• Title/Summary/Keyword: Component materials

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Diffusion Behaviors of B and P at the Interfaces of Si/$SiO_2$ Multilayer System After the Annealing Process

  • Jang, Jong-Shik;Kang, Hee-Jae;Hwang, Hyun-Hye;Kim, Kyung-Joong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.232-232
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    • 2012
  • The doping of semiconducting elements is essential for the development of silicon quantum dot (QD) solar cells. Especially the doping elements should be activated by substitution at the crystalline sites in the crystalline silicon QDs. However, no analysis technique has been developed for the analysis of the activated dopants in silicon QDs in $SiO_2$ matrix. Secondary ion mass spectrometry (SIMS) is a powerful technique for the in-depth analysis of solid materials and the impurities analysis of boron and phosphorus in semiconductor materials. For the study of diffusion behaviour of B and P by SIMS, Si/$SiO_2$ multilayer films doped by B or P were fabricated and annealed at high temperatures for the activated doping of B and P. The distributions of doping elements were analyzed by SIMS. Boron found to be preferentially distributed in Si layer rather than the $SiO_2$ layer. Especially the B in the Si layers was separated to two components of an interfacial component and a central one. The central component was understood as the activated elements. On the other hand, phosphorus did not show any preferred diffusion.

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Crytal Structure Study of Random Copolymers by CPMAS Solid-State NMR Spectrosecopy (고체상태에서의 CPMAS NMR분광법을 이용한 랜덤 공중합체의 결정구조 연구)

  • Yoo, Hee-Yeoul;Shim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.3 no.4
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    • pp.344-351
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    • 1993
  • The crystal structunes of poly(ethylene terephthalate-eo-1, 4 cyciohexylene dimethylene terephthalate), P(ET CT), copolymers were studied by CPMAS solid state NMR spectroscopy. With the estimation of methylene resonance peaks, the bulkier CT component of the copolymer in the range of 0 20 mol% CT is excluded from the ET crystal lattice, whereas smaller ET component of the copolymer in the range of 66 100 mol% CT can be partially included into the CT crystal lattice. Those different crystallization behavior can be explained with the difference in chain bulkiness and crystal lattice dimension be tween two copolymer compurwnts.

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Surface Modification of Cellulose Acetate using $UV/O_3$ Irradiation

  • Lee, Hae-Sung;Jeong, Yong-Kyun;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.35-41
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    • 2006
  • Upon $UV/O_3$ irradiation cellulose acetate (CA) films showed modified surface properties such as increased hydrophilicity and surface roughness as well as increased dyeability to cationic dyes. UV treatment induced photoscission of acetyl groups in the main chain of CA resulting in decreased degree of substitution from 2.2 to 1.3. The slight decreases in reflectance and transmittance were caused by remarkably increased nano-scale surface roughness of the CA surface as much as 20-fold, which can destructively interfere with visible lights of wavelength lower thu 500nm. Water contact angle decreased from $54^{\circ}\;to\;14^{\circ}$ with increasing UV energy. Surface energy also increased slightly. The surface energy change was attributed to significant contribution of polar component rather than nonpolar component indicating surface photooxidation of CA film. The increased dyeability to cationic dyes in terms of both K/S and %E may be due to photochemically introduced anionic and dipolar dyeing sites on the film surfaces.

A Study on the Operating Characteristics of Commercial Frequency Plasma Jet Torch (상용 주파수 (60Hz) Plasma Jet Torch의 동작특성에 관한 연구)

