• Title/Summary/Keyword: Complex transfer center

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Eco-Friendly Light Emitting Diodes Based on Graphene Quantum Dots and III-V Colloidal Quantum Dots

  • Lee, Chang-Lyoul
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.65-65
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    • 2015
  • In this talk, I will introduce two topics. The first topic is the polymer light emitting diodes (PLEDs) using graphene oxide quantum dots as emissive center. More specifically, the energy transfer mechanism as well as the origin of white electroluminescence in the PLED were investigated. The second topic is the facile synthesis of eco-friendly III-V colloidal quantum dots and their application to light emitting diodes. Polymer (organic) light emitting diodes (PLEDs) using quantum dots (QDs) as emissive materials have received much attention as promising components for next-generation displays. Despite their outstanding properties, toxic and hazardous nature of QDs is a serious impediment to their use in future eco-friendly opto-electronic device applications. Owing to the desires to develop new types of nanomaterial without health and environmental effects but with strong opto-electrical properties similar to QDs, graphene quantum dots (GQDs) have attracted great interest as promising luminophores. However, the origin of electroluminescence (EL) from GQDs incorporated PLEDs is unclear. Herein, we synthesized graphene oxide quantum dots (GOQDs) using a modified hydrothermal deoxidization method and characterized the PLED performance using GOQDs blended poly(N-vinyl carbazole) (PVK) as emissive layer. Simple device structure was used to reveal the origin of EL by excluding the contribution of and contamination from other layers. The energy transfer and interaction between the PVK host and GOQDs guest were investigated using steady-state PL, time-correlated single photon counting (TCSPC) and density functional theory (DFT) calculations. Experiments revealed that white EL emission from the PLED originated from the hybridized GOQD-PVK complex emission with the contributions from the individual GOQDs and PVK emissions. (Sci Rep., 5, 11032, 2015). New III-V colloidal quantum dots (CQDs) were synthesized using the hot-injection method and the QD-light emitting diodes (QLEDs) using these CQDs as emissive layer were demonstrated for the first time. The band gaps of the III-V CQDs were varied by varying the metal fraction and by particle size control. The X-ray absorption fine structure (XAFS) results show that the crystal states of the III-V CQDs consist of multi-phase states; multi-peak photoluminescence (PL) resulted from these multi-phase states. Inverted structured QLED shows green EL emission and a maximum luminance of ~45 cd/m2. This result shows that III-V CQDs can be a good substitute for conventional cadmium-containing CQDs in various opto-electronic applications, e.g., eco-friendly displays. (Un-published results).

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Optimum design of injection mold heater for uniform curing of LSR seal for waterproof connector (방수 커넥터용 LSR Seal의 균일 경화를 위한 사출 금형 히터의 최적 설계)

  • Song, Min-Jae;Cha, Baeg-Soon;Hong, Seok-Kwan;Ko, Young-Bae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.7
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    • pp.310-315
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    • 2017
  • Automotive waterproof connectors are highly functional parts that must be air-tight in a complex environment. In the LSR multi-cavity injection molding process for manufacturing waterproof connectors, it is important to maintain a uniform curing temperature between the cavities in order to obtain a quality product. For this purpose, we designed the capacity of the cartridge heater differently for each position, and then linked the heat transfer analysis and optimization module to obtain the optimal cartridge heater capacity. As a result of the optimization analysis, the temperature deviation between cavities was decreased from $13.1^{\circ}C$ to $8.1^{\circ}C$ compared with the case in which constant heater capacity was applied, so that the design criterion could be satisfied within a temperature deviation of $10^{\circ}C$ for uniform curing. This study suggests that this method can be applied efficiently to the design of a large area multi-cavity LSR mold heater.

