• Title/Summary/Keyword: Composite Membrane

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Separation of $H_2$ and $N_2$ Gases by PTMSP-NaY Zeolite Composite Membranes (PTMSP-NaY Zeolite 복합막에 의한 수소-질소 기체 분리에 관한 연구)

  • Kim, Ok-Su;Hong, Se Ryeong
    • Membrane Journal
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    • v.24 no.4
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    • pp.285-291
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    • 2014
  • The PTMSP[Poly(1-trimethylsilyl-1-propyne)]-NaY zeolite composite membranes were prepared by adding 0~50 wt% NaY zeolite to PTMSP. In order to investigate the characteristics of these membranes, we used the analytical methods such as FT-IR, $^1H$-NMR, GPC, DSC, TGA, and SEM. Gas permeation experiments were carried out at $23{\sim}26^{\circ}C$, $2kgf/cm^2$, and the permselectivity of $H_2$ and $N_2$ gases through the composite membranes was studied as a function of the NaY zeolite contents. According to TGA measurements, when NaY zeolite was inserted within the PTMSP, thermal stability of PTMSP was enhanced. Based on SEM observation, NaY zeolite was dispersed in the PTMSP-NaY zeolite composite membrane with a size of $1.5{\mu}m$. The permeability of $H_2$ and $N_2$ through the PTMSP-NaY zeolite composite membranes increased as NaY zeolite content increased. On the contrary, the selectivity($H_2/N_2$) of the PTMSP-NaY zeolite composite membranes decreased as zeolite content increased.

Transport Coefficients across Charged Mosaic Membrane

  • Yang, Wong-Kang
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.665-667
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    • 2004
  • In previous studies, charged mosaic membranes having two different fixed charges in the membrane matrix indicated unique transport behavior such as preferential material transport. In this study, the composite charged mosaic membrane endurable to mechanical pressure in practical application was investigated from the same aspect of solute and solvent transport as before. Lp and ${\omega}$ estimated by taking account of active layer thickness were satisfactorily consistent with those in mosaic membrane without reinforcement. On the other hand, the reflection coefficient s indicated the negative value that suggests preferential material transport.

Separation of Organic Liquid Mixtures using Plasma Membrane (플라즈마 멤브레인을 이용한 유기용매 혼합을 분리)

  • 김성오;박복기;김두석;박진교;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.642-644
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    • 1999
  • We have prepared the plasma-polymerized membrane for pervaporation of organic-liquid mixtures by the plasma polymerization technique. Plasma polymerization techniques were utilized in the development of hydrophilic composite membranes having high hydrogen ion permeability and excellent dimensional stability. To develop an organic liquid permselective Membrane, suppressing membrane swearing as well as enhancing the solubility difference is impotant. the objectives of the present study are to disign a suitable membrane for an organic-mixture system by the control of the plasma-polymer solubility.

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Study on Simultaneous Material Transport through Charged Mosaic Membrane

  • Myeongkwan Song;Lee, Jang-Oo;Akira Yamauchi;Wongkang Yang
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.109-112
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    • 2004
  • The charged mosaic membranes having cation and anion exchange mixed groups within membrane were researched. The composite charged mosaic membrane was investigated from simultaneous transport such as solute and solvent flux. On the other hand, the reflection coefficient and salt flux coefficient were estimated by taking account of the cross constants of the phenomenological equation.(omitted)

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Hydrogen Permeation of SiC-CeO2 Composite Membrane by Dip-coating Process

  • Park, Jihye;Jung, Miewon
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.485-488
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    • 2013
  • A SiC-$CeO_2$ composite membrane was successfully fabricated using an ally-hydridopolycarbosilane (AHPCS) binder and treated by dip-coating at 60 times with a $CeO_2$ sol solution. The dip-coated SiC membrane was calcined at 773 K and then sintered at 1173 K under an air atmosphere. The coated membrane was characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and a BET surface analysis. The difference in permeation performance between $H_2$ and CO gases was measured by varying the temperature. The permeation flux of $H_2$ on the SiC membrane with layered $CeO_2$ was obtained as $8.45{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The CO permeation flux was $2.64{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The reaction enthalpy (${\Delta}H^{\circ}$) for the hydrogen permeation process was calculated as -7.82 J/mol by Arrhenius plots.