  • 전춘생;정재웅
    • 전기의세계
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    • v.24 no.1
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    • pp.75-85
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    • 1975
  • In order to develop the commercial frequency (60Hz) plasma torch of small capacity for material cutting, welding and other industrial heating, the A.C plasma jet generator of non-transfered type is made domestically and the electrode configurations of plasma torch are composed of two kinds of electrodes W-C and W-Cu, combined by thermal emission and field emission electrode materials. In this paper, the characteristics of input power, thermal efficiency, electrode consumption, the flame and forms of arc voltage and arc current for A.C plasma torch are investigated in relation to such variables as arc current, argon flow and magnetic field intensity to obtain the basic design data necessary to A.C plasma jet generator. The result are as follows; (1)The input power, thermal efficiency and electrode consumption are influenced greatly by argon flow, magnetic field intensity and nozzle materials. (2)A.C arc voltage and current are non-symmetrial, involving D.C Component. Due to this current of D.C Component, transformer core is saturated and a large abnormal current flows into the primary winding coil. In order to prevent this abnormal current flow, a condenser must be connected in series to the main discharge circuit. (3)The stability and sharpness of jet flame are improved more in the torch of W-C electrode configuration than in the torch of W-Cu electrode configuration.

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A Study on the Dynamic Stress Intensity Factor of Orthotropic Materials(I) (직교 이방성체의 동적 응력확대계수에 관한 연구(I))

  • 이광호;황재석;최선호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.2
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    • pp.313-330
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    • 1993
  • The propagating crack problems under dynamic plane mode in orthotropic material is studied in this paper. To analyze the dynamic fracture problems in orthortropic material, it is important to know the dynamic stress components and dynamic displacement components around the crack tip. Therefore the dynamic stress components of dynamic stress field and dynamic displacement components of dynamic displacement field in the crack tip of orthotropic material under the dynamic load and the steady state in crack propagation were derived. When the crack propagation speed approachs to zero, the dynamic stress component and dynamic displacement components derived in this study are identical to the those of static state. In addition, the relationships between dynamic stress intensity factor and dynamic energy release rate are determinded by using the concept of crack closure closure energy with the dynamic stresses and represented according to physical properties of the orthotrophic material and crack speeds. The faster the crack velocity, the greater the stress value of stress components in crack tip. The stress value of the stress component of crack tip is greater when fiber direction coincides with the crack propagation than when fider direction is normal to the crack propagation.

Synthesis and Flame Retardant Improvement of PU Coatings Containing Trichloro Modified Polyester/IPDI-Isocyanurate

  • Kim, Ji-Hyun;Keun, Jang-Hyoun;Jung, Choong-Ho;Kim, Seung-Jin;Kim, Young-Geun;Kim, Seong-Kil;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.332-340
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    • 2008
  • Two component polyurethane (PU) flame retardant coatings were prepared by blending trichloro modified polyesters (TCMPs) and isophorone diisocyanate isocyanurate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid (TCBA), a flame retardant component, with adipic acid, 1,4 butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. Theses new flame retardant coatings showed various properties comparable to other non flame retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as no burn. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index (LOI) values of 26% and 29% respectively, which implied relatively good flame retardancy.

A.C. Impedance Properties on $RuO_2$-Based Thick Film Resistors. ($RuO_2$계 후막저항체의 교류 임피던스특성)

  • Koo, Bon-Keup;Kim, Ho-Gi
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.215-220
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    • 1990
  • A.C. impedance properties of $RuO_2$ based thick film resistors which having different resistivity value (DuPont 1721 : $100{\Omega}$/ sq., 1741 : $10K{\Omega}$/sq.) were investigated using by impedance analyzer. In case of lower resistivity 1721 system, the complex impedance was composed nearly R component for all speciman sintered at above $600^{\circ}C$, and the frequency dependancy on impedance was not affected very much up to 5MHz and again gradually increase with increasing the frequency. In case of higher resistivity 1741 resistor system, impedance properties were very depandant on sintering temperature. When sintering temperature was $600^{\circ}C$, the complex impedance plot shows a vertical line, which correspond to lone capacitance equivalant circuit, and the impedance linearly decreased with increasing frequency. In case of speciman sintered at $700-900^{\circ}C$, the complex impedance plot shows semi-circular are correspond to a lumped RC combination, and the impedance shows constant value to 5MHz, again decreased with increasing frequency. But the complex impedance behavior of speciman sintered at $1000^{\circ}C$ was shows the equivalent circuit correspont to parallel combined LCR component, and the impedance was not varied with frequency.