A study on the feasibility assessment model of urban utility tunnel by analytic hierarchy process (계층의사분석 기법을 적용한 도심지 공동구 타당성 평가모델 연구)

  • Chung, Jee-Seung;Na, Gwi-Tae
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.1
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    • pp.131-144
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    • 2018
  • The urban center of a large city has a high concentration ratio of population, commerce, and traffic. Therefore, the expected effect is high from the introduction of the urban utility tunnel and it also has sufficient economic feasibility considering life cycle cost. Moreover, the construction cost can be greatly reduced if it is included in a large underground development such as a subway or a complex transfer center construction. However, it is not reflected in actual underground development plan. When planning a urban utility tunnel in Korea, it is expected to have difficulties such as the cost of relocation of the existing Life-Line, conflicts among the individual facility institutions, procurement of construction resources and sharing. Furthermore, it is possible to promote the project only if a consensus is drawn up by a collective council composed of all facilities and project developers. Therefore, an optimal alternative should be proposed using economic analysis and feasibility assessment system. In this study, the analytic hierarchy process (AHP) is performed considering the characteristics of urban areas and the importance of each indicator is quantified. As a result, we can support reasonable design capacity optimization using the feasibility assessment system.

Three-Dimensional Finite Element Analysis for Comparison between Titanium Implant Abutment and Zirconia Implant Abutment (지르코니아 임플란트 지대주와 티타늄 임플란트 지대주의 삼차원적 유한요소응력분석)

  • Yun, Mi-Jung;Kim, Chang-Weop;Jeong, Chan-Mo;Seo, Seung-U
    • Journal of Dental Rehabilitation and Applied Science
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    • v.27 no.1
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    • pp.51-61
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    • 2011
  • Recently, restoring implants in the esthetically demanding region, zirconia-based materials are widely used due to their superior mechanical properties, accuracies, and esthetics. The purpose of this study was to investigate the load transfer and mechanical stability of zirconia and titanium implant abutments by using the three-dimensional finite element analysis model. The internal conical joint type and external butt joint type implant system was selected as an experimental model. Finite element models of bone/implant/prosthesis complex were constructed. An load of 250N was applied vertically beside 3mm of implant axis. Stress distribution of zirconia and titanium implant abutment is similar. The maximum equivalent stress of titanium implant abutment is lower than zirconia implant abutment about 15%. Howevere considering a high mechanical strength that exceed those of titanium implant abutment, zirconia implant abutment had similar mechanical stability of titanium implant abutment clinically.

Three-dimensional finite element analysis for influence of marginal bone resorption on stress distribution in internal conical joint type implant fixture (변연골 흡수가 내측연결 임플란트 매식체의 응력분포에 미치는 영향)

  • Yun, Mi-Jung;Yoon, Min-Chul;Eom, Tae-Gwan;Huh, Jung-Bo;Jeong, Chang-Mo
    • The Journal of Korean Academy of Prosthodontics
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    • v.50 no.2
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    • pp.99-105
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    • 2012
  • Purpose: The change of the marginal bone around dental implants have significance not only for the functional maintenance but also for the esthetic success of the implant. The purpose of this study was to investigate the load transfer of internal conical joint type implant according to marginal bone resorption by using the three-dimensional finite element analysis model. Materials and methods: The internal conical joint type system was selected as an experimental model. Finite element models of bone/implant/prosthesis complex were constructed. A load of 300 N was applied vertically beside 3 mm of implant axis. Results: The pattern of stress distribution according to marginal bone resorption was similar. The maximum equivalent stress of implant was increase according to marginal bone resorption and the largest maximum equivalent stress was shown at model of 1 mm marginal bone resorption. Although marginal bone loss more than 1mm was occurred increasing of stress, the width of the stress increase was decreasing. Conclusion: According to these results, the exposure of thin neck portion of internal conical joint type implant is most important factor in stress increasing.

