• Title/Summary/Keyword: Composite Degree

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Effect of moisture and drying time on the bond strength of the one-step self-etching adhesive system

  • Lee, Yoon;Park, Jeong-Won
    • Restorative Dentistry and Endodontics
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    • v.37 no.3
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    • pp.155-159
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    • 2012
  • Objectives: To investigate the effect of dentin moisture degree and air-drying time on dentin-bond strength of two different one-step self-etching adhesive systems. Materials and Methods: Twenty-four human third molars were used for microtensile bond strength testing of G-Bond and Clearfil $S^3$ Bond. The dentin surface was either blot-dried or air-dried before applying these adhesive agents. After application of the adhesive agent, three different air drying times were evaluated: 1, 5, and 10 sec. Composite resin was build up to 4 mm thickness and light cured for 40 sec with 2 separate layers. Then the tooth was sectioned and trimmed to measure the microtensile bond strength using a universal testing machine. The measured bond strengths were analyzed with three-way ANOVA and regression analysis was done (p = 0.05). Results: All three factors, materials, dentin wetness and air drying time, showed significant effect on the microtensile bond strength. Clearfil $S^3$ Bond, dry dentin surface and 10 sec air drying time showed higher bond strength. Conclusions: Within the limitation of this experiment, air drying time after the application of the one-step self-etching adhesive agent was the most significant factor affecting the bond strength, followed by the material difference and dentin moisture before applying the adhesive agent.

A simplified seismic design method for low-rise dual frame-steel plate shear wall structures

  • Bai, Jiulin;Zhang, Jianyuan;Du, Ke;Jin, Shuangshuang
    • Steel and Composite Structures
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    • v.37 no.4
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    • pp.447-462
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    • 2020
  • In this paper, a simplified seismic design method for low-rise dual frame-steel plate shear wall (SPSW) structures is proposed in the framework of performance-based seismic design. The dynamic response of a low-rise structure is mainly dominated by the first-mode and the structural system can be simplified to an equivalent single degree-of-freedom (SDOF) oscillator. The dual frame-SPSW structure was decomposed into a frame system and a SPSW system and they were simplified to an equivalent F-SDOF (SDOF for frame) oscillator and an equivalent S-SDOF (SDOF for SPSW) oscillator, respectively. The analytical models of F-SDOF and S-SDOF oscillators were constructed based on the OpenSees platform. The equivalent SDOF oscillator (D-SDOF, dual SDOF) for the frame-SPSW system was developed by combining the F-SDOF and S-SDOF oscillators in parallel. By employing the lateral force resistance coefficients and seismic demands of D-SDOF oscillator, the design approach of SPSW systems was developed. A 7-story frame-SPSW system was adopted to verify the feasibility and demonstrate the design process of the simplified method. The results also show the seismic demands derived by the equivalent dual SDOF oscillator have a good consistence with that by the frame-SPSW structure.

Critical buckling analyses of nonlinear FG-CNT reinforced nano-composite beam

  • Zerrouki, Rachid;Karas, Abdelkader;Zidour, Mohamed
    • Advances in nano research
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    • v.9 no.3
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    • pp.211-220
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    • 2020
  • This paper investigates the effect of linear and non-linear distribution of carbon nanotube volume fraction in the FG-CNTRC beams on the critical buckling by using higher-order shear deformation theories. Here, the material properties of the CNTRC beams are assumed to be graded in the thickness direction according to a new exponential power law distribution in terms of the carbon nanotube volume fractions. The single-walled carbon nanotube is aligned and distributed in the polymeric matrix with different patterns of reinforcement; the material properties of the CNTRC beams are described by using the rule of mixture. The governing equations are derived through using Hamilton's principle. The Navier solution method is used under the specified boundary conditions for simply supported CNTRC beams. The mathematical models provided in this work are numerically validated by comparison with some available results. New results of critical buckling with the non-linear distribution of CNT volume fraction in different patterns are presented and discussed in detail, and compared with the linear distribution. Several aspects of beam types, CNT volume fraction, exponent degree (n), aspect ratio, etc., are taken into this investigation. It is revealed that the influences of non-linearity distribution in the beam play an important role to improve the mechanical properties, especially in buckling behavior. The results show that the X-Beam configuration is the strongest among all different types of CNTRC beams in supporting the buckling loads.

