• 제목/요약/키워드: Complex surface

검색결과 2,349건 처리시간 0.028초

IMI-O 고분자 LB막의 제작 및 전기적 특성 (Fabrication and Electrical Properties of IMI-O Polymer LB Films)

  • 정상범;유승엽;박재철;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권2호
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    • pp.87-91
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    • 2000
  • Metal ion complex of poly(N-(2,4-imidazoly)ethyl)maleimide-alt-l-octadecene (IMO-O) polymer used to confirm the possibility of molecular device made by Langmuir-Blodgett(LB) method. Electrical properties of the metal ion complex LB film were investigated using Metal/Insulator/Metal(MIM) structure. In the surface pressure-area($\pi$-A) isotherm of IMI-O polymer, the surface pressure at collapse point has a difference due to the interaction between polymer and metal ions. And the complex between polymer and metal ions could be verified through the investigation by Raman spectroscopy. In the current-voltage(I-V) property, the conductivity change of IMO-O polymer complexes due to the kinds of metal of metal ions couldn't be observed. However, the limiting area of molecules was changed by the concentration of the metal ions and the conductivity was increased with the occupied molecular area.

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Effects of Mixing Ratio on the Mechanical and Thermal Properties of Polyelectrolyte Complex Film

  • Son Tae-Won;Kim Byung-Giu;Park Young-Mi;Lim Hak-Sang;Kwon Oh-Kyung
    • Macromolecular Research
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    • 제14권3호
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    • pp.267-271
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    • 2006
  • Polyelectrolyte complex films were prepared with two compounds, chitosan and poly(ethylene glycol)-monosuccinate, using a casting in order to synthesize a polyelectrolyte complex film with various mole ratios of chitosan and poly(ethylene glycol)-monosuccinate. The solution properties of isolated PEC were investigated for the effects of FTIR, pH value, Brookfield viscosity and cell viability assay using MTT staining. The PEC films were evaluated for mechanical properties by typical stress-strain curve, far thermal properties by DSC and TGA and for surface morphology Properties by SEM. Furthermore, the surface resistance, moisture regain and water content of the films were characterized. The solution properties were affected by several factors including the chitosan content in the PEC, the mixing ratio of PEG and chitosan, and pH. Several PEC in acidic conditions exhibited film formation under appropriate conditions of mixing ratio and chitosan concentration in the mixing process. These PEC films were found to have sufficiently flexible and stable properties due to their hydrophilic structure, which was farmed by the oppositely charged interaction between PEG-MS and chitosan matrix. The results showed the potential applicability of chitosan and poly(ethylene glycol)-monosuccinate films as a biocompatible polymer.

Polysulfone/nanocomposites mixed matrix ultrafiltration membrane for the recovery of Maillard reaction products

  • Basu, Subhankar;Mukherjee, Sanghamitra;Balakrishnan, Malini;Deepthi, M.V.;Sailaja, R.R.N.
    • Membrane and Water Treatment
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    • 제9권2호
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    • pp.105-113
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    • 2018
  • Maillard reaction products like melanoidins present in industrial fermentation wastewaters are complex compounds with various functional properties. In this work, novel ultrafiltration (UF) mixed matrix membrane (MMM) composed of polysulfone (PSF) and nanocomposites was prepared through a phase inversion process for the recovery of melanoidins. Nanocomposites were prepared with acid functionalized multiwalled carbon nanotubes (MWCNTs) as the reinforcing filler for chitosan-thermoplastic starch blend. Higher nanocomposites content in the PSF matrix reduced the membrane permeability and melanoidins retention indicating tighter membrane with surface defects. The membrane surface defects could be sealed with dilute polyvinyl alcohol (PVA) solution. The best performing membrane (1% nanocomposites in 18% PSF membrane sealed with 0.25% PVA coating) resulted in uniform melanoidins retention of 98% and permeability of 3.6 L/m2 h bar over a period of 8h. This demonstrates a low fouling PSF membrane for high melanoidins recovery.