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Respondence Between Electrochemicl Fluctuations and Phenomenon for Localized Corrosion of Less-Noble Metals

  • Itoi, Yasuhiko;Take, Seisho;Tsuru, Tooru
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.35-39
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    • 2008
  • We have been studying application of electrochemical noise (Fluctuation) analysis for localized corrosion. Foils of Zinc, Aluminum and Magnesium were used as specimens for electrochemical cell simulating localized corrosion. These specimens were dipped in sodium chloride solutions adjusted to each exponent of Hydrogen ion concentration (pH) condition of 5.5, 10, 12 respectively. Time variations of potential and current were measured in those solutions, and simultaneously the surfaces of specimens were observed using microscope with television monitor. Two types of electrochemical cells were arranged for experiments simulated localized corrosion. The fluctuations on trendy component of short-circuited potential and short-circuited current were appeared in synchronization. It was seemed that these fluctuations result from hydrogen evolution on the aluminum active site in the crevice from the microscopic observation. In the case of zinc and magnesium, fluctuations appeared on the trendy component of the corrosion potential. Two types fluctuation were detected. First one is the fluctuation varied periodically. The second one is the random fluctuation. It was seemed that these fluctuations result from generation of corrosion products and hydrogen evolution on the active site in the crevice of zinc and magnesium from the microscopic observation.

Synthesis of Silicone Softner for Permanent Press Finish and Its Characterization (Permanent Press 가공용 실리콘 유연제의 합성과 그의 특성화)

  • Park, Chang-Hwan;Kim, Seung-Jin;Kim, Young-Geun;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.29-34
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    • 1995
  • Silicone softner(SSN-3) for permanent press(PP) finish was prepared by blending beef tallow hardened oil for Improving softness, water, the emulsion, which was synthesized from pentaerythritol monostearate as a softening component and silicone oil KF-96 as a lubricating component. The prepared SSN-3 and the PP finishing resin were applied to PP finishing cotton broad cloth and P/C gingham samples using one bath method. The properties such as crease recovery, tear strength, bending resistance test were tested. The samples treated with SSN-3 and PP finishing resin have improved properties, compared with nontreated samples, those treated only with PP finishing resin, those treated with commercial PP finishing softners and PP finishing resin. Also from the bending resistance test, the two kinds of fabric samples treated with SSN-3 of 3% showed grade 5 and these were good enough in feeling.

Near-infrared studies of iron knots in Cassiopeia A supernova remnant: I. Spectral classification using principal component analysis

  • Lee, Yong-Hyun;Koo, Bon-Chul;Moon, Dae-Sik;Burton, Michael G.
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.1
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    • pp.49.1-49.1
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    • 2013
  • We have been carrying out near-infrared (NIR) spectroscopy as well as [Fe II] narrow band imaging observations of Cassiopeia A supernova remnant (SNR). In this presentation, we describe the spectral classification of the iron knots around the SNR. From eight long-slit spectroscopic observations for the iron-bright shell, we identified a total of 61 iron knots making use of a clump-finding algorithm, and performed principal component analysis in an attempt to spectrally classify the iron knots. Three major components have emerged from the analysis; (1) Iron-rich, (2) Helium-rich, and (3) Sulfur-rich groups. The Helium-rich knots have low radial velocities (${\mid}v_r{\mid}$ < 100 km/s) and radiate strong He I and [Fe II] lines, that match well with Quasi-Stationary Flocculi (QSFs) of circumstellar medium, while the Sulfur-rich knots show strong lines of oxygen burning materials with large radial velocity up to +2000 km/s, which imply that they are supernova ejecta (i.e. Fast-Moving Knots). The Iron-rich knots have intermediate characteristics; large velocity with QSF-like spectra. We suggest that the Iron-rich knots are missing "pure" iron materials ejected from the inner most region of the progenitor and now encountering the reverse shock.

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