Poly(vinylbenzyl chloride-glycidyl methacrylate)/Polyethylene Composite Anion Exchange Membranes for Vanadium Redox Battery Application

  • Park, Min-A;Shim, Joonmok;Park, Se-Kook;Jeon, Jae-Deok;Jin, Chang-Soo;Lee, Ki Bong;Shin, Kyoung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1651-1655
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    • 2013
  • Anion exchange membranes for a vanadium redox flow battery (VRB) were prepared by pore-filling on a PE substrate with the copolymerization of vinylbenzyl chloride (VBC) and glycidyl methacrylate (GMA). The ion exchange capacity, water uptake and weight gain ratio were increased with a similar tendency up to 65% of GMA content, indicating that the monomer improved the pore-filling degree and membrane properties. The vanadium ion permeability and open-circuit voltage were also investigated. The permeability of the VG65 membrane was only $1.23{\times}10^{-7}\;cm^2\;min^{-1}$ compared to $17.9{\times}10^{-7}\;cm^2\;min^{-1}$ for Nafion 117 and $1.8{\times}10^{-7}\;cm^2\;min^{-1}$ for AMV. Consequently, a VRB single cell using the prepared membrane showed higher energy efficiency (over 80%) of up to 100 cycles compared to the commercial membranes, Nafion 117 (ca. 58%) and AMV (ca. 70%).

Synthesis of conducting and magnetic nanocomposite of cross-linked aniline sulfide resin

  • Hosseini, Seyed Hossein
    • Advances in materials Research
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    • v.3 no.4
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    • pp.233-242
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    • 2014
  • Magnetic and conducting aniline sulfide resin cross-linked (ASC-Fe3O4) nanocomposite has been prepared in the presence of aniline sulfide resin (ASR), aniline, $Fe_3O_4$ coated by polyethylene glycol (PEG) and initiator. The magnetic properties of the resulting composites showed ferromagnetic behavior, such as high-saturated magnetization (Ms= 41 emu/g), and coercive force (Hc=1.5 Oe). The saturated magnetization was increased by increasing of $Fe_3O_4$ content and decreased by increasing aniline ratio. The transmission electron micrograph (TEM) and X-ray diffraction proved that nanometer-sized about 20-30 nm $Fe_3O_4$ in the composite. The average size of ASC-$Fe_3O_4$ nanocomposite with core-shell structure was about 50-60 nm, and polydisperse. This approach may also be extended to the synthesis and modification of other polymers. Electrical conductivity of aniline sulfide resin cross-linked (ASC) nanocomposite has been studied by four-point probe method and produced $3.3{\times}10^{-4}S/cm$ conductivity for it. The conductivity of the composites at room temperature depended on the $Fe_3O_4$, aniline ratio and doping degree. The thermogravimetry analysis (TGA) results showed that this resin is thermal resistance near of $500^{\circ}C$. So, It can be used for resistance thermal coating for military applications. $Fe_3O_4$-PASC nanocomposite has been flexible structure with electrical and magnetic properties.

A Novel Route to Realise High Degree of Graphitization in Carbon-carbon Composites Derived from Hard Carbons

  • Mathur, R.B.;Bahl, O.P.;Dhami, T.L.;Chauhan, S.K.
    • Carbon letters
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    • v.4 no.3
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    • pp.111-116
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    • 2003
  • Carbon/carbon composites were developed using PAN based carbon fibres and phenolic resin as matrix in different volume fractions and heat treated to temperatures between $1000^{\circ}C$ to $2500^{\circ}C$. Although both the starting precursors are nongraphitizing hard carbons individually, their composites lead to very interesting properties e.g. x-ray diffractograms show the development of graphitic phase for composites having fibre volume fractions of 30~40%. Consequently the electrical resistivity of such composites reaches a value of $0.8\;m{\Omega}cm$, very close to highly graphitic material. However, it was found that by increasing the fibre volume fraction to 50~60%, the trend is reversed. Optical microscopy of the composites also reveals the development of strong columnar type microstructure at the fibre (matrix interface due to stress graphitization of the matrix. The study forcasts a unique possibility of producing high thermal conductivity carbon/carbon composites starting with carbon fibres in the chopped form only.