Label-free and sensitive detection of purine catabolites in complex solutions by surface-enhanced raman spectroscopy

  • Davaa-Ochir, Batmend;Ansah, Iris Baffour;Park, Sung Gyu;Kim, Dong-Ho
    • 한국표면공학회지
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    • 제55권6호
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    • pp.342-352
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    • 2022
  • Purine catabolite screening enables reliable diagnosis of certain diseases. In this regard, the development of a facile detection strategy with high sensitivity and selectivity is demanded for point-of-care applications. In this work, the simultaneous detection of uric acid (UA), xanthine (XA), and hypoxanthine (HX) was carried out as model purine catabolites by surface-enhanced Raman Spectroscopy (SERS). The detection assay was conducted by employing high-aspect ratio Au nanopillar substrates coupled with in-situ Au electrodeposition on the substrates. The additional modification of the Au nanopillar substrates via electrodeposition was found to be an effective method to encapsulate molecules in solution into nanogaps of growing Au films that increase metal-molecule contact and improve substrate's sensitivity and selectivity. In complex solutions, the approach facilitated ternary identification of UA, XA, and HX down to concentration limits of 4.33 𝜇M, 0.71 𝜇M, and 0.22 𝜇M, respectively, which are comparable to their existing levels in normal human physiology. These results demonstrate that the proposed platform is reliable for practical point-of-care analysis of biofluids where solution matrix effects greatly reduce selectivity and sensitivity for rapid on-site disease diagnosis.

단지 유형에 따른 도시의 미기후 조절 계획에 관한 연구 (The Planning of Micro-climate Control by Complex Types)

  • 정주리;정민희
    • KIEAE Journal
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    • 제17권1호
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    • pp.49-54
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    • 2017
  • Purpose: Temperature in urban areas increase much more than suburban areas and it is called urban heat island (UHI) phenomenon. There are several solutions to control UHI phenomenon such as green roof system, water space construction, and cool roof system. However, application of green roof system and cool roof system to some of the buildings which compose the city has a critical limit. Therefore, in order to diminish the temperature rising and UHI phenomenon due to climate change of the city, it needs to approach from the viewpoint of site or city, rather than the viewpoint of individual buildings. This study is aims at analyzing UHI phenomenon by characteristics of surface materials and suggesting the solutions to reduce UHI phenomenon by types of complex. Method: Literature reviews were conducted to analyze the cause, mitigating plan, and recent trends of UHI phenomenon. For the simulation analysis, the type of complex was classified 3 representative complex. Based on measured reflectivity, simulation about UHI phenomenon was conducted by setting 4 strategies; albedo of roof, road pavement, green roof system, and vegetating around buildings. Result: As the results of simulating the UHI reduction factor by types of complex, it showed that the effect of temperature reduction on the building roof layer is more effective than adjusting the reflectivity of buildings such as green roof system, planting near the buildings in both the detached house complex, apartment complex, and commercial complex.

회전하는 터빈 블레이드 이차유로내 요철 배열이 열/물질전달에 미치는 영향 (Effect of Heat/Mass Transfer in the turbine blade internal passage with various rib arrangement)

  • 이세영;조형희
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집B
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    • pp.22-29
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    • 2001
  • The present study investigates the effects of various rib arrangements and rotating on heat/mass transfer in the cooling passage of gas turbine blades. The cooling passage has very complex flow structure, because of the rib turbulator and rotating effect. Experiments and numerical calculation are conducted to investigate the complex flow structures and heat transfer characteristics; the numerical computation is performed using a commercial code, FLUENT ver.5, to calculate the flow structures and the experiments are conducted to measure heat/mass transfer coefficients using a naphthalene sublimation technique. For the rotating duct tests, the test duct, which is the cross section of is $20mm\times40mm$ (the hydraulic diameter, $D_h$, of 26.7 mm, has two-pass with $180^{\circ}$ turning and the rectangular ribs on the wall. The rib angle of attack is $70^{\circ}$ and the maximum radius of rotation is $21.63D_h$. The partition wall has 10 mm thickness, which is 0.5 times to the channel width, and the distance between the tip of the partition wall and the outer wall of the turning region is 26.7 mm $(1D_h)$. The turning effect of duct flow makes the very complex flow structure including Dean type vortex and high turbulence, so that the heat/mass transfer increases in the turning region and at the entrance of the second pass. The Coriolis effect deflects the flow to the trailing surface, resulting in enhancement of the heat/mass transfer on the trailing surface and reduction on the leading surface in the first pass. However, the opposite phenomena are observed in the second pass. The each rib arrangement makes different secondary flow patterns. The complex heat/mass transfer characteristics are observed by the combined effects of the rib arrangements, duct rotation and flow turning.