Electrochemical Detection of Uric Acid using Three Osmium Hydrogels (세개의 오스뮴 고분자를 이용한 요산의 전기화학적 측정방법)

  • Jeon, Won-Yong;Choi, Young-Bong
    • Journal of the Korean Electrochemical Society
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    • v.19 no.2
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    • pp.29-38
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    • 2016
  • Screen printed carbon electrodes (SPCEs) with immobilized osmium-based hydrogel redox polymer, uricase and PEGDGE can be used to apply uric acid electrochemical detecting. The osmium redox complexes were synthesized by the coordinating pyridine group having different functional group at 4-position with osmium compounds. The synthesized poly-osmium hydrogel complexes are described as PAA-PVI-$[Os(dCl-bpy)_2Cl]^{+/2+}$, PAA-PVI-$[Os(dme-bpy)_2Cl]^{+/2+}$, PAA-PVI-$[Os(dmo-bpy)_2Cl]^{+/2+}$. The different concentrations of uric acid were measured by cyclic voltammetry technique using enzyme-immobilized SPCEs. The prepared SPCEs using PAA-PVI-$[Os(dme-bpy)_2Cl]^{+/2+}$ showed no interference from common physiologic interferents such as ascorbic acid (AA) or glucose. The resulting electrical currents at 0.33 V vs. Ag/AgCl displayed a good linear response with uric acid concentrations from 1.0 to 5.0 mM. Therefore, this approach allowed the development of a simple, point of care in the medical field, disposable electrochemical uric acid biosensor.

Study on the stress distribution depending on the bone type and implant abutment connection by finite element analysis (지대주 연결 형태와 골질에 따른 저작압이 임프란트 주위골내 응력분포에 미치는 영향)

  • Park, Hyun-Soo;Lim, Sung-Bin;Chung, Chin-Hyung;Hong, Ki-Seok
    • Journal of Periodontal and Implant Science
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    • v.36 no.2
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    • pp.531-554
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    • 2006
  • Oral implants must fulfill certain criteria arising from special demands of function, which include biocompatibility, adequate mechanical strength, optimum soft and hard tissue integration, and transmission of functional forces to bone within physiological limits. And one of the critical elements influencing the long-term uncompromise functioning of oral implants is load distribution at the implant- bone interface, Factors that affect the load transfer at the bone-implant interface include the type of loading, material properties of the implant and prosthesis, implant geometry, surface structure, quality and quantity of the surrounding bone, and nature of the bone-implant interface. To understand the biomechanical behavior of dental implants, validation of stress and strain measurements is required. The finite element analysis (FEA) has been applied to the dental implant field to predict stress distribution patterns in the implant-bone interface by comparison of various implant designs. This method offers the advantage of solving complex structural problems by dividing them into smaller and simpler interrelated sections by using mathematical techniques. The purpose of this study was to evaluate the stresses induced around the implants in bone using FEA, A 3D FEA computer software (SOLIDWORKS 2004, DASSO SYSTEM, France) was used for the analysis of clinical simulations. Two types (external and internal) of implants of 4.1 mm diameter, 12.0 mm length were buried in 4 types of bone modeled. Vertical and oblique forces of lOON were applied on the center of the abutment, and the values of von Mises equivalent stress at the implant-bone interface were computed. The results showed that von Mises stresses at the marginal. bone were higher under oblique load than under vertical load, and the stresses were higher at the lingual marginal bone than at the buccal marginal bone under oblique load. Under vertical and oblique load, the stress in type I, II, III bone was found to be the highest at the marginal bone and the lowest at the bone around apical portions of implant. Higher stresses occurred at the top of the crestal region and lower stresses occurred near the tip of the implant with greater thickness of the cortical shell while high stresses surrounded the fixture apex for type N. The stresses in the crestal region were higher in Model 2 than in Model 1, the stresses near the tip of the implant were higher in Model 1 than Model 2, and Model 2 showed more effective stress distribution than Model.