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The Impact of the Knowledge Management Strategic Alignment on the Innovation of Manufacturing Firms (기업전략과 지식경영 전략의 연계가 제조기업의 혁신에 미치는 영향)

  • Choe, Jong-Min
    • Journal of the Korean Operations Research and Management Science Society
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    • v.36 no.2
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    • pp.67-88
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    • 2011
  • This study empirically investigated the effects of knowledge management(KM) strategic alignment on the KM activities as well as the product and process innovation of manufacturing firms. Based on the framework, which employs the usage levels of target costing systems(TCS) and information technology(IT) infrastructure, four types of KM strategies were identified and proposed:mixed, explorative, exploitative and negative strategies. In this research, these four types of KM strategies were empirically validated. According to the results of this study, it was found that when a explorative KM strategy is aligned with a low-cost strategy, KM activities are activated and the degree of a process innovation is increased. It was observed that in the case of the alignment between a differentiation strategy and a exploitative KM strategy, both KM activities and the level of a product innovation are enhanced. The results also demonstrated that for the enhancement of both a process and a product innovation through the activation of KM activities, a mixed KM strategy must be aligned with a composite business strategy, which focuses on a low-cost as well as a differentiation strategies. Accordingly, it is concluded that the KM activities and the levels of the product and process innovation can be activated or improved with the alignment of the KM strategies and business strategies.

Fabrication of Porous Cu-Ni by Freeze Drying and Hydrogen Reduction of CuO-NiO Powder Mixture (CuO-NiO 혼합분말의 동결건조 및 수소환원에 의한 Cu-Ni 다공체 제조)

  • Seo, Han Gil;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.21 no.1
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    • pp.34-38
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    • 2014
  • Cu-Ni alloys with unidirectionally aligned pores were prepared by freeze-drying process of CuO-NiO/camphene slurry. Camphene slurries with dispersion stability by the addition of oligomeric polyester were frozen at $-25^{\circ}C$, and pores in the frozen specimens were generated by sublimation of the camphene during drying in air. The green bodies were hydrogen-reduced at $300^{\circ}C$ and sintered at $850^{\circ}C$ for 1 h. X-ray diffraction analysis revealed that CuO-NiO composite powders were completely converted to Cu-Ni alloy without any reaction phases by hydrogen reduction. The sintered samples showed large and aligned parallel pores to the camphene growth direction, and small pores in the internal wall of large pores. The pore size and porosity decreased with increase in CuO-NiO content from 5 to 10 vol%. The change of pore characteristics was explained by the degree of powder rearrangement in slurry and the accumulation behavior of powders in the interdendritic spaces of solidified camphene.

Synthesis of Inorganic/Organic Core-Shell Polymer (무기/유기 Core-Shell 에멀젼 고분자의 합성)

  • Kim, Nam-Seok;Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.4
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    • pp.265-272
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    • 2002
  • $CaCO_{3}$ absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when $CaCO_{3}$; core prepared by adding 2,0 wt% SLS, $CaCO_{3}$ core/PSt shell polymerization was carried out on the surface of $CaCO_{3}$ particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of $CaCO_{3}$ using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

Spray Drying of Zirconia/Alumina Composite Powder Using PVP as a Binder (PVP 결합제를 이용한 지르코니아/알루미나 복합분말의 분무건조)

  • Shim, Hyung-Bo;Moon, Joo-Ho;Kim, Dae-Joon
    • Journal of the Korean Ceramic Society
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    • v.39 no.5
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    • pp.446-451
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    • 2002
  • Zirconia/alumina mixture powder was spray-dried various degree of dispersion, type of dispersants and powder content in the slurry. The quality of the granule was determined by observation of the granule shapes after spray drying and fracture of intergranular boundaries during pressing. Defect-free granules were obtained from the powders that formed weak flocs in the slurry. The granules, spray-dried from the slurry containing 32.5 vol% powder mixture and PVP as binder, were fractured completely during shaping and the sintered specimens showed a density of 99.7% and a flexural strength of 850 MPa.