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Quality monitoring of complex manufacturing systems on the basis of model driven approach

  • Castano, Fernando;Haber, Rodolfo E.;Mohammed, Wael M.;Nejman, Miroslaw;Villalonga, Alberto;Lastra, Jose L. Martinez
    • Smart Structures and Systems
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    • 제26권4호
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    • pp.495-506
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    • 2020
  • Monitoring of complex processes faces several challenges mainly due to the lack of relevant sensory information or insufficient elaborated decision-making strategies. These challenges motivate researchers to adopt complex data processing and analysis in order to improve the process representation. This paper presents the development and implementation of quality monitoring framework based on a model-driven approach using embedded artificial intelligence strategies. In this work, the strategies are applied to the supervision of a microfabrication process aiming at showing the great performance of the framework in a very complex system in the manufacturing sector. The procedure involves two methods for modelling a representative quality variable, such as surface roughness. Firstly, the hybrid incremental modelling strategy is applied. Secondly, a generalized fuzzy clustering c-means method is developed. Finally, a comparative study of the behavior of the two models for predicting a quality indicator, represented by surface roughness of manufactured components, is presented for specific manufacturing process. The manufactured part used in this study is a critical structural aerospace component. In addition, the validation and testing are performed at laboratory and industrial levels, demonstrating proper real-time operation for non-linear processes with relatively fast dynamics. The results of this study are very promising in terms of computational efficiency and transfer of knowledge to manufacturing industry.

현대건축에서 나타나는 복합적 외피의 표현적 특성에 관한 연구 - 헤르조그 & 드 뮤론의 건축물을 중심으로 - (The Study on the Expressive Characteristics of Complex Surface in Contemporary Architecture - focused on of Herzog & de Meuron's Architecture -)

  • 김정곤
    • 한국실내디자인학회논문집
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    • 제21권5호
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    • pp.3-11
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    • 2012
  • The first visual contact in architecture happens in surface, and it could be significant object as well as the starting point to recognize the essence and perceive the buildings. Architecture surface could not get out of the restriction of structures and materials that support buildings for a long time in the past. Architecture surface in the past should fulfill the structural role to form are appearance of buildings and support buildings at the same time, so it was difficult to get out of logic for material and thickness of walls, arrangements and sizes of windows. However, since the modern age, architecture surface came to be freer according to the development of building technology, and development of technology changes shows tendencies to express role of new design factor as an architectural element emphasized expression and autonomy,s which was escaped from the subordinate relationship that the surface of building must do the structural function. In this study, it would be examined the expressive characteristics of various epidermis that are expressed in architecture of Herzog & de Meuron since the end of 20thcentury focused on comprehended and analyzed results of changes and characteristics of contemporary society. Through this, it would be comprehended the epidermis of architecture that has particular character expressed in modern buildings of Herzog & de Meuron, and it would be composed a certain linkage between this and characteristics of contemporary society and it would be investigated that the establishing process of inner spaces. Identification through case analysis for this would perform a role of catalyst for the new possibility and development of contemporary architecture's surface expression in the future.

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음함수 곡면기법을 이용한 폴리곤 모델의 홀메움에 관한 연구 (A Study on Filling Holes of the Polygon Model using Implicit Surface Scheme)

  • 유동진
    • 한국정밀공학회지
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    • 제22권3호
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    • pp.107-114
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    • 2005
  • A new approach which combines implicit surface scheme and point projection method is presented in order to fill the arbitrarily shaped holes in the polygon model. In the method a trimmed surface which has an outer boundary curve is generated by using the implicit surface scheme and normal projection of point onto the base surface. The base surface is constructed by creating smooth implicit surface from the incomplete polygon model through which the surface should pass. In this paper an implicit surface is defined by a radial basis function, a continuous scalar-valued function over the domain $R^3$. The base surface is the set of all points at which this scalar function takes on the value zero and is created by placing zero-valued constraints at the vertices of the polygon model. In order to show the validity of the present study, various hole fillings are carried out for the complex polygon model of arbitrary topology.