Sensitivity of COMS/GOCI Measured Top-of-atmosphere Reflectances to Atmospheric Aerosol Properties (COMS/GOCI 관측값의 대기 에어러솔의 특성에 대한 민감도 분석)

  • Lee, Kwon-Ho;Kim, Young-Joon
    • Korean Journal of Remote Sensing
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    • v.24 no.6
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    • pp.559-569
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    • 2008
  • The Geostationary Ocean Color Imager (GOCI) on board the Communication Ocean Meteorological Satellite (COMS), the first geostationary ocean color sensor, requires accurate atmospheric correction since its eight bands are also affected by atmospheric constituents such as gases, molecules and atmospheric aerosols. Unlike gases and molecules in the atmosphere, aerosols can interact with sunlight by complex scattering and absorption properties. For the purpose of qualified ocean remote sensing, understanding of aerosol-radiation interactions is needed. In this study, we show micro-physical and optical properties of aerosols using the Optical Property of Aerosol and Cloud (OPAC) aerosol models. Aerosol optical properties, then, were used to analysis the relationship between theoretical satellite measured radiation from radiative transfer calculations and aerosol optical thickness (AOT) under various environments (aerosol type and loadings). It is found that the choice of aerosol type makes little different in AOT retrieval for AOT<0.2. Otherwise AOT differences between true and retrieved increase as AOT increases. Furthermore, the differences between the AOT and angstrom exponent from standard algorithms and this study, and the comparison with ground based sunphotometer observations are investigated. Over the northeast Asian region, these comparisons suggest that spatially averaged mean AOT retrieved from this study is much better than from standard ocean color algorithm. Finally, these results will be useful for aerosol retrieval or atmospheric correction of COMS/GOCI data processing.

Estimation of Hourly Variations in Public Transit Demand according to the Addition of Sales Facilities to Railway Stations: Focusing on Metro and Bus Transit Demand (철도역사 판매시설 증축에 따른 시간대별 대중교통 수요 변화 추정: 지하철 및 버스 수요를 중심으로)

  • Jang, Jaemin;Moon, Dae Seop;Kim, Sujeong;Gim, Tae-Hyoung Tommy
    • Journal of the Korean Society for Railway
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    • v.18 no.6
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    • pp.630-638
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    • 2015
  • The total number of passengers on the KTX since its construction in 2004 surpassed 500 million in October, 2015. The operation of KTX made it possible to reach anywhere in a country in half a day, which subsequently altered people's lifestyle. As the KTX has become an important mode of transportation, there is a growing interest in the optimal size and location of its stations. Currently, the stations are constructed through public-private partnerships since a sufficient amount of budget is hard to secure only from the public sector; however, because railway stations are traditionally aimed at promoting public interests, an emphasis on the profitability of the private sector could compromise public interests. At this juncture, this study separately computes the number of users based on each of the two primary functions of the stations-as a railway station and as a sales facility-and estimates the numbers of people according to various transportation modes that are taken to access the stations. This estimation is applied to the case of Dongdaegu Station, which will open in 2016. Such an application helps to predict and respond to possible congestion as brought about by the expansion of the sales facility.

Development of a Coupled Eulerian-Lagrangian Finite Element Model for Dissimilar Friction Stir Welding (Coupled Eulerian-Lagrangian기법을 이용한 이종 마찰교반용접 해석모델 개발)

  • Lim, Jae-Yong;Lee, Jinho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.2
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    • pp.7-13
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    • 2019
  • This study aims to develop a FE Model to simulate dissimilar friction stir welding and to address its potential for fundamental analysis and practical applications. The FE model is based on Coupled Eulerian-Lagrangian approach. Multiphysics systems are calculated using explicit time integration algorithm, and heat generations by friction and inelastic heat conversion as well as heat transfer through the bottom surface are included. Using the developed model, friction stir welding between an Al6061T6 plate and an AZ61 plate were simulated. Three simulations are carried out varying the welding parameters. The model is capable of predicting the temperature and plastic strain fields and the distribution of void. The simulation results showed that temperature was generally greater in Mg plates and that, as a rotation speed increase, not the maximum temperature of Mg plate increased, but did the temperature of Al plate. In addition, the model could predict flash defects, however, the prediction of void near the welding tool was not satisfactory. Since the model includes the complex physics closely occurring during FSW, the model possibly analyze a lot of phenomena hard to discovered by experiments. However, practical applications may be limited due to huge simulation time.